Regioselective Synthesis of 3- and 5-Functional Derivatives of Pyrazolidine. 1. Synthesis of Ketones of the Pyrazolidine Series View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-10

AUTHORS

L. A. Sviridova, A. N. Tavtorkin, P. B. Terentiev, I. F. Lescheva, N. G. Kolotyrkina, K. A. Kochetkov

ABSTRACT

When 5-hydroxypyrazolidines reacted with ketones on the surface of basic adsorbents the 3-regioisomers were obtained in addition to the expected 5-oxoalkylpyrazolidines. The conditions for the regiodirection of the process have been found.

PAGES

1314-1320

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-005-0318-x

DOI

http://dx.doi.org/10.1007/s10593-005-0318-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003539266


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "M. V. Lomonosov Moscow State University, 119992, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "M. V. Lomonosov Moscow State University, 119992, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sviridova", 
        "givenName": "L. A.", 
        "id": "sg:person.011301711767.73", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011301711767.73"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tavtorkin", 
        "givenName": "A. N.", 
        "id": "sg:person.013120303232.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013120303232.11"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "M. V. Lomonosov Moscow State University, 119992, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "M. V. Lomonosov Moscow State University, 119992, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Terentiev", 
        "givenName": "P. B.", 
        "id": "sg:person.010117511673.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010117511673.01"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "M. V. Lomonosov Moscow State University, 119992, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "M. V. Lomonosov Moscow State University, 119992, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lescheva", 
        "givenName": "I. F.", 
        "id": "sg:person.015400045275.38", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015400045275.38"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kolotyrkina", 
        "givenName": "N. G.", 
        "id": "sg:person.016374705303.78", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016374705303.78"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kochetkov", 
        "givenName": "K. A.", 
        "id": "sg:person.015077576525.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015077576525.37"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2005-10", 
    "datePublishedReg": "2005-10-01", 
    "description": "When 5-hydroxypyrazolidines reacted with ketones on the surface of basic adsorbents the 3-regioisomers were obtained in addition to the expected 5-oxoalkylpyrazolidines. The conditions for the regiodirection of the process have been found.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s10593-005-0318-x", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1358699", 
        "issn": [
          "0132-6244", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "10", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "41"
      }
    ], 
    "keywords": [
      "synthesis of ketones", 
      "regioselective synthesis", 
      "basic adsorbent", 
      "ketones", 
      "synthesis", 
      "adsorbent", 
      "pyrazolidine", 
      "derivatives", 
      "surface", 
      "series", 
      "addition", 
      "process", 
      "conditions", 
      "regiodirection", 
      "Derivatives of Pyrazolidine", 
      "Pyrazolidine Series"
    ], 
    "name": "Regioselective Synthesis of 3- and 5-Functional Derivatives of Pyrazolidine. 1. Synthesis of Ketones of the Pyrazolidine Series", 
    "pagination": "1314-1320", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1003539266"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10593-005-0318-x"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10593-005-0318-x", 
      "https://app.dimensions.ai/details/publication/pub.1003539266"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T18:08", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_399.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s10593-005-0318-x"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10593-005-0318-x'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10593-005-0318-x'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10593-005-0318-x'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10593-005-0318-x'


 

This table displays all metadata directly associated to this object as RDF triples.

115 TRIPLES      21 PREDICATES      42 URIs      34 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10593-005-0318-x schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author N1fbd7766ee4546ff9f7598929b10b2e8
4 schema:datePublished 2005-10
5 schema:datePublishedReg 2005-10-01
6 schema:description When 5-hydroxypyrazolidines reacted with ketones on the surface of basic adsorbents the 3-regioisomers were obtained in addition to the expected 5-oxoalkylpyrazolidines. The conditions for the regiodirection of the process have been found.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf Na6f49dfbc0194868b2f668267ddd5c62
11 Nd8d64be382cd4d0987e8498367af3c33
12 sg:journal.1358699
13 schema:keywords Derivatives of Pyrazolidine
14 Pyrazolidine Series
15 addition
16 adsorbent
17 basic adsorbent
18 conditions
19 derivatives
20 ketones
21 process
22 pyrazolidine
23 regiodirection
24 regioselective synthesis
25 series
26 surface
27 synthesis
28 synthesis of ketones
29 schema:name Regioselective Synthesis of 3- and 5-Functional Derivatives of Pyrazolidine. 1. Synthesis of Ketones of the Pyrazolidine Series
30 schema:pagination 1314-1320
31 schema:productId N27b9674c6b2b45f39c6273ed4869955e
32 Ncac5e481279644fe9df3d9ba39eea281
33 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003539266
34 https://doi.org/10.1007/s10593-005-0318-x
35 schema:sdDatePublished 2021-11-01T18:08
36 schema:sdLicense https://scigraph.springernature.com/explorer/license/
37 schema:sdPublisher N600babd2600b43879fa299eaaa9c248c
38 schema:url https://doi.org/10.1007/s10593-005-0318-x
39 sgo:license sg:explorer/license/
40 sgo:sdDataset articles
41 rdf:type schema:ScholarlyArticle
42 N0dd92b23fdcf4314b7f1bbabd4770e2c rdf:first sg:person.013120303232.11
43 rdf:rest N4043686bff07485aaca5e475b6591b3f
44 N1e5cbfd5f9ed45eaa246ded1376e301a rdf:first sg:person.015400045275.38
45 rdf:rest N763edcfe385b47ff928cb7558d1b5f10
46 N1fbd7766ee4546ff9f7598929b10b2e8 rdf:first sg:person.011301711767.73
47 rdf:rest N0dd92b23fdcf4314b7f1bbabd4770e2c
48 N27b9674c6b2b45f39c6273ed4869955e schema:name doi
49 schema:value 10.1007/s10593-005-0318-x
50 rdf:type schema:PropertyValue
51 N4043686bff07485aaca5e475b6591b3f rdf:first sg:person.010117511673.01
52 rdf:rest N1e5cbfd5f9ed45eaa246ded1376e301a
53 N600babd2600b43879fa299eaaa9c248c schema:name Springer Nature - SN SciGraph project
54 rdf:type schema:Organization
55 N763edcfe385b47ff928cb7558d1b5f10 rdf:first sg:person.016374705303.78
56 rdf:rest N897123773ed9444ab9a9223892ba3adf
57 N897123773ed9444ab9a9223892ba3adf rdf:first sg:person.015077576525.37
58 rdf:rest rdf:nil
59 Na6f49dfbc0194868b2f668267ddd5c62 schema:volumeNumber 41
60 rdf:type schema:PublicationVolume
61 Ncac5e481279644fe9df3d9ba39eea281 schema:name dimensions_id
62 schema:value pub.1003539266
63 rdf:type schema:PropertyValue
64 Nd8d64be382cd4d0987e8498367af3c33 schema:issueNumber 10
65 rdf:type schema:PublicationIssue
66 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
67 schema:name Chemical Sciences
68 rdf:type schema:DefinedTerm
69 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
70 schema:name Organic Chemistry
71 rdf:type schema:DefinedTerm
72 sg:journal.1358699 schema:issn 0132-6244
73 1573-8353
74 schema:name Chemistry of Heterocyclic Compounds
75 schema:publisher Springer Nature
76 rdf:type schema:Periodical
77 sg:person.010117511673.01 schema:affiliation grid-institutes:grid.14476.30
78 schema:familyName Terentiev
79 schema:givenName P. B.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010117511673.01
81 rdf:type schema:Person
82 sg:person.011301711767.73 schema:affiliation grid-institutes:grid.14476.30
83 schema:familyName Sviridova
84 schema:givenName L. A.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011301711767.73
86 rdf:type schema:Person
87 sg:person.013120303232.11 schema:affiliation grid-institutes:grid.431939.5
88 schema:familyName Tavtorkin
89 schema:givenName A. N.
90 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013120303232.11
91 rdf:type schema:Person
92 sg:person.015077576525.37 schema:affiliation grid-institutes:grid.431939.5
93 schema:familyName Kochetkov
94 schema:givenName K. A.
95 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015077576525.37
96 rdf:type schema:Person
97 sg:person.015400045275.38 schema:affiliation grid-institutes:grid.14476.30
98 schema:familyName Lescheva
99 schema:givenName I. F.
100 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015400045275.38
101 rdf:type schema:Person
102 sg:person.016374705303.78 schema:affiliation grid-institutes:grid.439283.7
103 schema:familyName Kolotyrkina
104 schema:givenName N. G.
105 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016374705303.78
106 rdf:type schema:Person
107 grid-institutes:grid.14476.30 schema:alternateName M. V. Lomonosov Moscow State University, 119992, Moscow, Russia
108 schema:name M. V. Lomonosov Moscow State University, 119992, Moscow, Russia
109 rdf:type schema:Organization
110 grid-institutes:grid.431939.5 schema:alternateName A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia
111 schema:name A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia
112 rdf:type schema:Organization
113 grid-institutes:grid.439283.7 schema:alternateName N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia
114 schema:name N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia
115 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...