Reaction of 3-Arylaminobenzofuro-, 3-Arylaminobenzothieno-, and 3-Arylaminoindolo[2,3-c]pyrylium Salts with Nucleophilic Reagents View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-04

AUTHORS

V. S. Tolkunov, Yu. B. Vysotsky, O. A. Gorban’, S. V. Shishkina, O. V. Shishkin, V. I. Dulenko

ABSTRACT

We have studied the reactions of 3-arylaminobenzofuro-, 3-arylaminobenzothieno-, and 3-arylaminoindolo[2,3-c]pyrylium salts with ammonium acetate, primary amines, and hydrazine hydrate. In an alcoholic medium, primary amines and hydrazine hydrate open up the pyrylium ring to form arylamides of 2-(N-benzylmethylketimine)hetaryl-3-acetic acids or the corresponding hydrazones, where further heterocyclization does not occur. Upon treatment with ammonium acetate in acetic acid, 2-aryl-1-methylhetero[2,3-c]pyridin-3-(2H)-ones are formed along with their 2-unsubstituted analogs. More... »

PAGES

515-525

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10593-005-0181-9

DOI

http://dx.doi.org/10.1007/s10593-005-0181-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1036596039


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