Study of europium and selected actinides uptake on composite material CMPO-PAN View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-01

AUTHORS

J. Kameník, F. Šebesta

ABSTRACT

Modified CMPO-PAN production was used and the resulting composite material was tested for purposes of extraction chromatography. A commercially avaialble extraction agent octyl(phenyl)-N,N’-diisobutylcarbamoylmethylphosphine oxide (CMPO) and polyacrylonitrile (PAN) were used. The europium uptake kinetics by composite material was studied in two different nitric acid solutions. The dependences of weight distribution coefficients (Dg) of europium, americium, plutonium, uranium, and neptunium on nitric acid concentration (0.01–5 mol L−1) in the presence of sodium nitrate (0.1 mol L−1) were determined. High Dg-values were found in 0.1–5 M nitric acid for all elements tested. Increase in europium and americium Dg-values with decrease in nitric acid concentration (bellow 0.1 mol L−1) was observed. This behaviour in diluted nitric acid solutions differs from the behaviour of the similar materials with another support. CMPO-PAN composite material was compared with commercially available TRU Resin. Dg-values of the tested elements in all solutions used were higher for CMPO-PAN than for TRU Resin. The retention of the studied elements on CMPO-PAN in hydrochloric acid was made as a screening study. More... »

PAGES

d493-d500

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10582-006-1057-7

DOI

http://dx.doi.org/10.1007/s10582-006-1057-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017741434


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Materials Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Department of Nuclear Chemistry, Czech Technical University, B\u0159ehov\u00e1 7, CZ-115 19, Prague 1, Czech Republic", 
          "id": "http://www.grid.ac/institutes/grid.6652.7", 
          "name": [
            "Department of Nuclear Chemistry, Czech Technical University, B\u0159ehov\u00e1 7, CZ-115 19, Prague 1, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kamen\u00edk", 
        "givenName": "J.", 
        "id": "sg:person.011235673125.19", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011235673125.19"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Centre for Radiochemistry and Radiation Chemistry, Czech Technical University, B\u0159ehov\u00e1 7, CZ-115 19, Prague 1, Czech Republic", 
          "id": "http://www.grid.ac/institutes/grid.6652.7", 
          "name": [
            "Centre for Radiochemistry and Radiation Chemistry, Czech Technical University, B\u0159ehov\u00e1 7, CZ-115 19, Prague 1, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "\u0160ebesta", 
        "givenName": "F.", 
        "id": "sg:person.014502716325.78", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014502716325.78"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf02347462", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004517838", 
          "https://doi.org/10.1007/bf02347462"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02035352", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016301358", 
          "https://doi.org/10.1007/bf02035352"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/978-94-011-4546-6_9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024819580", 
          "https://doi.org/10.1007/978-94-011-4546-6_9"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02060190", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006926858", 
          "https://doi.org/10.1007/bf02060190"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1020829228253", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041676095", 
          "https://doi.org/10.1023/a:1020829228253"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10582-003-0076-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029920699", 
          "https://doi.org/10.1007/s10582-003-0076-x"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2006-01", 
    "datePublishedReg": "2006-01-01", 
    "description": "Modified CMPO-PAN production was used and the resulting composite material was tested for purposes of extraction chromatography. A commercially avaialble extraction agent octyl(phenyl)-N,N\u2019-diisobutylcarbamoylmethylphosphine oxide (CMPO) and polyacrylonitrile (PAN) were used. The europium uptake kinetics by composite material was studied in two different nitric acid solutions. The dependences of weight distribution coefficients (Dg) of europium, americium, plutonium, uranium, and neptunium on nitric acid concentration (0.01\u20135 mol L\u22121) in the presence of sodium nitrate (0.1 mol L\u22121) were determined. High Dg-values were found in 0.1\u20135 M nitric acid for all elements tested. Increase in europium and americium Dg-values with decrease in nitric acid concentration (bellow 0.1 mol L\u22121) was observed. This behaviour in diluted nitric acid solutions differs from the behaviour of the similar materials with another support. CMPO-PAN composite material was compared with commercially available TRU Resin. Dg-values of the tested elements in all solutions used were higher for CMPO-PAN than for TRU Resin. The retention of the studied elements on CMPO-PAN in hydrochloric acid was made as a screening study.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s10582-006-1057-7", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1297212", 
        "issn": [
          "0011-4626", 
          "1572-9486"
        ], 
        "name": "Czechoslovak Journal of Physics", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "56"
      }
    ], 
    "keywords": [
      "composite materials", 
      "nitric acid solution", 
      "nitric acid concentration", 
      "Study of europium", 
      "different nitric acid solutions", 
      "weight distribution coefficients", 
      "acid solution", 
      "similar materials", 
      "TRU resin", 
      "extraction agent", 
      "materials", 
      "nitric acid", 
      "polyacrylonitrile", 
      "resin", 
      "distribution coefficients", 
      "hydrochloric acid", 
      "sodium nitrate", 
      "DG values", 
      "solution", 
      "extraction chromatography", 
      "acid concentration", 
      "behavior", 
      "oxide", 
      "elements", 
      "europium", 
      "coefficient", 
      "plutonium", 
      "americium", 
      "actinides", 
      "uranium", 
      "kinetics", 
      "studied elements", 
      "dependence", 
      "concentration", 
      "nitrate", 
      "retention", 
      "increase", 
      "production", 
      "decrease", 
      "uptake kinetics", 
      "study", 
      "purpose", 
      "presence", 
      "acid", 
      "support", 
      "screening study", 
      "agents", 
      "chromatography"
    ], 
    "name": "Study of europium and selected actinides uptake on composite material CMPO-PAN", 
    "pagination": "d493-d500", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1017741434"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10582-006-1057-7"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10582-006-1057-7", 
      "https://app.dimensions.ai/details/publication/pub.1017741434"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-05-10T09:55", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220509/entities/gbq_results/article/article_429.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s10582-006-1057-7"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10582-006-1057-7'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10582-006-1057-7'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10582-006-1057-7'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10582-006-1057-7'


 

This table displays all metadata directly associated to this object as RDF triples.

139 TRIPLES      22 PREDICATES      80 URIs      66 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10582-006-1057-7 schema:about anzsrc-for:09
2 anzsrc-for:0912
3 schema:author Na616cacbd3734bf89d0a56d94410f808
4 schema:citation sg:pub.10.1007/978-94-011-4546-6_9
5 sg:pub.10.1007/bf02035352
6 sg:pub.10.1007/bf02060190
7 sg:pub.10.1007/bf02347462
8 sg:pub.10.1007/s10582-003-0076-x
9 sg:pub.10.1023/a:1020829228253
10 schema:datePublished 2006-01
11 schema:datePublishedReg 2006-01-01
12 schema:description Modified CMPO-PAN production was used and the resulting composite material was tested for purposes of extraction chromatography. A commercially avaialble extraction agent octyl(phenyl)-N,N’-diisobutylcarbamoylmethylphosphine oxide (CMPO) and polyacrylonitrile (PAN) were used. The europium uptake kinetics by composite material was studied in two different nitric acid solutions. The dependences of weight distribution coefficients (Dg) of europium, americium, plutonium, uranium, and neptunium on nitric acid concentration (0.01–5 mol L−1) in the presence of sodium nitrate (0.1 mol L−1) were determined. High Dg-values were found in 0.1–5 M nitric acid for all elements tested. Increase in europium and americium Dg-values with decrease in nitric acid concentration (bellow 0.1 mol L−1) was observed. This behaviour in diluted nitric acid solutions differs from the behaviour of the similar materials with another support. CMPO-PAN composite material was compared with commercially available TRU Resin. Dg-values of the tested elements in all solutions used were higher for CMPO-PAN than for TRU Resin. The retention of the studied elements on CMPO-PAN in hydrochloric acid was made as a screening study.
13 schema:genre article
14 schema:inLanguage en
15 schema:isAccessibleForFree false
16 schema:isPartOf N102ad4cd13674e238518c2cb97267f44
17 N71e2f1c2992d4ed8ba2242a75c617a22
18 sg:journal.1297212
19 schema:keywords DG values
20 Study of europium
21 TRU resin
22 acid
23 acid concentration
24 acid solution
25 actinides
26 agents
27 americium
28 behavior
29 chromatography
30 coefficient
31 composite materials
32 concentration
33 decrease
34 dependence
35 different nitric acid solutions
36 distribution coefficients
37 elements
38 europium
39 extraction agent
40 extraction chromatography
41 hydrochloric acid
42 increase
43 kinetics
44 materials
45 nitrate
46 nitric acid
47 nitric acid concentration
48 nitric acid solution
49 oxide
50 plutonium
51 polyacrylonitrile
52 presence
53 production
54 purpose
55 resin
56 retention
57 screening study
58 similar materials
59 sodium nitrate
60 solution
61 studied elements
62 study
63 support
64 uptake kinetics
65 uranium
66 weight distribution coefficients
67 schema:name Study of europium and selected actinides uptake on composite material CMPO-PAN
68 schema:pagination d493-d500
69 schema:productId N2e8ede3d8774441e810612d6ba10afcf
70 Nb5248b1c133b495884dea12964adf766
71 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017741434
72 https://doi.org/10.1007/s10582-006-1057-7
73 schema:sdDatePublished 2022-05-10T09:55
74 schema:sdLicense https://scigraph.springernature.com/explorer/license/
75 schema:sdPublisher N6386f064d8d0485db7d23c1000d2566f
76 schema:url https://doi.org/10.1007/s10582-006-1057-7
77 sgo:license sg:explorer/license/
78 sgo:sdDataset articles
79 rdf:type schema:ScholarlyArticle
80 N102ad4cd13674e238518c2cb97267f44 schema:issueNumber 1
81 rdf:type schema:PublicationIssue
82 N2e8ede3d8774441e810612d6ba10afcf schema:name dimensions_id
83 schema:value pub.1017741434
84 rdf:type schema:PropertyValue
85 N6386f064d8d0485db7d23c1000d2566f schema:name Springer Nature - SN SciGraph project
86 rdf:type schema:Organization
87 N71e2f1c2992d4ed8ba2242a75c617a22 schema:volumeNumber 56
88 rdf:type schema:PublicationVolume
89 N77ca30e857834440b72dc86cdb2ed2b5 rdf:first sg:person.014502716325.78
90 rdf:rest rdf:nil
91 Na616cacbd3734bf89d0a56d94410f808 rdf:first sg:person.011235673125.19
92 rdf:rest N77ca30e857834440b72dc86cdb2ed2b5
93 Nb5248b1c133b495884dea12964adf766 schema:name doi
94 schema:value 10.1007/s10582-006-1057-7
95 rdf:type schema:PropertyValue
96 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
97 schema:name Engineering
98 rdf:type schema:DefinedTerm
99 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
100 schema:name Materials Engineering
101 rdf:type schema:DefinedTerm
102 sg:journal.1297212 schema:issn 0011-4626
103 1572-9486
104 schema:name Czechoslovak Journal of Physics
105 schema:publisher Springer Nature
106 rdf:type schema:Periodical
107 sg:person.011235673125.19 schema:affiliation grid-institutes:grid.6652.7
108 schema:familyName Kameník
109 schema:givenName J.
110 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011235673125.19
111 rdf:type schema:Person
112 sg:person.014502716325.78 schema:affiliation grid-institutes:grid.6652.7
113 schema:familyName Šebesta
114 schema:givenName F.
115 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014502716325.78
116 rdf:type schema:Person
117 sg:pub.10.1007/978-94-011-4546-6_9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024819580
118 https://doi.org/10.1007/978-94-011-4546-6_9
119 rdf:type schema:CreativeWork
120 sg:pub.10.1007/bf02035352 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016301358
121 https://doi.org/10.1007/bf02035352
122 rdf:type schema:CreativeWork
123 sg:pub.10.1007/bf02060190 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006926858
124 https://doi.org/10.1007/bf02060190
125 rdf:type schema:CreativeWork
126 sg:pub.10.1007/bf02347462 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004517838
127 https://doi.org/10.1007/bf02347462
128 rdf:type schema:CreativeWork
129 sg:pub.10.1007/s10582-003-0076-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1029920699
130 https://doi.org/10.1007/s10582-003-0076-x
131 rdf:type schema:CreativeWork
132 sg:pub.10.1023/a:1020829228253 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041676095
133 https://doi.org/10.1023/a:1020829228253
134 rdf:type schema:CreativeWork
135 grid-institutes:grid.6652.7 schema:alternateName Centre for Radiochemistry and Radiation Chemistry, Czech Technical University, Břehová 7, CZ-115 19, Prague 1, Czech Republic
136 Department of Nuclear Chemistry, Czech Technical University, Břehová 7, CZ-115 19, Prague 1, Czech Republic
137 schema:name Centre for Radiochemistry and Radiation Chemistry, Czech Technical University, Břehová 7, CZ-115 19, Prague 1, Czech Republic
138 Department of Nuclear Chemistry, Czech Technical University, Břehová 7, CZ-115 19, Prague 1, Czech Republic
139 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...