TPE/REE separation with the use of zirconium salt of HDBP View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2003-01

AUTHORS

R. G. Glekov, O. V. Shmidt, Yu. V. Palenik, N. D. Goletsky, S. Yu. Sukhareva, Yu. S. Fedorov, B. Ya. Zilberman

ABSTRACT

Partitioning of long-lived radionuclides (minor actinides, fission products) is considered as TBP-compatible ZEALEX-process for extraction separation of transplutonium elements (TPE) and rare-earth elements (REE), as well as Y, Mo, Fe and residual amounts of Np, Pu, U. Zirconium salt of dibutyl phosphoric acid (ZS-HDBP) dissolved in 30 % TBP is used as a solvent. The process was tested in multistage centrifugal contactors. Lanthanides, Y and TPE, as well as Mo, Fe were extracted from high-level Purex raffinate, Am and ceric subgroup of REE being separated from the polyvalent elements by stripping with HNO3. TPE/REE partitioning was achieved in the second cycle of the ZEALEX-process using DTPA in formic acid media. The integral decontamination factor of Am from La and Ce after both cycles is >200, from Pr and Nd 20–30 and from Sm and Eu 3.6; REE strips in both cycles contained <0,1% of the initial amount of TPE. More... »

PAGES

a595-a601

References to SciGraph publications

Journal

TITLE

Czechoslovak Journal of Physics

ISSUE

Suppl 1

VOLUME

53

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10582-003-0077-9

DOI

http://dx.doi.org/10.1007/s10582-003-0077-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1013204418


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