Extraction of transplutionium and rare-earth elements, molybdenum and iron with zirconium salt of dibutyl phosphoric acid View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2003-01

AUTHORS

B. Ya. Zilberman, Yu. S. Fedorov, O. V. Shmidt, N. D. Goletsky, S. Yu. Sukhareva, E. A. Puzikov, D. N. Suglobov, L. G. Mashirov, G. R. Choppin

ABSTRACT

Zirconium salt of dibutyl phosphoric acid (ZS-HDBP) dissolved in dilute tributyl phosphate (TBP) is proposed as a solvent for separation of transplutonium and rare-earth elements (TPE, RE), including yttrium, from high-level waste in the presence of molybdenum and iron. The optimum HDBP:Zr ratio is 9 for RE and TPE extraction and is 12.5 for Mo. IR spectra indicate formation of Zr(DBP)4(HDBP)4 complex as a base of solvation. HNO3 depresses RE and TPE extraction, while Mo extraction is characterised by a minimum at 2.5 mol/L HNO3. Presence of TBP in the solvent, independently of the used diluent, leads to reduction of the distribution coefficients, but ZS-HDBP extraction capacity for the above elements is increased, as well as solubility of their solvates. Two types of complexes M(DBP)3 and MNO3(DBP)2 are formed at RE and TPE extraction by ZS-HDBP in dilute TBP. Molybdenum extraction is based both on cation exchange and on Mo solvation with HDBP as a neutral ligand. Iron extraction is formally similar to that of Mo, being influenced by the latter if both metals are present in the solution. More... »

PAGES

a479-a486

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10582-003-0061-4

DOI

http://dx.doi.org/10.1007/s10582-003-0061-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1025828421


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "V. G. Khlopin Radium Institute", 
          "id": "https://www.grid.ac/institutes/grid.470918.3", 
          "name": [
            "V.G. Khlopin Radium Institute, 2nd Murinsky av. 28, 194021, Saint Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zilberman", 
        "givenName": "B. Ya.", 
        "id": "sg:person.012370647407.23", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012370647407.23"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "V. G. Khlopin Radium Institute", 
          "id": "https://www.grid.ac/institutes/grid.470918.3", 
          "name": [
            "V.G. Khlopin Radium Institute, 2nd Murinsky av. 28, 194021, Saint Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Fedorov", 
        "givenName": "Yu. S.", 
        "id": "sg:person.010634570235.31", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010634570235.31"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "V. G. Khlopin Radium Institute", 
          "id": "https://www.grid.ac/institutes/grid.470918.3", 
          "name": [
            "V.G. Khlopin Radium Institute, 2nd Murinsky av. 28, 194021, Saint Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shmidt", 
        "givenName": "O. V.", 
        "id": "sg:person.010662354427.70", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010662354427.70"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "V. G. Khlopin Radium Institute", 
          "id": "https://www.grid.ac/institutes/grid.470918.3", 
          "name": [
            "V.G. Khlopin Radium Institute, 2nd Murinsky av. 28, 194021, Saint Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Goletsky", 
        "givenName": "N. D.", 
        "id": "sg:person.010701106742.97", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010701106742.97"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "V. G. Khlopin Radium Institute", 
          "id": "https://www.grid.ac/institutes/grid.470918.3", 
          "name": [
            "V.G. Khlopin Radium Institute, 2nd Murinsky av. 28, 194021, Saint Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sukhareva", 
        "givenName": "S. Yu.", 
        "id": "sg:person.012601153071.81", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012601153071.81"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "V. G. Khlopin Radium Institute", 
          "id": "https://www.grid.ac/institutes/grid.470918.3", 
          "name": [
            "V.G. Khlopin Radium Institute, 2nd Murinsky av. 28, 194021, Saint Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Puzikov", 
        "givenName": "E. A.", 
        "id": "sg:person.015166227313.94", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015166227313.94"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "V. G. Khlopin Radium Institute", 
          "id": "https://www.grid.ac/institutes/grid.470918.3", 
          "name": [
            "V.G. Khlopin Radium Institute, 2nd Murinsky av. 28, 194021, Saint Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Suglobov", 
        "givenName": "D. N.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "V. G. Khlopin Radium Institute", 
          "id": "https://www.grid.ac/institutes/grid.470918.3", 
          "name": [
            "V.G. Khlopin Radium Institute, 2nd Murinsky av. 28, 194021, Saint Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mashirov", 
        "givenName": "L. G.", 
        "id": "sg:person.011624614633.02", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011624614633.02"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Florida State University", 
          "id": "https://www.grid.ac/institutes/grid.255986.5", 
          "name": [
            "Florida State University, 32306-4390, Tallahassee, Florida, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Choppin", 
        "givenName": "G. R.", 
        "id": "sg:person.07463223743.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07463223743.10"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/0022-1902(73)80142-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000264137"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-1902(73)80142-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000264137"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-1902(68)80089-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002911616"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-1902(68)80089-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002911616"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/07366299108918085", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024526844"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00473354", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029593490", 
          "https://doi.org/10.1007/bf00473354"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00473354", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029593490", 
          "https://doi.org/10.1007/bf00473354"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2003-01", 
    "datePublishedReg": "2003-01-01", 
    "description": "Zirconium salt of dibutyl phosphoric acid (ZS-HDBP) dissolved in dilute tributyl phosphate (TBP) is proposed as a solvent for separation of transplutonium and rare-earth elements (TPE, RE), including yttrium, from high-level waste in the presence of molybdenum and iron. The optimum HDBP:Zr ratio is 9 for RE and TPE extraction and is 12.5 for Mo. IR spectra indicate formation of Zr(DBP)4(HDBP)4 complex as a base of solvation. HNO3 depresses RE and TPE extraction, while Mo extraction is characterised by a minimum at 2.5 mol/L HNO3. Presence of TBP in the solvent, independently of the used diluent, leads to reduction of the distribution coefficients, but ZS-HDBP extraction capacity for the above elements is increased, as well as solubility of their solvates. Two types of complexes M(DBP)3 and MNO3(DBP)2 are formed at RE and TPE extraction by ZS-HDBP in dilute TBP. Molybdenum extraction is based both on cation exchange and on Mo solvation with HDBP as a neutral ligand. Iron extraction is formally similar to that of Mo, being influenced by the latter if both metals are present in the solution.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s10582-003-0061-4", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1297212", 
        "issn": [
          "0011-4626", 
          "1572-9486"
        ], 
        "name": "Czechoslovak Journal of Physics", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "Suppl 1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "53"
      }
    ], 
    "name": "Extraction of transplutionium and rare-earth elements, molybdenum and iron with zirconium salt of dibutyl phosphoric acid", 
    "pagination": "a479-a486", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "7b0d10b1ed20fea06758f6bcbdf24d9a78d77c5bdf2f91900226f4fd6241847a"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10582-003-0061-4"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1025828421"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10582-003-0061-4", 
      "https://app.dimensions.ai/details/publication/pub.1025828421"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T14:32", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000373_0000000373/records_13099_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/s10582-003-0061-4"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10582-003-0061-4'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10582-003-0061-4'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10582-003-0061-4'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10582-003-0061-4'


 

This table displays all metadata directly associated to this object as RDF triples.

132 TRIPLES      21 PREDICATES      31 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10582-003-0061-4 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N067fbd18fbea46f6a735bae41d0624cb
4 schema:citation sg:pub.10.1007/bf00473354
5 https://doi.org/10.1016/0022-1902(68)80089-2
6 https://doi.org/10.1016/0022-1902(73)80142-3
7 https://doi.org/10.1080/07366299108918085
8 schema:datePublished 2003-01
9 schema:datePublishedReg 2003-01-01
10 schema:description Zirconium salt of dibutyl phosphoric acid (ZS-HDBP) dissolved in dilute tributyl phosphate (TBP) is proposed as a solvent for separation of transplutonium and rare-earth elements (TPE, RE), including yttrium, from high-level waste in the presence of molybdenum and iron. The optimum HDBP:Zr ratio is 9 for RE and TPE extraction and is 12.5 for Mo. IR spectra indicate formation of Zr(DBP)4(HDBP)4 complex as a base of solvation. HNO3 depresses RE and TPE extraction, while Mo extraction is characterised by a minimum at 2.5 mol/L HNO3. Presence of TBP in the solvent, independently of the used diluent, leads to reduction of the distribution coefficients, but ZS-HDBP extraction capacity for the above elements is increased, as well as solubility of their solvates. Two types of complexes M(DBP)3 and MNO3(DBP)2 are formed at RE and TPE extraction by ZS-HDBP in dilute TBP. Molybdenum extraction is based both on cation exchange and on Mo solvation with HDBP as a neutral ligand. Iron extraction is formally similar to that of Mo, being influenced by the latter if both metals are present in the solution.
11 schema:genre research_article
12 schema:inLanguage en
13 schema:isAccessibleForFree false
14 schema:isPartOf N79c3d12aaca0415ca77afe15ba389fb4
15 N91091857457f4378beac63db778837c0
16 sg:journal.1297212
17 schema:name Extraction of transplutionium and rare-earth elements, molybdenum and iron with zirconium salt of dibutyl phosphoric acid
18 schema:pagination a479-a486
19 schema:productId N0994ba4fb4fb43fc97018e1f7914de50
20 Ne47a680640a64c579ff3339a20ed18a5
21 Nfb23543f18f34fdeb1ab7b8f174d6637
22 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025828421
23 https://doi.org/10.1007/s10582-003-0061-4
24 schema:sdDatePublished 2019-04-11T14:32
25 schema:sdLicense https://scigraph.springernature.com/explorer/license/
26 schema:sdPublisher Ne4611850ec454ac298be0d3854d9feaf
27 schema:url http://link.springer.com/10.1007/s10582-003-0061-4
28 sgo:license sg:explorer/license/
29 sgo:sdDataset articles
30 rdf:type schema:ScholarlyArticle
31 N067fbd18fbea46f6a735bae41d0624cb rdf:first sg:person.012370647407.23
32 rdf:rest N356c66660f8d49c0b440836d5636123b
33 N0994ba4fb4fb43fc97018e1f7914de50 schema:name dimensions_id
34 schema:value pub.1025828421
35 rdf:type schema:PropertyValue
36 N333748db731d4e2cbfb675731bdf2f14 rdf:first sg:person.010701106742.97
37 rdf:rest Nf2a5cc895e43496296c3d1ec060a3d28
38 N356c66660f8d49c0b440836d5636123b rdf:first sg:person.010634570235.31
39 rdf:rest Neef1afa11229445ba0eaa0726c6108b8
40 N64453b87f1704b00b788b91dd9e61e79 schema:affiliation https://www.grid.ac/institutes/grid.470918.3
41 schema:familyName Suglobov
42 schema:givenName D. N.
43 rdf:type schema:Person
44 N79c3d12aaca0415ca77afe15ba389fb4 schema:issueNumber Suppl 1
45 rdf:type schema:PublicationIssue
46 N8f0b2ea9daf44428b911de63dc0a2702 rdf:first sg:person.011624614633.02
47 rdf:rest N92524189ec0f482f9dc3a0047e1e463c
48 N91091857457f4378beac63db778837c0 schema:volumeNumber 53
49 rdf:type schema:PublicationVolume
50 N92524189ec0f482f9dc3a0047e1e463c rdf:first sg:person.07463223743.10
51 rdf:rest rdf:nil
52 Na1204660f85242a288d5f5d635ec98ba rdf:first N64453b87f1704b00b788b91dd9e61e79
53 rdf:rest N8f0b2ea9daf44428b911de63dc0a2702
54 Nc90f2ced1ebf42339fb20a4d608f9153 rdf:first sg:person.015166227313.94
55 rdf:rest Na1204660f85242a288d5f5d635ec98ba
56 Ne4611850ec454ac298be0d3854d9feaf schema:name Springer Nature - SN SciGraph project
57 rdf:type schema:Organization
58 Ne47a680640a64c579ff3339a20ed18a5 schema:name readcube_id
59 schema:value 7b0d10b1ed20fea06758f6bcbdf24d9a78d77c5bdf2f91900226f4fd6241847a
60 rdf:type schema:PropertyValue
61 Neef1afa11229445ba0eaa0726c6108b8 rdf:first sg:person.010662354427.70
62 rdf:rest N333748db731d4e2cbfb675731bdf2f14
63 Nf2a5cc895e43496296c3d1ec060a3d28 rdf:first sg:person.012601153071.81
64 rdf:rest Nc90f2ced1ebf42339fb20a4d608f9153
65 Nfb23543f18f34fdeb1ab7b8f174d6637 schema:name doi
66 schema:value 10.1007/s10582-003-0061-4
67 rdf:type schema:PropertyValue
68 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
69 schema:name Chemical Sciences
70 rdf:type schema:DefinedTerm
71 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
72 schema:name Inorganic Chemistry
73 rdf:type schema:DefinedTerm
74 sg:journal.1297212 schema:issn 0011-4626
75 1572-9486
76 schema:name Czechoslovak Journal of Physics
77 rdf:type schema:Periodical
78 sg:person.010634570235.31 schema:affiliation https://www.grid.ac/institutes/grid.470918.3
79 schema:familyName Fedorov
80 schema:givenName Yu. S.
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010634570235.31
82 rdf:type schema:Person
83 sg:person.010662354427.70 schema:affiliation https://www.grid.ac/institutes/grid.470918.3
84 schema:familyName Shmidt
85 schema:givenName O. V.
86 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010662354427.70
87 rdf:type schema:Person
88 sg:person.010701106742.97 schema:affiliation https://www.grid.ac/institutes/grid.470918.3
89 schema:familyName Goletsky
90 schema:givenName N. D.
91 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010701106742.97
92 rdf:type schema:Person
93 sg:person.011624614633.02 schema:affiliation https://www.grid.ac/institutes/grid.470918.3
94 schema:familyName Mashirov
95 schema:givenName L. G.
96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011624614633.02
97 rdf:type schema:Person
98 sg:person.012370647407.23 schema:affiliation https://www.grid.ac/institutes/grid.470918.3
99 schema:familyName Zilberman
100 schema:givenName B. Ya.
101 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012370647407.23
102 rdf:type schema:Person
103 sg:person.012601153071.81 schema:affiliation https://www.grid.ac/institutes/grid.470918.3
104 schema:familyName Sukhareva
105 schema:givenName S. Yu.
106 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012601153071.81
107 rdf:type schema:Person
108 sg:person.015166227313.94 schema:affiliation https://www.grid.ac/institutes/grid.470918.3
109 schema:familyName Puzikov
110 schema:givenName E. A.
111 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015166227313.94
112 rdf:type schema:Person
113 sg:person.07463223743.10 schema:affiliation https://www.grid.ac/institutes/grid.255986.5
114 schema:familyName Choppin
115 schema:givenName G. R.
116 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07463223743.10
117 rdf:type schema:Person
118 sg:pub.10.1007/bf00473354 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029593490
119 https://doi.org/10.1007/bf00473354
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1016/0022-1902(68)80089-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002911616
122 rdf:type schema:CreativeWork
123 https://doi.org/10.1016/0022-1902(73)80142-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000264137
124 rdf:type schema:CreativeWork
125 https://doi.org/10.1080/07366299108918085 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024526844
126 rdf:type schema:CreativeWork
127 https://www.grid.ac/institutes/grid.255986.5 schema:alternateName Florida State University
128 schema:name Florida State University, 32306-4390, Tallahassee, Florida, USA
129 rdf:type schema:Organization
130 https://www.grid.ac/institutes/grid.470918.3 schema:alternateName V. G. Khlopin Radium Institute
131 schema:name V.G. Khlopin Radium Institute, 2nd Murinsky av. 28, 194021, Saint Petersburg, Russia
132 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...