Criteria of the Critical State of the Ni—Al System during Mechanical Activation View Full Text


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Article Info

DATE

2010-07

AUTHORS

D. Yu. Kovalev, N. A. Kochetov, V. I. Ponomarev

ABSTRACT

The influence of mechanical activation on the structural state and reactivity of a Ni—Al powder mixture is studied. Mechanical activation of the Ni—Al mixture is demonstrated to have an induction period that involves accumulation of deformation defects of the crystal structure of the species; the NiAl phase of the reaction product is not yet registered in this period. Partial amorphization of aluminum increasing the system reactivity is revealed. Based on results of a diffraction analysis, a quantitative criterion of the state of the species during their activation is proposed: the value of stresses of the second kind. The system becomes unstable and autogenerates a synthesis reaction when microstresses are accumulated in the initial material to the level of the yield stress of the corresponding substance. More... »

PAGES

457-463

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10573-010-0060-2

DOI

http://dx.doi.org/10.1007/s10573-010-0060-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033081965


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