Study of the CL-20 flame structure using probing molecular beam mass spectrometry View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-05

AUTHORS

A. A. Paletsky, A. G. Tereshchenko, E. N. Volkov, O. P. Korobeinichev, G. V. Sakovich, V. F. Komarov, V. A. Shandakov

ABSTRACT

The CL-20 flame structure at pressures of 0.1 and 0.5 MPa was studied using probing molecular beam mass spectrometry. At a pressure of 0.1 MPa, the gaseous products near the surface of the foamy carbonaceous carcass were found to contain eight species: NO, NO2, CO, CO2, N2, H2O, HCN, and HNCO. At a pressure of 0.5 MPa, NO2 was not found and the concentration profiles of the remaining seven species were measured versus the distance to the carbonaceous carcass. In the CL-20 flame at a pressure of 0.5 MPa, consumption of N2 and CO2 with the formation of NO and HNCO occurred in a zone of width ≈0.8 mm from the surface of the carbonaceous carcass. At a pressure of 0.5 MPa, the composition of the gaseous combustion products of CL-20 at a distance of 3–4 mm differed from the composition at thermodynamic equilibrium. Key words: flame structure, CL-20, probing molecular beam mass spectrometry. More... »

PAGES

286-292

References to SciGraph publications

  • 2003. Studies on CL-20: The most powerful high energy material in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2005-03. Hexanitrohexaazaisowurtzitane (CL-20) and CL-20-based formulations (review) in COMBUSTION, EXPLOSION, AND SHOCK WAVES
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s10573-009-0038-0

    DOI

    http://dx.doi.org/10.1007/s10573-009-0038-0

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1035849369


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Engineering", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0904", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Engineering", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0913", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Mechanical Engineering", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Institute of Chemical Kinetics and Combustion, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia", 
              "id": "http://www.grid.ac/institutes/grid.415877.8", 
              "name": [
                "Institute of Chemical Kinetics and Combustion, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Paletsky", 
            "givenName": "A. A.", 
            "id": "sg:person.011225506145.26", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011225506145.26"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Institute of Chemical Kinetics and Combustion, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia", 
              "id": "http://www.grid.ac/institutes/grid.415877.8", 
              "name": [
                "Institute of Chemical Kinetics and Combustion, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Tereshchenko", 
            "givenName": "A. G.", 
            "id": "sg:person.012113244673.58", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012113244673.58"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Institute of Chemical Kinetics and Combustion, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia", 
              "id": "http://www.grid.ac/institutes/grid.415877.8", 
              "name": [
                "Institute of Chemical Kinetics and Combustion, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Volkov", 
            "givenName": "E. N.", 
            "id": "sg:person.010463030253.79", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010463030253.79"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Novosibirsk State University, 630090, Novosibirsk, Russia", 
              "id": "http://www.grid.ac/institutes/grid.4605.7", 
              "name": [
                "Institute of Chemical Kinetics and Combustion, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia", 
                "Novosibirsk State University, 630090, Novosibirsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Korobeinichev", 
            "givenName": "O. P.", 
            "id": "sg:person.012337071637.17", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012337071637.17"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Institute of Problems of Chemical-Engineering Technologies, Siberian Division, Russian Academy of Sciences, 659322, Biisk, Russia", 
              "id": "http://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "Institute of Problems of Chemical-Engineering Technologies, Siberian Division, Russian Academy of Sciences, 659322, Biisk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Sakovich", 
            "givenName": "G. V.", 
            "id": "sg:person.07523164533.19", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07523164533.19"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Institute of Problems of Chemical-Engineering Technologies, Siberian Division, Russian Academy of Sciences, 659322, Biisk, Russia", 
              "id": "http://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "Institute of Problems of Chemical-Engineering Technologies, Siberian Division, Russian Academy of Sciences, 659322, Biisk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Komarov", 
            "givenName": "V. F.", 
            "id": "sg:person.01154077725.84", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01154077725.84"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Altai Federal Research-and-Production Center, 659322, Biisk, Russia", 
              "id": "http://www.grid.ac/institutes/None", 
              "name": [
                "Altai Federal Research-and-Production Center, 659322, Biisk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Shandakov", 
            "givenName": "V. A.", 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1023/a:1025859203860", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1037709595", 
              "https://doi.org/10.1023/a:1025859203860"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s10573-005-0014-2", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1005257258", 
              "https://doi.org/10.1007/s10573-005-0014-2"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2009-05", 
        "datePublishedReg": "2009-05-01", 
        "description": "The CL-20 flame structure at pressures of 0.1 and 0.5 MPa was studied using probing molecular beam mass spectrometry. At a pressure of 0.1 MPa, the gaseous products near the surface of the foamy carbonaceous carcass were found to contain eight species: NO, NO2, CO, CO2, N2, H2O, HCN, and HNCO. At a pressure of 0.5 MPa, NO2 was not found and the concentration profiles of the remaining seven species were measured versus the distance to the carbonaceous carcass. In the CL-20 flame at a pressure of 0.5 MPa, consumption of N2 and CO2 with the formation of NO and HNCO occurred in a zone of width \u22480.8 mm from the surface of the carbonaceous carcass. At a pressure of 0.5 MPa, the composition of the gaseous combustion products of CL-20 at a distance of 3\u20134 mm differed from the composition at thermodynamic equilibrium. Key words: flame structure, CL-20, probing molecular beam mass spectrometry.", 
        "genre": "article", 
        "id": "sg:pub.10.1007/s10573-009-0038-0", 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1049027", 
            "issn": [
              "0010-5082", 
              "1573-8345"
            ], 
            "name": "Combustion, Explosion, and Shock Waves", 
            "publisher": "Springer Nature", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "3", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "45"
          }
        ], 
        "keywords": [
          "flame structure", 
          "gaseous combustion products", 
          "molecular beam mass spectrometry", 
          "zone of width", 
          "combustion products", 
          "CL-20", 
          "MPa", 
          "gaseous products", 
          "beam mass spectrometry", 
          "concentration profiles", 
          "formation of NO", 
          "mass spectrometry", 
          "surface", 
          "thermodynamic equilibrium", 
          "flame", 
          "CO2", 
          "pressure", 
          "N2", 
          "structure", 
          "NO2", 
          "spectrometry", 
          "width", 
          "composition", 
          "CO", 
          "HNCO", 
          "products", 
          "distance", 
          "zone", 
          "consumption", 
          "H2O", 
          "species", 
          "formation", 
          "NO", 
          "equilibrium", 
          "HCN", 
          "profile", 
          "carcasses", 
          "study"
        ], 
        "name": "Study of the CL-20 flame structure using probing molecular beam mass spectrometry", 
        "pagination": "286-292", 
        "productId": [
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1035849369"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/s10573-009-0038-0"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/s10573-009-0038-0", 
          "https://app.dimensions.ai/details/publication/pub.1035849369"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2022-12-01T06:27", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-springernature-scigraph/baseset/20221201/entities/gbq_results/article/article_484.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "https://doi.org/10.1007/s10573-009-0038-0"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10573-009-0038-0'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10573-009-0038-0'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10573-009-0038-0'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10573-009-0038-0'


     

    This table displays all metadata directly associated to this object as RDF triples.

    158 TRIPLES      21 PREDICATES      66 URIs      55 LITERALS      6 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/s10573-009-0038-0 schema:about anzsrc-for:09
    2 anzsrc-for:0904
    3 anzsrc-for:0913
    4 schema:author Na22fac9e7e454539a86ef3da142c6336
    5 schema:citation sg:pub.10.1007/s10573-005-0014-2
    6 sg:pub.10.1023/a:1025859203860
    7 schema:datePublished 2009-05
    8 schema:datePublishedReg 2009-05-01
    9 schema:description The CL-20 flame structure at pressures of 0.1 and 0.5 MPa was studied using probing molecular beam mass spectrometry. At a pressure of 0.1 MPa, the gaseous products near the surface of the foamy carbonaceous carcass were found to contain eight species: NO, NO2, CO, CO2, N2, H2O, HCN, and HNCO. At a pressure of 0.5 MPa, NO2 was not found and the concentration profiles of the remaining seven species were measured versus the distance to the carbonaceous carcass. In the CL-20 flame at a pressure of 0.5 MPa, consumption of N2 and CO2 with the formation of NO and HNCO occurred in a zone of width ≈0.8 mm from the surface of the carbonaceous carcass. At a pressure of 0.5 MPa, the composition of the gaseous combustion products of CL-20 at a distance of 3–4 mm differed from the composition at thermodynamic equilibrium. Key words: flame structure, CL-20, probing molecular beam mass spectrometry.
    10 schema:genre article
    11 schema:isAccessibleForFree false
    12 schema:isPartOf N076b4d566d9a47a58b8e0166db8ef0d2
    13 N35f3deb15d4840089d0aaf44399be5c8
    14 sg:journal.1049027
    15 schema:keywords CL-20
    16 CO
    17 CO2
    18 H2O
    19 HCN
    20 HNCO
    21 MPa
    22 N2
    23 NO
    24 NO2
    25 beam mass spectrometry
    26 carcasses
    27 combustion products
    28 composition
    29 concentration profiles
    30 consumption
    31 distance
    32 equilibrium
    33 flame
    34 flame structure
    35 formation
    36 formation of NO
    37 gaseous combustion products
    38 gaseous products
    39 mass spectrometry
    40 molecular beam mass spectrometry
    41 pressure
    42 products
    43 profile
    44 species
    45 spectrometry
    46 structure
    47 study
    48 surface
    49 thermodynamic equilibrium
    50 width
    51 zone
    52 zone of width
    53 schema:name Study of the CL-20 flame structure using probing molecular beam mass spectrometry
    54 schema:pagination 286-292
    55 schema:productId N9b9a57f3360c41af84b5fd64f25164e5
    56 Na38540ec603a49b4b061768022fe385d
    57 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035849369
    58 https://doi.org/10.1007/s10573-009-0038-0
    59 schema:sdDatePublished 2022-12-01T06:27
    60 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    61 schema:sdPublisher Nb20c98e195884637a1f2e77782d9e986
    62 schema:url https://doi.org/10.1007/s10573-009-0038-0
    63 sgo:license sg:explorer/license/
    64 sgo:sdDataset articles
    65 rdf:type schema:ScholarlyArticle
    66 N076b4d566d9a47a58b8e0166db8ef0d2 schema:issueNumber 3
    67 rdf:type schema:PublicationIssue
    68 N2e0daf7b41de4e3e8a1b802d5f2977d9 rdf:first sg:person.07523164533.19
    69 rdf:rest Ne9a08b397ef7449dbefa8eb03abc466e
    70 N35f3deb15d4840089d0aaf44399be5c8 schema:volumeNumber 45
    71 rdf:type schema:PublicationVolume
    72 N37e12e47f4464d98bb34971db6ed7578 schema:affiliation grid-institutes:None
    73 schema:familyName Shandakov
    74 schema:givenName V. A.
    75 rdf:type schema:Person
    76 N5ca810c428934b398e67fe9547d2fffb rdf:first sg:person.012337071637.17
    77 rdf:rest N2e0daf7b41de4e3e8a1b802d5f2977d9
    78 N9b9a57f3360c41af84b5fd64f25164e5 schema:name dimensions_id
    79 schema:value pub.1035849369
    80 rdf:type schema:PropertyValue
    81 N9da74565e65f421d8a5b0f9883ef6176 rdf:first N37e12e47f4464d98bb34971db6ed7578
    82 rdf:rest rdf:nil
    83 Na22fac9e7e454539a86ef3da142c6336 rdf:first sg:person.011225506145.26
    84 rdf:rest Nf227ab36ab3e4d88b486a6f39baa4be9
    85 Na38540ec603a49b4b061768022fe385d schema:name doi
    86 schema:value 10.1007/s10573-009-0038-0
    87 rdf:type schema:PropertyValue
    88 Nb20c98e195884637a1f2e77782d9e986 schema:name Springer Nature - SN SciGraph project
    89 rdf:type schema:Organization
    90 Nd50718e130c64f1b84855a818305d148 rdf:first sg:person.010463030253.79
    91 rdf:rest N5ca810c428934b398e67fe9547d2fffb
    92 Ne9a08b397ef7449dbefa8eb03abc466e rdf:first sg:person.01154077725.84
    93 rdf:rest N9da74565e65f421d8a5b0f9883ef6176
    94 Nf227ab36ab3e4d88b486a6f39baa4be9 rdf:first sg:person.012113244673.58
    95 rdf:rest Nd50718e130c64f1b84855a818305d148
    96 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
    97 schema:name Engineering
    98 rdf:type schema:DefinedTerm
    99 anzsrc-for:0904 schema:inDefinedTermSet anzsrc-for:
    100 schema:name Chemical Engineering
    101 rdf:type schema:DefinedTerm
    102 anzsrc-for:0913 schema:inDefinedTermSet anzsrc-for:
    103 schema:name Mechanical Engineering
    104 rdf:type schema:DefinedTerm
    105 sg:journal.1049027 schema:issn 0010-5082
    106 1573-8345
    107 schema:name Combustion, Explosion, and Shock Waves
    108 schema:publisher Springer Nature
    109 rdf:type schema:Periodical
    110 sg:person.010463030253.79 schema:affiliation grid-institutes:grid.415877.8
    111 schema:familyName Volkov
    112 schema:givenName E. N.
    113 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010463030253.79
    114 rdf:type schema:Person
    115 sg:person.011225506145.26 schema:affiliation grid-institutes:grid.415877.8
    116 schema:familyName Paletsky
    117 schema:givenName A. A.
    118 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011225506145.26
    119 rdf:type schema:Person
    120 sg:person.01154077725.84 schema:affiliation grid-institutes:grid.4886.2
    121 schema:familyName Komarov
    122 schema:givenName V. F.
    123 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01154077725.84
    124 rdf:type schema:Person
    125 sg:person.012113244673.58 schema:affiliation grid-institutes:grid.415877.8
    126 schema:familyName Tereshchenko
    127 schema:givenName A. G.
    128 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012113244673.58
    129 rdf:type schema:Person
    130 sg:person.012337071637.17 schema:affiliation grid-institutes:grid.4605.7
    131 schema:familyName Korobeinichev
    132 schema:givenName O. P.
    133 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012337071637.17
    134 rdf:type schema:Person
    135 sg:person.07523164533.19 schema:affiliation grid-institutes:grid.4886.2
    136 schema:familyName Sakovich
    137 schema:givenName G. V.
    138 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07523164533.19
    139 rdf:type schema:Person
    140 sg:pub.10.1007/s10573-005-0014-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005257258
    141 https://doi.org/10.1007/s10573-005-0014-2
    142 rdf:type schema:CreativeWork
    143 sg:pub.10.1023/a:1025859203860 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037709595
    144 https://doi.org/10.1023/a:1025859203860
    145 rdf:type schema:CreativeWork
    146 grid-institutes:None schema:alternateName Altai Federal Research-and-Production Center, 659322, Biisk, Russia
    147 schema:name Altai Federal Research-and-Production Center, 659322, Biisk, Russia
    148 rdf:type schema:Organization
    149 grid-institutes:grid.415877.8 schema:alternateName Institute of Chemical Kinetics and Combustion, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia
    150 schema:name Institute of Chemical Kinetics and Combustion, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia
    151 rdf:type schema:Organization
    152 grid-institutes:grid.4605.7 schema:alternateName Novosibirsk State University, 630090, Novosibirsk, Russia
    153 schema:name Institute of Chemical Kinetics and Combustion, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia
    154 Novosibirsk State University, 630090, Novosibirsk, Russia
    155 rdf:type schema:Organization
    156 grid-institutes:grid.4886.2 schema:alternateName Institute of Problems of Chemical-Engineering Technologies, Siberian Division, Russian Academy of Sciences, 659322, Biisk, Russia
    157 schema:name Institute of Problems of Chemical-Engineering Technologies, Siberian Division, Russian Academy of Sciences, 659322, Biisk, Russia
    158 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...