Cellulose nanosheets formed by mild additive-free ball milling View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-03

AUTHORS

Yunxiu Zhang, Shigenori Kuga, Min Wu, Yong Huang

ABSTRACT

Cellulose nanosheets similar to those obtained by milling with silicone oil (Zhao et al. in Cellulose 23:2809–2818, 2016) were obtained by mild additive-free milling followed by dispersion in ethanol. Typical nanosheets were of 4 nm thickness, possibly formed by monolayer association of elementary fibrils. The thickness decreased with prolonged milling to 2 nm or less, and the thinnest sheets observed were about 0.4 nm, corresponding to monomolecular layer of cellulose. Further milling caused disappearance of nanosheets due to complete decrystallization. This observation indicates that nanosheet formation is an intermediate stage of decrystallization of cellulose. More... »

PAGES

1-11

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10570-019-02282-7

DOI

http://dx.doi.org/10.1007/s10570-019-02282-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1112038874


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43 schema:description Cellulose nanosheets similar to those obtained by milling with silicone oil (Zhao et al. in Cellulose 23:2809–2818, 2016) were obtained by mild additive-free milling followed by dispersion in ethanol. Typical nanosheets were of 4 nm thickness, possibly formed by monolayer association of elementary fibrils. The thickness decreased with prolonged milling to 2 nm or less, and the thinnest sheets observed were about 0.4 nm, corresponding to monomolecular layer of cellulose. Further milling caused disappearance of nanosheets due to complete decrystallization. This observation indicates that nanosheet formation is an intermediate stage of decrystallization of cellulose.
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