Ontology type: schema:ScholarlyArticle
2008-06
AUTHORSRoger Ibbett, Jim Taylor, K. Christian Schuster, Mike Cox
ABSTRACTThe uptake of solutions of sodium hydroxide by lyocell fibre results in a phenomenon in textiles described as swelling–shrinkage. The response of woven fabrics in a tensile stress–relaxation experiment shows two time-dependent processes, corresponding to different mechanisms of pressure development. Rapid diffusion has been assigned to osmotic swelling through the interconnected pore structure of the fibre (D = 6–15 × 10−12 m2/s), which is influenced by the extent of ionization of hydroxyl groups at the pore surfaces. A ratio for the cellulose and water dissociation constants (Kcell/Kw) of 70 provides best agreement with experimental data. A second slower diffusion process (D = 2–10 × 10−14 m2/s) is assigned to transport through the cellulose polymer structure, associated with the Na-cellulose transition. This can be modeled assuming an ion-exchange equilibrium, where the cellulose gel converts reversibly between compact hydrogen and expanded sodium forms, with K = 1.04 × 1014, in favour of the hydrogen form. The model successfully predicts the concentration dependence of the transition and the movement to higher concentration with external constraint. The slow diffusion process only becomes apparent at high alkali concentrations, as the pores in the fibre collapse due to the expansion of the gel. Continued gel-diffusion is only possible through the polymer phase, which then dominates over fast pore-diffusion. More... »
PAGES393-406
http://scigraph.springernature.com/pub.10.1007/s10570-007-9180-6
DOIhttp://dx.doi.org/10.1007/s10570-007-9180-6
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1009714666
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "University of Manchester",
"id": "https://www.grid.ac/institutes/grid.5379.8",
"name": [
"Christian Doppler Laboratory for Fibre and Textile Chemistry in Cellulosics, University of Manchester, School of Materials, Sackville Street, M601QD, Manchester, UK"
],
"type": "Organization"
},
"familyName": "Ibbett",
"givenName": "Roger",
"id": "sg:person.011607476155.52",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011607476155.52"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Lenzing (Austria)",
"id": "https://www.grid.ac/institutes/grid.425223.0",
"name": [
"Lenzing AG, 4860, Lenzing, Austria"
],
"type": "Organization"
},
"familyName": "Taylor",
"givenName": "Jim",
"id": "sg:person.010077720557.52",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010077720557.52"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Lenzing (Austria)",
"id": "https://www.grid.ac/institutes/grid.425223.0",
"name": [
"Lenzing AG, 4860, Lenzing, Austria"
],
"type": "Organization"
},
"familyName": "Schuster",
"givenName": "K. Christian",
"id": "sg:person.01211137007.40",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01211137007.40"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of Manchester",
"id": "https://www.grid.ac/institutes/grid.5379.8",
"name": [
"Christian Doppler Laboratory for Fibre and Textile Chemistry in Cellulosics, University of Manchester, School of Materials, Sackville Street, M601QD, Manchester, UK"
],
"type": "Organization"
},
"familyName": "Cox",
"givenName": "Mike",
"type": "Person"
}
],
"citation": [
{
"id": "https://doi.org/10.1002/masy.19940830123",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1000090244"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1108/eum0000000005780",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1001703148"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1023/a:1009249332222",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1002514402",
"https://doi.org/10.1023/a:1009249332222"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1080/19447022908661501",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1004352210"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/app.10256",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1007577373"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/pol.1959.1203713114",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1009817368"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/app.1987.070330314",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1011015780"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/app.1985.070300128",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1012889966"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0032-3861(93)90765-3",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1013803755"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0032-3861(93)90765-3",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1013803755"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/pol.1962.1205816613",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1017906184"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/app.1990.070410325",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1019062431"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1006/jtbi.1993.1115",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1019707974"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/app.1984.070291247",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1021276434"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0079-6700(01)00025-9",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1021416039"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s10570-006-9052-5",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1027832264",
"https://doi.org/10.1007/s10570-006-9052-5"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s10570-006-9052-5",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1027832264",
"https://doi.org/10.1007/s10570-006-9052-5"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.polymer.2006.12.034",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1034705011"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0032-3861(99)00502-9",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1035082841"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1098/rspa.1952.0162",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1035254732"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/app.1980.070251215",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1036935712"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s10570-004-2786-z",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1037878075",
"https://doi.org/10.1007/s10570-004-2786-z"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s10570-004-2786-z",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1037878075",
"https://doi.org/10.1007/s10570-004-2786-z"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0014-3057(02)00132-5",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1038410575"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/app.20648",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1040166178"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0032-3861(78)90027-7",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1045336119"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0032-3861(78)90027-7",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1045336119"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1080/19447023708658809",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1051665575"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/bm049409x",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055220235"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/bm049409x",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055220235"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja01146a042",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055773405"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ma00003a020",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056172363"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ma00003a021",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056172364"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1177/004051750107100212",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1063691743"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1177/004051750107100212",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1063691743"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1515/zpch-1934-16834",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1085335799"
],
"type": "CreativeWork"
}
],
"datePublished": "2008-06",
"datePublishedReg": "2008-06-01",
"description": "The uptake of solutions of sodium hydroxide by lyocell fibre results in a phenomenon in textiles described as swelling\u2013shrinkage. The response of woven fabrics in a tensile stress\u2013relaxation experiment shows two time-dependent processes, corresponding to different mechanisms of pressure development. Rapid diffusion has been assigned to osmotic swelling through the interconnected pore structure of the fibre (D = 6\u201315 \u00d7 10\u221212 m2/s), which is influenced by the extent of ionization of hydroxyl groups at the pore surfaces. A ratio for the cellulose and water dissociation constants (Kcell/Kw) of 70 provides best agreement with experimental data. A second slower diffusion process (D = 2\u201310 \u00d7 10\u221214 m2/s) is assigned to transport through the cellulose polymer structure, associated with the Na-cellulose transition. This can be modeled assuming an ion-exchange equilibrium, where the cellulose gel converts reversibly between compact hydrogen and expanded sodium forms, with K = 1.04 \u00d7 1014, in favour of the hydrogen form. The model successfully predicts the concentration dependence of the transition and the movement to higher concentration with external constraint. The slow diffusion process only becomes apparent at high alkali concentrations, as the pores in the fibre collapse due to the expansion of the gel. Continued gel-diffusion is only possible through the polymer phase, which then dominates over fast pore-diffusion.",
"genre": "research_article",
"id": "sg:pub.10.1007/s10570-007-9180-6",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1033767",
"issn": [
"0969-0239",
"1572-882X"
],
"name": "Cellulose",
"type": "Periodical"
},
{
"issueNumber": "3",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "15"
}
],
"name": "Interpretation of relaxation and swelling phenomena in lyocell regenerated cellulosic fibres and textiles associated with the uptake of solutions of sodium hydroxide",
"pagination": "393-406",
"productId": [
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"2e47960897d5169aedc1218989ce7ebefc32bf299559998889f7c068d28922d5"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/s10570-007-9180-6"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1009714666"
]
}
],
"sameAs": [
"https://doi.org/10.1007/s10570-007-9180-6",
"https://app.dimensions.ai/details/publication/pub.1009714666"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-11T14:25",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000373_0000000373/records_13068_00000000.jsonl",
"type": "ScholarlyArticle",
"url": "http://link.springer.com/10.1007/s10570-007-9180-6"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10570-007-9180-6'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10570-007-9180-6'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10570-007-9180-6'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10570-007-9180-6'
This table displays all metadata directly associated to this object as RDF triples.
177 TRIPLES
21 PREDICATES
57 URIs
19 LITERALS
7 BLANK NODES