Preparation of Betulone Via Betulin Oxidation Over Ru Nanoparticles Deposited on Graphitic Carbon Nitride View Full Text


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Article Info

DATE

2019-03

AUTHORS

N. D. Shcherban, P. Mäki-Arvela, A. Aho, S. А. Sergiienko, M. A. Skoryk, E. Kolobova, I. L. Simakova, K. Eränen, A. Smeds, J. Hemming, D. Yu. Murzin

ABSTRACT

Derivatives of betulin obtained by oxidation have broad pharmacological applications, demonstrating anti-inflammatory, antioxidant, hepatoprotective, and anticancer activity. Ru supported catalysts based on graphitic carbon nitride or N-doped carbon were prepared via a mild reduction of the initial Ru precursor with hydrazine. These catalysts along with Ru supported on carbon nanofibers and a mesoporous carbon support Sibunit were studied in catalytic oxidation of betulin. Ru/carbon nitride demonstrated catalytic activity in betulin oxidation higher than Ru/N-doped carbon (conversion of betulin up to ca. 70% and 30%, respectively). Selectivity to different oxidation products was dependent on the properties of the carbon supports. More... »

PAGES

1-10

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10562-018-02649-8

DOI

http://dx.doi.org/10.1007/s10562-018-02649-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1111498150


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