Influence of Chemical Composition on the Catalytic Activity of Small Bimetallic FeRu Nanoparticles for Fischer–Tropsch Syntheses View Full Text


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Article Info

DATE

2015-01

AUTHORS

Anca Meffre, Viacheslav Iablokov, Yizhi Xiang, Roland Barbosa, Pier Francesco Fazzini, Vinciane Kelsen, Norbert Kruse, Bruno Chaudret

ABSTRACT

FeRu nanoparticles were prepared according to an organometallic route using {Fe[N(Si(CH3)3)2]2}2 and (η4-1,5-cyclooctadiene)(η6-1,3,5-cyclooctatriene) ruthenium(0) Ru(COD)(COT) precursors followed by their insertion into a mesoporous MCF-17 support host. The resulting nanoparticles had a uniform size of approximately 2 nm, with a relative Ru amount of up to 33 at.%. Steady-state Fischer–Tropsch catalysis at 6 bar total pressure (H2/CO = 1:1) demonstrated light olefins production with a selectivity close to 50 % (ex. CO2) for catalysts with low Ru content (5 at.%). The selectivity pattern changed to long chain-paraffin production with increasing Ru amounts. These catalysts were also more active than those containing few Ru. X-ray photoelectron spectroscopy showed under-parity Ru amounts to effectively cover the surface of Fe nanoparticles. The nanoparticle distribution inside the MFC-17 host was characterized by microtomia/transmission electron microscopy. More... »

PAGES

373-379

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10562-014-1421-3

DOI

http://dx.doi.org/10.1007/s10562-014-1421-3

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1052352538


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Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10562-014-1421-3'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10562-014-1421-3'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10562-014-1421-3'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10562-014-1421-3'


 

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