Solvent-Free Aerobic Oxidation of Toluene over Metalloporphyrin/NHPI/CTAB: Synergy and Mechanism View Full Text


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Article Info

DATE

2013-10-12

AUTHORS

Wei Deng, Yan-ping Wan, Hui Jiang, Wei-Ping Luo, Ze Tan, Qing Jiang, Can-Cheng Guo

ABSTRACT

The solvent-free catalytic oxidation of toluene using molecular oxygen over metalloporphyrin/N-hydroxyphthalimide (NHPI)/cetyl trimethyl ammonium bromide (CTAB) has been developed. The results showed that the type of metalloporphyrin used, catalyst loading, reaction temperature, and the flow rate of oxygen all influenced the conversion of toluene and the selectivities of the products. Furthermore, a co-catalysis was observed between metalloporphyrin, NHPI, and CTAB. The toluene conversion was significantly improved from 10.74 to 40.95 mol% after adding CTAB to the reaction mixture. Based upon experimental observations, a possible mechanism was also proposed for the present oxidation.Graphical Abstract More... »

PAGES

333-339

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10562-013-1104-5

DOI

http://dx.doi.org/10.1007/s10562-013-1104-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1049131419


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