On Cluster Size Dependent Activity and Selectivity in Heterogeneous Catalysis View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-11

AUTHORS

Dmitry Yu. Murzin

ABSTRACT

The impact of nanoparticle size effects in heterogeneous catalytic kinetics over supported metal catalysts is discussed for clusters having several distinct active sites. Theoretical analysis demonstrates that considerations of different activity for such sites not only allow a description of a smooth increase or decrease of turnover frequency as a function of cluster size, but also can in principle account for maxima in turnover frequency. Several examples are presented addressing advantages and shortcomings of the model (in some cases giving physically unreasonable values of parameters during numerical data fitting). Comparison with a rival model with a continuous variation of activity is presented. More... »

PAGES

1279-1285

References to SciGraph publications

Journal

TITLE

Catalysis Letters

ISSUE

11

VOLUME

142

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10562-012-0896-z

DOI

http://dx.doi.org/10.1007/s10562-012-0896-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1004516183


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