Hydrocracking of Biomass-Derived Materials into Alkanes in the Presence of Platinum-Based Catalyst and Hydrogen View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-11

AUTHORS

Kazuhisa Murata, Yanyong Liu, Megumu Inaba, Isao Takahara

ABSTRACT

Renewable green C2–C9 alkanes can be directly produced by Pt/H-ZSM-5-catalyzed hydrocracking of biomass-derived materials, no pre-treated or pre-treated by alcohol. The pre-treatment of cellulose in 1-hexanol at 623 K, followed by hydrocracking catalyzed by Pt/H-ZSM-5(23) at 673 K, produced C2–C9 alkanes in as high as 89% yields with CH4/COx yields of only 6%. The reaction pathway involves lowering of molecular weight of cellulose materials, producing, probably, oxygenates intermediates such as mono-saccharide and disaccharide, which are further efficiently converted to alkane products by successive hydrocracking and condensation, catalyzed by Pt/H-ZSM-5. More... »

PAGES

8-13

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10562-010-0396-y

DOI

http://dx.doi.org/10.1007/s10562-010-0396-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1015950066


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