Epoxidation of Cyclohexene with Air over the Composite Catalysts of Mn-mont Coordinated with Ligands View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-08

AUTHORS

Jian Jiang, Kun Ma, Yunfeng Zhen, Shunli Cai, Rong Li, Jiantai Ma

ABSTRACT

The catalytic activity of the composite catalysts of Mn-mont (where mont represents montmorillonite) coordinated with ligands for the epoxidation of cyclohexene by air under Mukaiyama conditions was studied. The composite catalysts were characterized by atomic absorption spectroscopic analysis, elemental analysis, fourier transform infrared spectra, diffuse reflectance ultraviolet visible spectra, X-ray photoelectron spectroscopy, powder-X-ray-diffraction, and scanning electron microscopy measurements. The effects of various reaction conditions on the catalytic reaction were studied. Experimental results indicated that the catalysts performed excellent activity for the epoxidation of cyclohexene by air. Repeated runs indicate that the catalyst is stable for 3 cycles. The composite catalysts of Mn-mont coordinated with ligands are economical and environmentally friendly for the epoxidation of cyclohexene. More... »

PAGES

105

Journal

TITLE

Catalysis Letters

ISSUE

1-2

VOLUME

131

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10562-009-9908-z

DOI

http://dx.doi.org/10.1007/s10562-009-9908-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003939568


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