[TMBSA][HSO4] Ionic Liquid as Novel Catalyst for the Rapid Acetylation of Alcohols, Hydroxyesters and Phenols under Solvent-free Conditions View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-02

AUTHORS

Wenjuan Wang, Wenping Cheng, Lili Shao, Jianguo Yang

ABSTRACT

Tri-methylammonium-butane sulfonate (TMBSA) ionic liquid (IL) catalyzed efficiently acetylation of acetic anhydride with various alcohols, hydroxyesters and phenols, under solvent-free conditions was described as a novel method. [TMBSA][HSO4] ionic liquid (1.0 mol%) is able to promote quantitative acetylation at low temperature, in high conversion and selectivity (≥95%). The process is highly effective, environmentally benign, and very selective. Furthermore, [TMBSA][HSO4] ionic liquid was conveniently separated with the products and easily recycled to catalyze acetylation reaction again with excellent yields. More... »

PAGES

77-80

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10562-007-9295-2

DOI

http://dx.doi.org/10.1007/s10562-007-9295-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1049165710


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