An easy way to Pd–Zn nanoalloy with defined composition from a heterobimetallic Pd(μ–OOCMe)4Zn(OH2) complex as evidenced by XAFS and XRD View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-12

AUTHORS

Olga P. Tkachenko, Alexander Yu. Stakheev, Leonid M. Kustov, Igor V. Mashkovsky, Maurits van den Berg, Wolfgang Grünert, Natalya Yu. Kozitsyna, Zhanna V. Dobrokhotova, Valery I. Zhilov, Sergei E. Nefedov, Michael N. Vargaftik, Ilya I. Moiseev

ABSTRACT

The heterobimetallic lantern complex Pd(μ-OOCMe)4Zn(OH2) was found to be readily reduced with H2 under fairly mild conditions (150–250 °C, 5–10% H2/He) both in the carbon-supported and crystalline states to afford a Pd–Zn nanoalloy as evidenced by the ICP elemental analysis, EXAFS, XANES and XRD data.

PAGES

155-161

Journal

TITLE

Catalysis Letters

ISSUE

3-4

VOLUME

112

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10562-006-0196-6

DOI

http://dx.doi.org/10.1007/s10562-006-0196-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1023878886


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