Methanol Steam Reforming Over NiAl and Ni (M) Al Layered Double Hydroxides (M = Au, Rh, Ir) Derived Catalysts View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-10

AUTHORS

Caixia Qi, John C. Amphlett, Brant A. Peppley

ABSTRACT

This paper deals with an experimental investigation concerning steam reforming of methanol at 280, 340 and 380 °C over NiAl and Ni (Au, Rh or Ir)Al layered double hydroxides (LDHs) derived catalysts. Incorporation of noble metal ions into the NiAl-LDH framework was evidenced by XRD, TGA and TEM techniques. High selectivity to H2 and CO2 with less than 5% (volume) CO and trace CH4 was observed over the NiAl-LDH catalyst. Whereas CO and H2 are major products at lower temperatures after addition of Au, Rh and Ir to the NiAl-LDH system. They are significantly reduced with the concomitant increase in CH4 and CO2 as the temperature increased. More... »

PAGES

57-62

Journal

TITLE

Catalysis Letters

ISSUE

1-2

VOLUME

104

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10562-005-7436-z

DOI

http://dx.doi.org/10.1007/s10562-005-7436-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1051949916


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140 schema:name Department of Chemistry and Chemical Engineering, Royal Military College of Canada, K7K 7B4, Kingston, Ontario, Canada
141 rdf:type schema:Organization
 




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