Hydrogenation of Unsaturated Hydrocarbons on Platinum and Palladium Catalysts Encapsulated in Mesoporous Bakelites View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-07

AUTHORS

M. P. Boronoev, A. B. Kulikov, E. S. Subbotina, L. A. Kulikov, S. V. Egazar’yants, Yu. S. Kardasheva, A. L. Maksimov, E. A. Karakhanov

ABSTRACT

Syntheses are reported for catalysts derived from platinum and palladium nanoparticles supported on a mesoporous phenol formaldehyde polymer modified by an ionic liquid. These catalysts are used for the hydrogenation of unsaturated compounds, specifically, acyclic and cyclic isoprenoids: isoprene, 2,5 – dimethyl–2,4–hexadiene, limonene, α –terpinene, γ –terpinene, as well as phenylacetylene, transstilbene, and 1,4–diphenyl–1,3–butadiene. High activity was found for these catalysts in hydrogenation reactions. The palladium catalysts were more active than their platinum analogs. The products of complete hydrogenation predominate in the hydrogenation of isoprenoids on the palladium catalysts, while monoene products predominate in the reactions on platinum catalysts. More... »

PAGES

318-332

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10553-017-0808-4

DOI

http://dx.doi.org/10.1007/s10553-017-0808-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1091399614


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