Spectroscopic investigations of U(VI) species sorbed by the green algae Chlorella vulgaris View Full Text


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Article Info

DATE

2008-06

AUTHORS

Alix Günther, Johannes Raff, Gerhard Geipel, Gert Bernhard

ABSTRACT

The green alga Chlorella vulgaris has the ability to bind high amounts of uranium(VI) in the pH range from 3 to 6. At pH 3 up to 40% of the uranium are bound by the algal cells. The uranium removal is almost complete at pH 5 and 6 under the given experimental conditions. Scanning electron microscopy and laser-induced fluorescence spectroscopy were used to characterize uranyl species formed in the selected pH range. The micrographs show a regular distribution of U(VI) on the cell surface. Fluorescence spectroscopic investigations of formed algal uranyl complexes indicate that the binding of U(VI) to carboxyl groups plays a dominating role at pH 3, whereas a minor impact of organic phosphate compounds on the U(VI) sorption cannot be excluded. In contrast, at pH 5 and 6 the phosphate groups are mainly responsible for the removal and binding of U(VI) by formation of organic and/or inorganic uranyl phosphates. More... »

PAGES

333-341

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10534-007-9122-7

DOI

http://dx.doi.org/10.1007/s10534-007-9122-7

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https://app.dimensions.ai/details/publication/pub.1011547313

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/18060601


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