Measuring adsorption isotherms with a flowmeter and a pressure gauge View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-04-02

AUTHORS

Fernando Vallejos-Burgos, Katsumi Kaneko

ABSTRACT

We revisit the quasi-equilibrium adsorption method as an inexpensive alternative to commercial volumetric apparatus for the measurement of gas adsorption isotherms. This method is based on how the pressure of a manifold containing the sample increases as a function of time when an adsorbing gas is introduced. We show that, under certain conditions, it is not necessary to employ ultra-low flow rates (i.e. below few cm3/h) to obtain reliable adsorption isotherms. Also, we show that by time-differentiating the mass balance equation, it is possible to obtain and measure directly the rates of adsorption. These new insights provide a low-cost and simple approach to the measurements of both adsorption equilibrium and rates. More... »

PAGES

1-9

References to SciGraph publications

Journal

TITLE

Adsorption

ISSUE

N/A

VOLUME

N/A

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10450-019-00068-8

DOI

http://dx.doi.org/10.1007/s10450-019-00068-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1113199714


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Shinshu University", 
          "id": "https://www.grid.ac/institutes/grid.263518.b", 
          "name": [
            "Center for Energy and Environmental Science, Shinshu University, 380-8553, Wakasato, Nagano, Japan", 
            "Morgan Advanced Materials, Carbon Science Centre of Excellence, 310 Innovation Blvd., Suite 250, 16803, State College, PA, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vallejos-Burgos", 
        "givenName": "Fernando", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shinshu University", 
          "id": "https://www.grid.ac/institutes/grid.263518.b", 
          "name": [
            "Center for Energy and Environmental Science, Shinshu University, 380-8553, Wakasato, Nagano, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kaneko", 
        "givenName": "Katsumi", 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/0095-8522(63)90104-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017643150"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0167-2991(08)61320-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020172898"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/cite.330311211", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020359385"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/ppsc.200400923", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024902474"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10450-016-9845-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027345660", 
          "https://doi.org/10.1007/s10450-016-9845-2"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10450-016-9845-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027345660", 
          "https://doi.org/10.1007/s10450-016-9845-2"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1515/pac-2014-1117", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032640091"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.carbon.2007.03.036", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032642317"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1201/b13722-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036979114"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1006/jcis.1996.0547", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038663392"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp5118085", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039554656"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1008965317983", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043357964", 
          "https://doi.org/10.1023/a:1008965317983"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/aic.690480115", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044455974"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0167-2991(09)60731-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052715567"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ac60053a023", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055024444"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/i360056a013", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055530730"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp061779n", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056065884"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp061779n", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056065884"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la00074a027", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056140496"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la00093a025", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056141480"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la801839b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056163211"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la801839b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056163211"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la991242j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056171752"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la991242j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056171752"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1051/jcp/1977740179", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1085895522"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/978-94-011-5672-1_4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1089775219", 
          "https://doi.org/10.1007/978-94-011-5672-1_4"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/978-94-011-5672-1_4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1089775219", 
          "https://doi.org/10.1007/978-94-011-5672-1_4"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/s41467-018-04224-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1103719862", 
          "https://doi.org/10.1038/s41467-018-04224-6"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2019-04-02", 
    "datePublishedReg": "2019-04-02", 
    "description": "We revisit the quasi-equilibrium adsorption method as an inexpensive alternative to commercial volumetric apparatus for the measurement of gas adsorption isotherms. This method is based on how the pressure of a manifold containing the sample increases as a function of time when an adsorbing gas is introduced. We show that, under certain conditions, it is not necessary to employ ultra-low flow rates (i.e. below few cm3/h) to obtain reliable adsorption isotherms. Also, we show that by time-differentiating the mass balance equation, it is possible to obtain and measure directly the rates of adsorption. These new insights provide a low-cost and simple approach to the measurements of both adsorption equilibrium and rates.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s10450-019-00068-8", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1134428", 
        "issn": [
          "0929-5607", 
          "1572-8757"
        ], 
        "name": "Adsorption", 
        "type": "Periodical"
      }
    ], 
    "name": "Measuring adsorption isotherms with a flowmeter and a pressure gauge", 
    "pagination": "1-9", 
    "productId": [
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10450-019-00068-8"
        ]
      }, 
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "9de932e47723e92cd5b87f9a7f47b04178dd93d02b3f24276cb1f4d7e25f89f8"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1113199714"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10450-019-00068-8", 
      "https://app.dimensions.ai/details/publication/pub.1113199714"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-15T09:14", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000376_0000000376/records_56164_00000006.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1007%2Fs10450-019-00068-8"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10450-019-00068-8'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10450-019-00068-8'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10450-019-00068-8'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10450-019-00068-8'


 

This table displays all metadata directly associated to this object as RDF triples.

134 TRIPLES      21 PREDICATES      47 URIs      16 LITERALS      5 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10450-019-00068-8 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Ne717e14e31aa41fdb4f359a938b8ac42
4 schema:citation sg:pub.10.1007/978-94-011-5672-1_4
5 sg:pub.10.1007/s10450-016-9845-2
6 sg:pub.10.1023/a:1008965317983
7 sg:pub.10.1038/s41467-018-04224-6
8 https://doi.org/10.1002/aic.690480115
9 https://doi.org/10.1002/cite.330311211
10 https://doi.org/10.1002/ppsc.200400923
11 https://doi.org/10.1006/jcis.1996.0547
12 https://doi.org/10.1016/0095-8522(63)90104-1
13 https://doi.org/10.1016/j.carbon.2007.03.036
14 https://doi.org/10.1016/s0167-2991(08)61320-8
15 https://doi.org/10.1016/s0167-2991(09)60731-x
16 https://doi.org/10.1021/ac60053a023
17 https://doi.org/10.1021/i360056a013
18 https://doi.org/10.1021/jp061779n
19 https://doi.org/10.1021/jp5118085
20 https://doi.org/10.1021/la00074a027
21 https://doi.org/10.1021/la00093a025
22 https://doi.org/10.1021/la801839b
23 https://doi.org/10.1021/la991242j
24 https://doi.org/10.1051/jcp/1977740179
25 https://doi.org/10.1201/b13722-2
26 https://doi.org/10.1515/pac-2014-1117
27 schema:datePublished 2019-04-02
28 schema:datePublishedReg 2019-04-02
29 schema:description We revisit the quasi-equilibrium adsorption method as an inexpensive alternative to commercial volumetric apparatus for the measurement of gas adsorption isotherms. This method is based on how the pressure of a manifold containing the sample increases as a function of time when an adsorbing gas is introduced. We show that, under certain conditions, it is not necessary to employ ultra-low flow rates (i.e. below few cm3/h) to obtain reliable adsorption isotherms. Also, we show that by time-differentiating the mass balance equation, it is possible to obtain and measure directly the rates of adsorption. These new insights provide a low-cost and simple approach to the measurements of both adsorption equilibrium and rates.
30 schema:genre research_article
31 schema:inLanguage en
32 schema:isAccessibleForFree false
33 schema:isPartOf sg:journal.1134428
34 schema:name Measuring adsorption isotherms with a flowmeter and a pressure gauge
35 schema:pagination 1-9
36 schema:productId N17bb4582e67b444f98aa3857801293f1
37 N4c864af8fb12489283b9c34b340f7b50
38 N7b463e9de1f04389b917879a22321207
39 schema:sameAs https://app.dimensions.ai/details/publication/pub.1113199714
40 https://doi.org/10.1007/s10450-019-00068-8
41 schema:sdDatePublished 2019-04-15T09:14
42 schema:sdLicense https://scigraph.springernature.com/explorer/license/
43 schema:sdPublisher N7c9d53768da048ebaddbd5491dc26b6b
44 schema:url https://link.springer.com/10.1007%2Fs10450-019-00068-8
45 sgo:license sg:explorer/license/
46 sgo:sdDataset articles
47 rdf:type schema:ScholarlyArticle
48 N17bb4582e67b444f98aa3857801293f1 schema:name dimensions_id
49 schema:value pub.1113199714
50 rdf:type schema:PropertyValue
51 N4c864af8fb12489283b9c34b340f7b50 schema:name doi
52 schema:value 10.1007/s10450-019-00068-8
53 rdf:type schema:PropertyValue
54 N6be2fbbe699b4516b41f2385736a7464 schema:affiliation https://www.grid.ac/institutes/grid.263518.b
55 schema:familyName Kaneko
56 schema:givenName Katsumi
57 rdf:type schema:Person
58 N7904b3d37b544b6491f91a458ed0840d rdf:first N6be2fbbe699b4516b41f2385736a7464
59 rdf:rest rdf:nil
60 N7b463e9de1f04389b917879a22321207 schema:name readcube_id
61 schema:value 9de932e47723e92cd5b87f9a7f47b04178dd93d02b3f24276cb1f4d7e25f89f8
62 rdf:type schema:PropertyValue
63 N7c9d53768da048ebaddbd5491dc26b6b schema:name Springer Nature - SN SciGraph project
64 rdf:type schema:Organization
65 Ncf953e7636e34e9d99095b82a1f093db schema:affiliation https://www.grid.ac/institutes/grid.263518.b
66 schema:familyName Vallejos-Burgos
67 schema:givenName Fernando
68 rdf:type schema:Person
69 Ne717e14e31aa41fdb4f359a938b8ac42 rdf:first Ncf953e7636e34e9d99095b82a1f093db
70 rdf:rest N7904b3d37b544b6491f91a458ed0840d
71 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
72 schema:name Chemical Sciences
73 rdf:type schema:DefinedTerm
74 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
75 schema:name Physical Chemistry (incl. Structural)
76 rdf:type schema:DefinedTerm
77 sg:journal.1134428 schema:issn 0929-5607
78 1572-8757
79 schema:name Adsorption
80 rdf:type schema:Periodical
81 sg:pub.10.1007/978-94-011-5672-1_4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1089775219
82 https://doi.org/10.1007/978-94-011-5672-1_4
83 rdf:type schema:CreativeWork
84 sg:pub.10.1007/s10450-016-9845-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027345660
85 https://doi.org/10.1007/s10450-016-9845-2
86 rdf:type schema:CreativeWork
87 sg:pub.10.1023/a:1008965317983 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043357964
88 https://doi.org/10.1023/a:1008965317983
89 rdf:type schema:CreativeWork
90 sg:pub.10.1038/s41467-018-04224-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1103719862
91 https://doi.org/10.1038/s41467-018-04224-6
92 rdf:type schema:CreativeWork
93 https://doi.org/10.1002/aic.690480115 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044455974
94 rdf:type schema:CreativeWork
95 https://doi.org/10.1002/cite.330311211 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020359385
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1002/ppsc.200400923 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024902474
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1006/jcis.1996.0547 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038663392
100 rdf:type schema:CreativeWork
101 https://doi.org/10.1016/0095-8522(63)90104-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017643150
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1016/j.carbon.2007.03.036 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032642317
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1016/s0167-2991(08)61320-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020172898
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1016/s0167-2991(09)60731-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1052715567
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1021/ac60053a023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055024444
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1021/i360056a013 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055530730
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1021/jp061779n schema:sameAs https://app.dimensions.ai/details/publication/pub.1056065884
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1021/jp5118085 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039554656
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1021/la00074a027 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056140496
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1021/la00093a025 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056141480
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1021/la801839b schema:sameAs https://app.dimensions.ai/details/publication/pub.1056163211
122 rdf:type schema:CreativeWork
123 https://doi.org/10.1021/la991242j schema:sameAs https://app.dimensions.ai/details/publication/pub.1056171752
124 rdf:type schema:CreativeWork
125 https://doi.org/10.1051/jcp/1977740179 schema:sameAs https://app.dimensions.ai/details/publication/pub.1085895522
126 rdf:type schema:CreativeWork
127 https://doi.org/10.1201/b13722-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036979114
128 rdf:type schema:CreativeWork
129 https://doi.org/10.1515/pac-2014-1117 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032640091
130 rdf:type schema:CreativeWork
131 https://www.grid.ac/institutes/grid.263518.b schema:alternateName Shinshu University
132 schema:name Center for Energy and Environmental Science, Shinshu University, 380-8553, Wakasato, Nagano, Japan
133 Morgan Advanced Materials, Carbon Science Centre of Excellence, 310 Innovation Blvd., Suite 250, 16803, State College, PA, USA
134 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...