The Structure of Water Monolayers on a Hydroxylated Chromium Oxide Surface View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-07

AUTHORS

Shigeharu Kittaka, Hiroyuki Sugiyama, Hiroshi Sumi, Shuichi Takahara

ABSTRACT

We have investigated the structure of monolayer water molecules on a hydroxylated (001) plane of Cr2O3 using GCMC simulations. The water molecules are adsorbed commensurately in the center of three surface hydroxyl groups by directing the proton of a water hydroxyl group towards the solid surface. Another type of water is adsorbed by bridging anchored water molecules, whereby, a two-dimensional (2D) condensed layer is formed. It was ascertained that 2D condensed monolayer water is not in a crystalline state below the 2D critical temperature (319 K), but is composed of many hexagonally linked rings. Above the 2D critical temperature, the hexagonal alignment of water changes to form a one-dimensional linked water structure. More... »

PAGES

103-107

References to SciGraph publications

  • 2007-12-14. Adsorption of alcohols on silica — evidence for the existence of aprotonic adsorption sites in MECHANISCHES VERHALTEN VON POLYMEREN WECHSELWIRKUNG IN POLYMEREN BZW. KOLLOIDEN SYSTEMEN
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s10450-005-5906-7

    DOI

    http://dx.doi.org/10.1007/s10450-005-5906-7

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1023014727


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Physical Chemistry (incl. Structural)", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Sciences", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Okayama University of Science", 
              "id": "https://www.grid.ac/institutes/grid.444568.f", 
              "name": [
                "Department of Chemistry, Faculty of Science, Okayama University of Science, 1-1 Ridaicho, 700-0005, Okayama, Japan"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Kittaka", 
            "givenName": "Shigeharu", 
            "id": "sg:person.0611144136.70", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0611144136.70"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Okayama University of Science", 
              "id": "https://www.grid.ac/institutes/grid.444568.f", 
              "name": [
                "Department of Chemistry, Faculty of Science, Okayama University of Science, 1-1 Ridaicho, 700-0005, Okayama, Japan"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Sugiyama", 
            "givenName": "Hiroyuki", 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Okayama University of Science", 
              "id": "https://www.grid.ac/institutes/grid.444568.f", 
              "name": [
                "Department of Chemistry, Faculty of Science, Okayama University of Science, 1-1 Ridaicho, 700-0005, Okayama, Japan"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Sumi", 
            "givenName": "Hiroshi", 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Okayama University of Science", 
              "id": "https://www.grid.ac/institutes/grid.444568.f", 
              "name": [
                "Department of Chemistry, Faculty of Science, Okayama University of Science, 1-1 Ridaicho, 700-0005, Okayama, Japan"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Takahara", 
            "givenName": "Shuichi", 
            "id": "sg:person.014463161765.79", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014463161765.79"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "https://doi.org/10.1016/0039-6028(93)90931-9", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1000220739"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0039-6028(93)90931-9", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1000220739"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0039-6028(81)90487-8", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1012290006"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0039-6028(81)90487-8", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1012290006"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0021-9797(76)90064-3", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1013780083"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1246/bcsj.53.26", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1016144256"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0021-9797(84)90248-0", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1029599651"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bfb0117382", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1030308740", 
              "https://doi.org/10.1007/bfb0117382"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bfb0117382", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1030308740", 
              "https://doi.org/10.1007/bfb0117382"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0022-0248(72)90147-9", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1040353092"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0254-0584(87)90056-3", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1040358827"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0254-0584(87)90056-3", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1040358827"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1246/bcsj.41.1533", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1046734320"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/j100687a012", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055676171"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja01864a025", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055820743"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2005-07", 
        "datePublishedReg": "2005-07-01", 
        "description": "We have investigated the structure of monolayer water molecules on a hydroxylated (001) plane of Cr2O3 using GCMC simulations. The water molecules are adsorbed commensurately in the center of three surface hydroxyl groups by directing the proton of a water hydroxyl group towards the solid surface. Another type of water is adsorbed by bridging anchored water molecules, whereby, a two-dimensional (2D) condensed layer is formed. It was ascertained that 2D condensed monolayer water is not in a crystalline state below the 2D critical temperature (319 K), but is composed of many hexagonally linked rings. Above the 2D critical temperature, the hexagonal alignment of water changes to form a one-dimensional linked water structure.", 
        "genre": "research_article", 
        "id": "sg:pub.10.1007/s10450-005-5906-7", 
        "inLanguage": [
          "en"
        ], 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1134428", 
            "issn": [
              "0929-5607", 
              "1572-8757"
            ], 
            "name": "Adsorption", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "Suppl 1", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "11"
          }
        ], 
        "name": "The Structure of Water Monolayers on a Hydroxylated Chromium Oxide Surface", 
        "pagination": "103-107", 
        "productId": [
          {
            "name": "readcube_id", 
            "type": "PropertyValue", 
            "value": [
              "6da5b39aafb850f27515b7e07de7ed6c3eeb27a26ccc7c38118d0016ae6d5a54"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/s10450-005-5906-7"
            ]
          }, 
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1023014727"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/s10450-005-5906-7", 
          "https://app.dimensions.ai/details/publication/pub.1023014727"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2019-04-11T12:03", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000360_0000000360/records_118305_00000000.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "http://link.springer.com/10.1007/s10450-005-5906-7"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10450-005-5906-7'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10450-005-5906-7'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10450-005-5906-7'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10450-005-5906-7'


     

    This table displays all metadata directly associated to this object as RDF triples.

    114 TRIPLES      21 PREDICATES      38 URIs      19 LITERALS      7 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/s10450-005-5906-7 schema:about anzsrc-for:03
    2 anzsrc-for:0306
    3 schema:author Ne4560f617aa5437ea2e3495d58fa6949
    4 schema:citation sg:pub.10.1007/bfb0117382
    5 https://doi.org/10.1016/0021-9797(76)90064-3
    6 https://doi.org/10.1016/0021-9797(84)90248-0
    7 https://doi.org/10.1016/0022-0248(72)90147-9
    8 https://doi.org/10.1016/0039-6028(81)90487-8
    9 https://doi.org/10.1016/0039-6028(93)90931-9
    10 https://doi.org/10.1016/0254-0584(87)90056-3
    11 https://doi.org/10.1021/j100687a012
    12 https://doi.org/10.1021/ja01864a025
    13 https://doi.org/10.1246/bcsj.41.1533
    14 https://doi.org/10.1246/bcsj.53.26
    15 schema:datePublished 2005-07
    16 schema:datePublishedReg 2005-07-01
    17 schema:description We have investigated the structure of monolayer water molecules on a hydroxylated (001) plane of Cr2O3 using GCMC simulations. The water molecules are adsorbed commensurately in the center of three surface hydroxyl groups by directing the proton of a water hydroxyl group towards the solid surface. Another type of water is adsorbed by bridging anchored water molecules, whereby, a two-dimensional (2D) condensed layer is formed. It was ascertained that 2D condensed monolayer water is not in a crystalline state below the 2D critical temperature (319 K), but is composed of many hexagonally linked rings. Above the 2D critical temperature, the hexagonal alignment of water changes to form a one-dimensional linked water structure.
    18 schema:genre research_article
    19 schema:inLanguage en
    20 schema:isAccessibleForFree false
    21 schema:isPartOf N5f3dc73ec89b447983c4cbcb08d56a91
    22 Nae9cb6d6585d431e92b28b3d270bc0a7
    23 sg:journal.1134428
    24 schema:name The Structure of Water Monolayers on a Hydroxylated Chromium Oxide Surface
    25 schema:pagination 103-107
    26 schema:productId N33aadd3ab80c4e3f9fe299db11bd0a05
    27 Nadab16dbbd7e44a1b1c78e8c2f340147
    28 Nde22fd59426d452f8c825267ab4500b0
    29 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023014727
    30 https://doi.org/10.1007/s10450-005-5906-7
    31 schema:sdDatePublished 2019-04-11T12:03
    32 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    33 schema:sdPublisher N14f7277cc4b344889d082439acf82670
    34 schema:url http://link.springer.com/10.1007/s10450-005-5906-7
    35 sgo:license sg:explorer/license/
    36 sgo:sdDataset articles
    37 rdf:type schema:ScholarlyArticle
    38 N14f7277cc4b344889d082439acf82670 schema:name Springer Nature - SN SciGraph project
    39 rdf:type schema:Organization
    40 N29c5c846e22d4b9f97143a49ed283d91 schema:affiliation https://www.grid.ac/institutes/grid.444568.f
    41 schema:familyName Sumi
    42 schema:givenName Hiroshi
    43 rdf:type schema:Person
    44 N33aadd3ab80c4e3f9fe299db11bd0a05 schema:name readcube_id
    45 schema:value 6da5b39aafb850f27515b7e07de7ed6c3eeb27a26ccc7c38118d0016ae6d5a54
    46 rdf:type schema:PropertyValue
    47 N42b4e1c05eac4348b9d18e6196e7283b rdf:first N29c5c846e22d4b9f97143a49ed283d91
    48 rdf:rest Nbe6803c53624486fbc3f758591007511
    49 N5f3dc73ec89b447983c4cbcb08d56a91 schema:issueNumber Suppl 1
    50 rdf:type schema:PublicationIssue
    51 Nadab16dbbd7e44a1b1c78e8c2f340147 schema:name doi
    52 schema:value 10.1007/s10450-005-5906-7
    53 rdf:type schema:PropertyValue
    54 Nae9cb6d6585d431e92b28b3d270bc0a7 schema:volumeNumber 11
    55 rdf:type schema:PublicationVolume
    56 Nbe6803c53624486fbc3f758591007511 rdf:first sg:person.014463161765.79
    57 rdf:rest rdf:nil
    58 Nd050d238a75342df9947d5fd717610a1 rdf:first Ne8a7bb43936741cb8914d0a78bc8936f
    59 rdf:rest N42b4e1c05eac4348b9d18e6196e7283b
    60 Nde22fd59426d452f8c825267ab4500b0 schema:name dimensions_id
    61 schema:value pub.1023014727
    62 rdf:type schema:PropertyValue
    63 Ne4560f617aa5437ea2e3495d58fa6949 rdf:first sg:person.0611144136.70
    64 rdf:rest Nd050d238a75342df9947d5fd717610a1
    65 Ne8a7bb43936741cb8914d0a78bc8936f schema:affiliation https://www.grid.ac/institutes/grid.444568.f
    66 schema:familyName Sugiyama
    67 schema:givenName Hiroyuki
    68 rdf:type schema:Person
    69 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
    70 schema:name Chemical Sciences
    71 rdf:type schema:DefinedTerm
    72 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
    73 schema:name Physical Chemistry (incl. Structural)
    74 rdf:type schema:DefinedTerm
    75 sg:journal.1134428 schema:issn 0929-5607
    76 1572-8757
    77 schema:name Adsorption
    78 rdf:type schema:Periodical
    79 sg:person.014463161765.79 schema:affiliation https://www.grid.ac/institutes/grid.444568.f
    80 schema:familyName Takahara
    81 schema:givenName Shuichi
    82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014463161765.79
    83 rdf:type schema:Person
    84 sg:person.0611144136.70 schema:affiliation https://www.grid.ac/institutes/grid.444568.f
    85 schema:familyName Kittaka
    86 schema:givenName Shigeharu
    87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0611144136.70
    88 rdf:type schema:Person
    89 sg:pub.10.1007/bfb0117382 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030308740
    90 https://doi.org/10.1007/bfb0117382
    91 rdf:type schema:CreativeWork
    92 https://doi.org/10.1016/0021-9797(76)90064-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013780083
    93 rdf:type schema:CreativeWork
    94 https://doi.org/10.1016/0021-9797(84)90248-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029599651
    95 rdf:type schema:CreativeWork
    96 https://doi.org/10.1016/0022-0248(72)90147-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040353092
    97 rdf:type schema:CreativeWork
    98 https://doi.org/10.1016/0039-6028(81)90487-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012290006
    99 rdf:type schema:CreativeWork
    100 https://doi.org/10.1016/0039-6028(93)90931-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000220739
    101 rdf:type schema:CreativeWork
    102 https://doi.org/10.1016/0254-0584(87)90056-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040358827
    103 rdf:type schema:CreativeWork
    104 https://doi.org/10.1021/j100687a012 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055676171
    105 rdf:type schema:CreativeWork
    106 https://doi.org/10.1021/ja01864a025 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055820743
    107 rdf:type schema:CreativeWork
    108 https://doi.org/10.1246/bcsj.41.1533 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046734320
    109 rdf:type schema:CreativeWork
    110 https://doi.org/10.1246/bcsj.53.26 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016144256
    111 rdf:type schema:CreativeWork
    112 https://www.grid.ac/institutes/grid.444568.f schema:alternateName Okayama University of Science
    113 schema:name Department of Chemistry, Faculty of Science, Okayama University of Science, 1-1 Ridaicho, 700-0005, Okayama, Japan
    114 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...