The Structure of Water Monolayers on a Hydroxylated Chromium Oxide Surface View Full Text


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Article Info

DATE

2005-07

AUTHORS

Shigeharu Kittaka, Hiroyuki Sugiyama, Hiroshi Sumi, Shuichi Takahara

ABSTRACT

We have investigated the structure of monolayer water molecules on a hydroxylated (001) plane of Cr2O3 using GCMC simulations. The water molecules are adsorbed commensurately in the center of three surface hydroxyl groups by directing the proton of a water hydroxyl group towards the solid surface. Another type of water is adsorbed by bridging anchored water molecules, whereby, a two-dimensional (2D) condensed layer is formed. It was ascertained that 2D condensed monolayer water is not in a crystalline state below the 2D critical temperature (319 K), but is composed of many hexagonally linked rings. Above the 2D critical temperature, the hexagonal alignment of water changes to form a one-dimensional linked water structure. More... »

PAGES

103-107

References to SciGraph publications

  • 2007-12-14. Adsorption of alcohols on silica — evidence for the existence of aprotonic adsorption sites in MECHANISCHES VERHALTEN VON POLYMEREN WECHSELWIRKUNG IN POLYMEREN BZW. KOLLOIDEN SYSTEMEN
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    http://scigraph.springernature.com/pub.10.1007/s10450-005-5906-7

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    http://dx.doi.org/10.1007/s10450-005-5906-7

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