Ontology type: schema:ScholarlyArticle
1999-04
AUTHORSV. A. Sadykov, Svetlana N. Pavlova, Galina V. Zabolotnaya, Raisa I. Maximovskaya, Sergei V. Tsybulya, Elena B. Burgina, Vladimir I. Zaikovskii, Galina S. Litvak, Marina V. Chaikina, Valerii V. Lunin, Natalya N. Kuznetsova, Rustum Roy, Dinesh K. Agrawal
ABSTRACTHigh-power ball mill activation of the mixture of hydrated zirconium and lanthanum salts (oxonitrates, oxochlorides) with ammonium phosphate followed by hydrothermal treatment at temperatures not exceeding 200°C and a nearly neutral pH was found to yield crystalline dispersed phase of a cubic NH4Zr2(PO4)3 type along with admixtures of disordered orthorhombic compounds of a zirconium orthophosphate type. In the same conditions and at the same Zr/P ratio, hydrothermal treatment of gels obtained by reacting mixed zirconium and lanthanum nitrates solutions with ammonium phosphates yields no crystalline products, and only treatment in acid media generates a phase of the α-ZrPO4(OH) type coexisting with the NH4Zr2(PO4)3 phase if polyethylene oxide is present. X-ray powder diffraction, transmission electron microscopy, 31MAS-NMR, FTIRS and thermal analysis were applied to elucidate factors affecting crystallization of complex zirconium phosphates in the hydrothermal conditions. The most essential factor appears to be generation of some nuclei of zirconium phosphates under high pressures developed in the course of mixed solids mechanical activation. These nuclei are embedded into matrix of such well-crystallized solid products as ammonium nitrate or chloride. Hence, metastable cubic or orthorhombic structure of the phases obtained via mechanical activation route can be assigned to the nuclei-matrix orientation relationship. Due to easily scaled-up synthesis procedure, these results appear to be very promising for manufacturing of dispersed framework zirconium phosphates as acid catalysts or fast proton conductors. More... »
PAGES328-337
http://scigraph.springernature.com/pub.10.1007/s100190050109
DOIhttp://dx.doi.org/10.1007/s100190050109
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1041538830
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Engineering",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Materials Engineering",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "The Boreskov Institute of Catalysis SB RAS, Novosibirsk State University, Novosibirsk 630090, Lavrentieva 5, Russia Fax: +7-3832-357687, e-mail: sadykov@catalysis.nsk.su, RU",
"id": "http://www.grid.ac/institutes/grid.4605.7",
"name": [
"The Boreskov Institute of Catalysis SB RAS, Novosibirsk State University, Novosibirsk 630090, Lavrentieva 5, Russia Fax: +7-3832-357687, e-mail: sadykov@catalysis.nsk.su, RU"
],
"type": "Organization"
},
"familyName": "Sadykov",
"givenName": "V. A.",
"id": "sg:person.07571716351.55",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07571716351.55"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "The Boreskov Institute of Catalysis SB RAS, Novosibirsk State University, Novosibirsk 630090, Lavrentieva 5, Russia Fax: +7-3832-357687, e-mail: sadykov@catalysis.nsk.su, RU",
"id": "http://www.grid.ac/institutes/grid.4605.7",
"name": [
"The Boreskov Institute of Catalysis SB RAS, Novosibirsk State University, Novosibirsk 630090, Lavrentieva 5, Russia Fax: +7-3832-357687, e-mail: sadykov@catalysis.nsk.su, RU"
],
"type": "Organization"
},
"familyName": "Pavlova",
"givenName": "Svetlana N.",
"id": "sg:person.016501116120.48",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016501116120.48"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "The Boreskov Institute of Catalysis SB RAS, Novosibirsk State University, Novosibirsk 630090, Lavrentieva 5, Russia Fax: +7-3832-357687, e-mail: sadykov@catalysis.nsk.su, RU",
"id": "http://www.grid.ac/institutes/grid.4605.7",
"name": [
"The Boreskov Institute of Catalysis SB RAS, Novosibirsk State University, Novosibirsk 630090, Lavrentieva 5, Russia Fax: +7-3832-357687, e-mail: sadykov@catalysis.nsk.su, RU"
],
"type": "Organization"
},
"familyName": "Zabolotnaya",
"givenName": "Galina V.",
"id": "sg:person.010505334712.49",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010505334712.49"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "The Boreskov Institute of Catalysis SB RAS, Novosibirsk State University, Novosibirsk 630090, Lavrentieva 5, Russia Fax: +7-3832-357687, e-mail: sadykov@catalysis.nsk.su, RU",
"id": "http://www.grid.ac/institutes/grid.4605.7",
"name": [
"The Boreskov Institute of Catalysis SB RAS, Novosibirsk State University, Novosibirsk 630090, Lavrentieva 5, Russia Fax: +7-3832-357687, e-mail: sadykov@catalysis.nsk.su, RU"
],
"type": "Organization"
},
"familyName": "Maximovskaya",
"givenName": "Raisa I.",
"id": "sg:person.07406026577.01",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07406026577.01"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "The Boreskov Institute of Catalysis SB RAS, Novosibirsk State University, Novosibirsk 630090, Lavrentieva 5, Russia Fax: +7-3832-357687, e-mail: sadykov@catalysis.nsk.su, RU",
"id": "http://www.grid.ac/institutes/grid.4605.7",
"name": [
"The Boreskov Institute of Catalysis SB RAS, Novosibirsk State University, Novosibirsk 630090, Lavrentieva 5, Russia Fax: +7-3832-357687, e-mail: sadykov@catalysis.nsk.su, RU"
],
"type": "Organization"
},
"familyName": "Tsybulya",
"givenName": "Sergei V.",
"id": "sg:person.011252704043.40",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011252704043.40"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "The Boreskov Institute of Catalysis SB RAS, Novosibirsk State University, Novosibirsk 630090, Lavrentieva 5, Russia Fax: +7-3832-357687, e-mail: sadykov@catalysis.nsk.su, RU",
"id": "http://www.grid.ac/institutes/grid.4605.7",
"name": [
"The Boreskov Institute of Catalysis SB RAS, Novosibirsk State University, Novosibirsk 630090, Lavrentieva 5, Russia Fax: +7-3832-357687, e-mail: sadykov@catalysis.nsk.su, RU"
],
"type": "Organization"
},
"familyName": "Burgina",
"givenName": "Elena B.",
"id": "sg:person.011163453051.19",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011163453051.19"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "The Boreskov Institute of Catalysis SB RAS, Novosibirsk State University, Novosibirsk 630090, Lavrentieva 5, Russia Fax: +7-3832-357687, e-mail: sadykov@catalysis.nsk.su, RU",
"id": "http://www.grid.ac/institutes/grid.4605.7",
"name": [
"The Boreskov Institute of Catalysis SB RAS, Novosibirsk State University, Novosibirsk 630090, Lavrentieva 5, Russia Fax: +7-3832-357687, e-mail: sadykov@catalysis.nsk.su, RU"
],
"type": "Organization"
},
"familyName": "Zaikovskii",
"givenName": "Vladimir I.",
"id": "sg:person.0770401015.84",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0770401015.84"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "The Boreskov Institute of Catalysis SB RAS, Novosibirsk State University, Novosibirsk 630090, Lavrentieva 5, Russia Fax: +7-3832-357687, e-mail: sadykov@catalysis.nsk.su, RU",
"id": "http://www.grid.ac/institutes/grid.4605.7",
"name": [
"The Boreskov Institute of Catalysis SB RAS, Novosibirsk State University, Novosibirsk 630090, Lavrentieva 5, Russia Fax: +7-3832-357687, e-mail: sadykov@catalysis.nsk.su, RU"
],
"type": "Organization"
},
"familyName": "Litvak",
"givenName": "Galina S.",
"id": "sg:person.07530237133.45",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07530237133.45"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institute Of Solid State Chemistry and Mechanochemistry SB RAS, Novosibirsk 630128, Kutateladze 18, Russia, RU",
"id": "http://www.grid.ac/institutes/grid.435414.3",
"name": [
"Institute Of Solid State Chemistry and Mechanochemistry SB RAS, Novosibirsk 630128, Kutateladze 18, Russia, RU"
],
"type": "Organization"
},
"familyName": "Chaikina",
"givenName": "Marina V.",
"id": "sg:person.010647111357.26",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010647111357.26"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Lomonosov State University, Chemical Department, Moscow 119899, Vorobyevy Gory, Russia, RU",
"id": "http://www.grid.ac/institutes/grid.14476.30",
"name": [
"Lomonosov State University, Chemical Department, Moscow 119899, Vorobyevy Gory, Russia, RU"
],
"type": "Organization"
},
"familyName": "Lunin",
"givenName": "Valerii V.",
"id": "sg:person.0633770006.49",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0633770006.49"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Lomonosov State University, Chemical Department, Moscow 119899, Vorobyevy Gory, Russia, RU",
"id": "http://www.grid.ac/institutes/grid.14476.30",
"name": [
"Lomonosov State University, Chemical Department, Moscow 119899, Vorobyevy Gory, Russia, RU"
],
"type": "Organization"
},
"familyName": "Kuznetsova",
"givenName": "Natalya N.",
"id": "sg:person.014240606043.19",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014240606043.19"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802, USA, US",
"id": "http://www.grid.ac/institutes/grid.29857.31",
"name": [
"Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802, USA, US"
],
"type": "Organization"
},
"familyName": "Roy",
"givenName": "Rustum",
"id": "sg:person.014504515123.62",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014504515123.62"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802, USA, US",
"id": "http://www.grid.ac/institutes/grid.29857.31",
"name": [
"Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802, USA, US"
],
"type": "Organization"
},
"familyName": "Agrawal",
"givenName": "Dinesh K.",
"id": "sg:person.012536714204.17",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012536714204.17"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1007/bf01145507",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1029745754",
"https://doi.org/10.1007/bf01145507"
],
"type": "CreativeWork"
}
],
"datePublished": "1999-04",
"datePublishedReg": "1999-04-01",
"description": "Abstract\u2002High-power ball mill activation of the mixture of hydrated zirconium and lanthanum salts (oxonitrates, oxochlorides) with ammonium phosphate followed by hydrothermal treatment at temperatures not exceeding 200\u00b0C and a nearly neutral pH was found to yield crystalline dispersed phase of a cubic NH4Zr2(PO4)3 type along with admixtures of disordered orthorhombic compounds of a zirconium orthophosphate type. In the same conditions and at the same Zr/P ratio, hydrothermal treatment of gels obtained by reacting mixed zirconium and lanthanum nitrates solutions with ammonium phosphates yields no crystalline products, and only treatment in acid media generates a phase of the \u03b1-ZrPO4(OH) type coexisting with the NH4Zr2(PO4)3 phase if polyethylene oxide is present. X-ray powder diffraction, transmission electron microscopy, 31MAS-NMR, FTIRS and thermal analysis were applied to elucidate factors affecting crystallization of complex zirconium phosphates in the hydrothermal conditions. The most essential factor appears to be generation of some nuclei of zirconium phosphates under high pressures developed in the course of mixed solids mechanical activation. These nuclei are embedded into matrix of such well-crystallized solid products as ammonium nitrate or chloride. Hence, metastable cubic or orthorhombic structure of the phases obtained via mechanical activation route can be assigned to the nuclei-matrix orientation relationship. Due to easily scaled-up synthesis procedure, these results appear to be very promising for manufacturing of dispersed framework zirconium phosphates as acid catalysts or fast proton conductors.",
"genre": "article",
"id": "sg:pub.10.1007/s100190050109",
"inLanguage": "en",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1137488",
"issn": [
"1432-8917",
"1433-075X"
],
"name": "Materials Research Innovations",
"publisher": "Taylor & Francis",
"type": "Periodical"
},
{
"issueNumber": "6",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "2"
}
],
"keywords": [
"mechanical activation route",
"mechanochemical activation route",
"hydrothermal treatment",
"zirconium phosphate",
"lanthanum nitrate solution",
"mechanical activation",
"polyethylene oxide",
"transmission electron microscopy",
"ray powder diffraction",
"activation route",
"orientation relationship",
"solid products",
"thermal analysis",
"hydrated zirconium",
"proton conductors",
"nitrate solution",
"framework zirconium phosphates",
"mixed zirconium",
"high pressure",
"fast proton conductors",
"electron microscopy",
"powder diffraction",
"orthorhombic structure",
"synthesis procedure",
"zirconium",
"lanthanum salts",
"same conditions",
"crystalline products",
"ammonium nitrate",
"phase",
"ammonium phosphate",
"manufacturing",
"acid medium",
"acid catalyst",
"conductors",
"oxide",
"temperature",
"phosphate yield",
"diffraction",
"hydrothermal conditions",
"conditions",
"crystalline",
"FTIR",
"microscopy",
"route",
"matrix",
"catalyst",
"crystallization",
"mixture",
"orthorhombic compound",
"solution",
"pressure",
"admixture",
"products",
"essential factor",
"phosphate",
"generation",
"neutral pH",
"structure",
"ratio",
"nitrate",
"types",
"gel",
"pH",
"results",
"chloride",
"salt",
"medium",
"procedure",
"analysis",
"yield",
"factors",
"synthesis",
"compounds",
"treatment",
"relationship",
"course",
"activation",
"elucidate factors",
"only treatment",
"nucleus"
],
"name": "Synthesis of high-surface-area complex zirconium phosphates via mechanochemical activation route",
"pagination": "328-337",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1041538830"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/s100190050109"
]
}
],
"sameAs": [
"https://doi.org/10.1007/s100190050109",
"https://app.dimensions.ai/details/publication/pub.1041538830"
],
"sdDataset": "articles",
"sdDatePublished": "2022-05-20T07:21",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220519/entities/gbq_results/article/article_308.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1007/s100190050109"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s100190050109'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s100190050109'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s100190050109'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s100190050109'
This table displays all metadata directly associated to this object as RDF triples.
236 TRIPLES
22 PREDICATES
108 URIs
99 LITERALS
6 BLANK NODES