Fluctuation synthesis and characterization of Ti3SiC2 powders View Full Text


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Article Info

DATE

1999-01

AUTHORS

Zhimei Sun, Y. Zhou

ABSTRACT

A novel fluctuation method for the synthesis of Ti3SiC2 powders was developed. The raw materials used in this process are Ti, Si, and graphite powders. Fluctuation synthesis utilized Si as in-situ liquid forming phase (additive), which was formed by heating the powder mixtures to 1300°C and using the heat released from the exothermic reaction for Ti3SiC2 formation. The result demonstrated that the reaction time for the formation of Ti3SiC2 was dramatically shortened using fluctuation method and the powders produced using this method contained more than twice amount of Ti3SiC2 compared to the solid reaction synthesized powders. The powders prepared by fluctuation method are fiber-like in morphology with dimensions of 0.8–2 µm in width and 5–10 µm in length. The growth direction of the fiber-like Ti3SiC2 particulate is {101–1}*. The lattice parameters for Ti3SiC2 were determined by a trial-and-error method and are a=3.067 Å and c=17.645 Å. More... »

PAGES

227-231

References to SciGraph publications

  • 1994-01. Solid-state synthesis and characterization of the ternary phase Ti3SiC2 in JOURNAL OF MATERIALS SCIENCE
  • 1991-07. Microstructure of alpha-silicon nitride whiskers in JOURNAL OF MATERIALS SCIENCE
  • 1994-10. On the chemical vapour deposition of Ti3SiC2 from TiCl4-SiCl4-CH4-H2 gas mixtures in JOURNAL OF MATERIALS SCIENCE
  • 1967-03. Die Kristallstruktur von Ti3SiC2—ein neuer Komplexcarbid-Typ in MONATSHEFTE FÜR CHEMIE - CHEMICAL MONTHLY
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1007/s100190050090

    DOI

    http://dx.doi.org/10.1007/s100190050090

    DIMENSIONS

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