Ontology type: schema:ScholarlyArticle
2000-06
AUTHORSV. A. Sadykov, S. N. Pavlova, G. V. Zabolotnaya, R. I. Maximovskaya, D. I. Kochubei, V. V. Kriventsov, G. V. Odegova, N. M. Ostrovskii, O. B. Bel’skaya, V. K. Duplyakin, V. I. Zaikovskii, E. A. Paukshtis, E. B. Burgina, S. V. Tsybulya, M. V. Chaikina, N. N. Kuznetsova, V. V. Lunin, R. Roy, D. K. Agrawal
ABSTRACTNanocomposites based upon framework zirconium phosphates with supported WO3, MoO3 and Pt nanoparticles were synthesized via the incipient wetness impregnation of high-surface-area mesoporous phosphate samples with water solutions of corresponding salts followed by drying and calcination. The structure and surface properties of nanocomposites were studied by using combination of structural and spectral methods. Due to a strong interaction between supports and supported species, the structure of the latter differs considerably from that of the bulk phases. Surface acid centers typical for zirconium phosphates disappear suggesting their participation in bonding nanoparticles of promoters. Instead, new types of strong acid sites associated with tungsten oxide clusters emerge. The effect of these promoters on performance of zirconium phosphates in the reaction of pentane and hexane isomerization is considered. More... »
PAGES276-285
http://scigraph.springernature.com/pub.10.1007/s100190000051
DOIhttp://dx.doi.org/10.1007/s100190000051
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1037200632
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Engineering",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Materials Engineering",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU"
],
"type": "Organization"
},
"familyName": "Sadykov",
"givenName": "V. A.",
"id": "sg:person.07571716351.55",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07571716351.55"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU"
],
"type": "Organization"
},
"familyName": "Pavlova",
"givenName": "S. N.",
"id": "sg:person.016501116120.48",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016501116120.48"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU"
],
"type": "Organization"
},
"familyName": "Zabolotnaya",
"givenName": "G. V.",
"id": "sg:person.010505334712.49",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010505334712.49"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU"
],
"type": "Organization"
},
"familyName": "Maximovskaya",
"givenName": "R. I.",
"id": "sg:person.07406026577.01",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07406026577.01"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU"
],
"type": "Organization"
},
"familyName": "Kochubei",
"givenName": "D. I.",
"id": "sg:person.014770054431.55",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014770054431.55"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU"
],
"type": "Organization"
},
"familyName": "Kriventsov",
"givenName": "V. V.",
"id": "sg:person.07711047073.65",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07711047073.65"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU"
],
"type": "Organization"
},
"familyName": "Odegova",
"givenName": "G. V.",
"id": "sg:person.010604640255.17",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010604640255.17"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU"
],
"type": "Organization"
},
"familyName": "Ostrovskii",
"givenName": "N. M.",
"id": "sg:person.016240312222.32",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016240312222.32"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU"
],
"type": "Organization"
},
"familyName": "Bel\u2019skaya",
"givenName": "O. B.",
"id": "sg:person.014155101105.62",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014155101105.62"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU"
],
"type": "Organization"
},
"familyName": "Duplyakin",
"givenName": "V. K.",
"id": "sg:person.016501016545.48",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016501016545.48"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU"
],
"type": "Organization"
},
"familyName": "Zaikovskii",
"givenName": "V. I.",
"id": "sg:person.0770401015.84",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0770401015.84"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU"
],
"type": "Organization"
},
"familyName": "Paukshtis",
"givenName": "E. A.",
"id": "sg:person.01330175745.06",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01330175745.06"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU"
],
"type": "Organization"
},
"familyName": "Burgina",
"givenName": "E. B.",
"id": "sg:person.011163453051.19",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011163453051.19"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva 5, Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia e-mail: sadykov@catalysis.nsk.su Fax: +7-3832-343056, RU"
],
"type": "Organization"
},
"familyName": "Tsybulya",
"givenName": "S. V.",
"id": "sg:person.011252704043.40",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011252704043.40"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institute of Solid State Chemistry, Siberian Branch of the Russian Academy of Sciences, Kutateladze 18, Novosibirsk 630090, Russia, RU",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"Institute of Solid State Chemistry, Siberian Branch of the Russian Academy of Sciences, Kutateladze 18, Novosibirsk 630090, Russia, RU"
],
"type": "Organization"
},
"familyName": "Chaikina",
"givenName": "M. V.",
"id": "sg:person.010647111357.26",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010647111357.26"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Chemical Department, Lomonosov Moscow State University, Vorobyovy gory, Moscow 119899, Russia, RU",
"id": "http://www.grid.ac/institutes/grid.14476.30",
"name": [
"Chemical Department, Lomonosov Moscow State University, Vorobyovy gory, Moscow 119899, Russia, RU"
],
"type": "Organization"
},
"familyName": "Kuznetsova",
"givenName": "N. N.",
"id": "sg:person.014240606043.19",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014240606043.19"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Chemical Department, Lomonosov Moscow State University, Vorobyovy gory, Moscow 119899, Russia, RU",
"id": "http://www.grid.ac/institutes/grid.14476.30",
"name": [
"Chemical Department, Lomonosov Moscow State University, Vorobyovy gory, Moscow 119899, Russia, RU"
],
"type": "Organization"
},
"familyName": "Lunin",
"givenName": "V. V.",
"id": "sg:person.014017763510.82",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014017763510.82"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "The Pennsylvania State University, 102 Materials Research Laboratory, University Park, PA 16802-4801, USA, US",
"id": "http://www.grid.ac/institutes/grid.29857.31",
"name": [
"The Pennsylvania State University, 102 Materials Research Laboratory, University Park, PA 16802-4801, USA, US"
],
"type": "Organization"
},
"familyName": "Roy",
"givenName": "R.",
"id": "sg:person.014504515123.62",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014504515123.62"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "The Pennsylvania State University, 102 Materials Research Laboratory, University Park, PA 16802-4801, USA, US",
"id": "http://www.grid.ac/institutes/grid.29857.31",
"name": [
"The Pennsylvania State University, 102 Materials Research Laboratory, University Park, PA 16802-4801, USA, US"
],
"type": "Organization"
},
"familyName": "Agrawal",
"givenName": "D. K.",
"id": "sg:person.012536714204.17",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012536714204.17"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1023/a:1019027628585",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1033966248",
"https://doi.org/10.1023/a:1019027628585"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1023/a:1019126708945",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1019143488",
"https://doi.org/10.1023/a:1019126708945"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s100190050109",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1041538830",
"https://doi.org/10.1007/s100190050109"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/978-3-662-12004-0",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1109712370",
"https://doi.org/10.1007/978-3-662-12004-0"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1557/proc-549-255",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1067944174",
"https://doi.org/10.1557/proc-549-255"
],
"type": "CreativeWork"
}
],
"datePublished": "2000-06",
"datePublishedReg": "2000-06-01",
"description": "Abstract\u2002Nanocomposites based upon framework zirconium phosphates with supported WO3, MoO3 and Pt nanoparticles were synthesized via the incipient wetness impregnation of high-surface-area mesoporous phosphate samples with water solutions of corresponding salts followed by drying and calcination. The structure and surface properties of nanocomposites were studied by using combination of structural and spectral methods. Due to a strong interaction between supports and supported species, the structure of the latter differs considerably from that of the bulk phases. Surface acid centers typical for zirconium phosphates disappear suggesting their participation in bonding nanoparticles of promoters. Instead, new types of strong acid sites associated with tungsten oxide clusters emerge. The effect of these promoters on performance of zirconium phosphates in the reaction of pentane and hexane isomerization is considered.",
"genre": "article",
"id": "sg:pub.10.1007/s100190000051",
"inLanguage": "en",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1137488",
"issn": [
"1432-8917",
"1433-075X"
],
"name": "Materials Research Innovations",
"publisher": "Taylor & Francis",
"type": "Periodical"
},
{
"issueNumber": "5",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "3"
}
],
"keywords": [
"framework zirconium phosphates",
"zirconium phosphate",
"surface properties",
"tungsten oxide clusters",
"incipient wetness impregnation",
"bulk phase",
"nanocomposites",
"Pt nanoparticles",
"water solution",
"wetness impregnation",
"new type",
"nanoparticles",
"phosphate samples",
"microstructure",
"spectral method",
"properties",
"strong interaction",
"WO3",
"strong acid sites",
"calcination",
"oxide clusters",
"MoO3",
"impregnation",
"acid sites",
"structure",
"performance",
"reaction of pentane",
"solution",
"phase",
"surface acid centers",
"pentane",
"hexane isomerization",
"phosphate",
"acid centers",
"alkane isomerization",
"method",
"salt",
"combination",
"effect",
"samples",
"types",
"reaction",
"corresponding salts",
"interaction",
"center",
"sites",
"support",
"isomerization",
"clusters",
"species",
"participation",
"promoter"
],
"name": "The microstructure and properties of framework zirconium phosphates based nanocomposites \u2013 catalysts of alkane isomerization",
"pagination": "276-285",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1037200632"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/s100190000051"
]
}
],
"sameAs": [
"https://doi.org/10.1007/s100190000051",
"https://app.dimensions.ai/details/publication/pub.1037200632"
],
"sdDataset": "articles",
"sdDatePublished": "2022-06-01T22:02",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220601/entities/gbq_results/article/article_312.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1007/s100190000051"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s100190000051'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s100190000051'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s100190000051'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s100190000051'
This table displays all metadata directly associated to this object as RDF triples.
272 TRIPLES
22 PREDICATES
85 URIs
70 LITERALS
6 BLANK NODES