Ontology type: schema:ScholarlyArticle
2017-11
AUTHORSYuji Mishima, Chikako Moriyoshi, Yoshihiro Kuroiwa
ABSTRACTElectrochemical reactions in the particulate crystal of olivine cathodes topotactically proceed in the lithiated and delithiated phases. Optimized-synthesis conditions for 4 V class LiMn0.8Fe0.2PO4 cathode materials permitted the surface modification and cation-mixing reduction for the resulting powder particles. The discharge capacities of a Li/LiMn0.8Fe0.2PO4 cell in the C–rate range of 0.1C (17.1 mA/g) and 5C (855 mA/g) were of practical values and compatible with those of a Li/LiFePO4 cell. However, since the crystallite size of LiMn0.8Fe0.2PO4 was about 80 nm and almost half as large as LiFePO4, the electrode density of LiMn0.8Fe0.2PO4 was 83 percentage of LiFePO4, meaning the reduction of the volumetric energy density. To examine the necessity of the reduced crystallite size to obtain the excellent gravimetric energy density, the charge–density distributions around the diffusion pathways of Li+ ions for the lithiated and delithiated materials have been investigated, which allows us to discuss the atomic scale diffusivities of Li+ ions. Graphical abstractᅟ ᅟ More... »
PAGES3221-3228
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DOIhttp://dx.doi.org/10.1007/s10008-017-3636-x
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