Electrochemical nucleation and growth of silicon in the KF-KCl-K2SiF6 melt View Full Text


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Article Info

DATE

2015-05

AUTHORS

Yurii P. Zaykov, Sergey I. Zhuk, Andrey V. Isakov, Olga V. Grishenkova, Vladimir A. Isaev

ABSTRACT

The work related to the study of the initial stages of the silicon electrodeposition on the glassy carbon electrode in molten KF-KCl-K2SiF6 was performed. The silicon nucleation and growth process was investigated using cyclic voltammetry, chronoamperometry, and scanning electron microscopy. It was shown that the electrocrystallization process occurs by the instantaneous nucleation with diffusion-controlled growth under the studied conditions. The Scharifker-Hills theoretical model was used to calculate the nucleation density and the diffusion coefficient of depositing ions. More... »

PAGES

1341-1345

References to SciGraph publications

  • 2009-04. The current transient for nucleation and diffusion-controlled growth of spherical caps in JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • 2006-10. Nucleation-growth kinetics of the oxidation of silver nanocrystals to silver halide crystals in JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • 2013-06. Galvanostatic nucleation and growth under diffusion control in JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • 1983-05. The electrodeposition of silicon in fluoride melts in JOURNAL OF APPLIED ELECTROCHEMISTRY
  • 2011-12. Electrochemical behavior of silicon compound in LiF–NaF–KF–Na2SiF6 molten salt in IONICS
  • 1988-01. Electrolytic production of silicon in JOURNAL OF APPLIED ELECTROCHEMISTRY
  • 2013-02. Current transient study of the kinetics of nucleation and diffusion-controlled growth of bimetallic phases in JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • 2004-01. Number of Nuclei Formed during Electrocrystallization and Overall Time Dependence of Their Growth Current in RUSSIAN JOURNAL OF ELECTROCHEMISTRY
  • 2014-09. Galvanostatic phase formation in JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • 1987-03. Electroplating silicon and titanium in molten fluoride media in JOURNAL OF APPLIED ELECTROCHEMISTRY
  • 2003-03. Overlapping of Diffusion Zones during the Growth of Electrodeposited Crystal Nuclei in RUSSIAN JOURNAL OF ELECTROCHEMISTRY
  • Journal

    TITLE

    Journal of Solid State Electrochemistry

    ISSUE

    5

    VOLUME

    19

    Author Affiliations

    From Grant

  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s10008-014-2729-z

    DOI

    http://dx.doi.org/10.1007/s10008-014-2729-z

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1040234958


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