(Mn,Cu)3O4-based conductive coatings as effective barriers to high-temperature oxidation of metallic interconnects for solid oxide fuel cells View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-02

AUTHORS

Nurhadi S. Waluyo, Beom-Kyeong Park, Seung-Bok Lee, Tak-Hyoung Lim, Seok-Joo Park, Rak-Hyun Song, Jong-Won Lee

ABSTRACT

(Mn,Cu)3O4-based conductive oxides are examined as protective coatings to improve the surface stability of metallic interconnects for solid oxide fuel cells at high temperatures. Nano-sized Mn3 − xCuxO4 materials with various Cu contents (x = 1.0–1.5) are synthesized and a composition-structure–property relationship is experimentally determined. The Cu content (x) has a significant influence on phase stability as well as sintering, electrical, and thermal expansion characteristics. Thin and dense Mn3 − xCuxO4 coatings are fabricated on the interconnects (Crofer 22 APU) by a slurry coating process and subsequent heat treatment. The coated interconnects exhibit area-specific resistances as low as 7.1–15.0 mΩ cm2 at 800 °C. The electrochemical cell shows no performance degradation in the presence of the Mn3 − xCuxO4-coated interconnect. The results indicate that the Mn3 − xCuxO4 coatings act as an effective barrier to high-temperature oxidation of the metallic interconnects. More... »

PAGES

445-452

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10008-013-2245-6

DOI

http://dx.doi.org/10.1007/s10008-013-2245-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1013200319


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