Ontology type: schema:ScholarlyArticle
2014-02
AUTHORSNurhadi S. Waluyo, Beom-Kyeong Park, Seung-Bok Lee, Tak-Hyoung Lim, Seok-Joo Park, Rak-Hyun Song, Jong-Won Lee
ABSTRACT(Mn,Cu)3O4-based conductive oxides are examined as protective coatings to improve the surface stability of metallic interconnects for solid oxide fuel cells at high temperatures. Nano-sized Mn3 − xCuxO4 materials with various Cu contents (x = 1.0–1.5) are synthesized and a composition-structure–property relationship is experimentally determined. The Cu content (x) has a significant influence on phase stability as well as sintering, electrical, and thermal expansion characteristics. Thin and dense Mn3 − xCuxO4 coatings are fabricated on the interconnects (Crofer 22 APU) by a slurry coating process and subsequent heat treatment. The coated interconnects exhibit area-specific resistances as low as 7.1–15.0 mΩ cm2 at 800 °C. The electrochemical cell shows no performance degradation in the presence of the Mn3 − xCuxO4-coated interconnect. The results indicate that the Mn3 − xCuxO4 coatings act as an effective barrier to high-temperature oxidation of the metallic interconnects. More... »
PAGES445-452
http://scigraph.springernature.com/pub.10.1007/s10008-013-2245-6
DOIhttp://dx.doi.org/10.1007/s10008-013-2245-6
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