The effect of the system polydispersity on voltammograms of nanoparticles electrooxidation View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2013-01

AUTHORS

Kh. Z. Brainina, L. G. Galperin, Е. V. Vikulova, A. L. Galperin

ABSTRACT

The paper proposes a mathematical model describing electrooxidation of a polydisperse system of metal nanoparticles from the surface of an indifferent macro-electrode. It is shown that the degree of dispersion of a nanoparticle ensemble affects the shape of oxidation voltammograms. When the degree of dispersion rises and the average size of nanoparticles becomes smaller, the range of oxidation potentials increases. The results of the experimental study of electrooxidation of gold nanoparticles with different degrees of dispersion are given. The particles were localized on the surface of graphite screen-printed electrodes. A good agreement between the parameters of the experimental and calculated voltammograms confirms the correctness of the proposed model. More... »

PAGES

43-53

References to SciGraph publications

  • 2012-07. Electrochemistry of metal nanoparticles: the effect of substrate in JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • 2010-06. Mathematical modeling and numerical simulation of metal nanoparticles electrooxidation in JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • 2011-12. Bismuth nanoparticles electrooxidation: theory and experiment in JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • 2012-07. Silver nanoparticles electrooxidation: theory and experiment in JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • 2011-05. Gold nanoparticles electrooxidation: comparison of theory and experiment in JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s10008-012-1852-y

    DOI

    http://dx.doi.org/10.1007/s10008-012-1852-y

    DIMENSIONS

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