Partial stripping of Ag atoms from silver bilayer on a Au(111) surface accompanied with the reductive desorption of hexanethiol SAM View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-07

AUTHORS

Toshihiro Kondo, Kazuhisa Tamura, Satoru Takakusagi, Ken Kitamura, Masamitu Takahasi, Jun’ichiro Mizuki, Kohei Uosaki

ABSTRACT

The interfacial structures of Ag bilayer prepared by underpotential deposition on Au(111) (Ag(2ML)/Au(111)) were determined by ex situ scanning tunneling microscopy and in situ surface X-ray scattering measurements before and after oxidative adsorption and after reductive desorption of a self-assembled monolayer (SAM) of hexanethiol (C6SH) in alkaline ethanol solution. While no structural change was observed after oxidative formation of C6SH SAM on the Ag(2ML)/Au(111) in an ethanol solution containing 20 mM KOH and 0.1 mM C6SH, some of the Ag atoms in the bilayer were stripped when the SAM was reductively desorbed. More... »

PAGES

1141-1145

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10008-008-0764-3

DOI

http://dx.doi.org/10.1007/s10008-008-0764-3

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1036040979


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