LiNi0.8Co0.2−xTixO2 nanoparticles: synthesis, structure, and evaluation of electrochemical properties for lithium ion cell application View Full Text


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Article Info

DATE

2007-04-21

AUTHORS

R. Sathiyamoorthi, P. Santhosh, P. Shakkthivel, T. Vasudevan

ABSTRACT

Layered Ti-doped lithiated nickel cobaltate, LiNi0.8Co0.2 − xTixO2 (where x = 0.01, 0.03, and 0.05) nanopowders were prepared by wet-chemistry technique. The structural properties of synthesized materials were characterized by X-ray diffraction (XRD) and thermo-gravimetric/differential thermal analysis (TG/DTA). The morphological changes brought about by the changes in composition of LiNi0.8Co0.2 − xTixO2 particles were examined through surface examination techniques such as scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analyses. Electrochemical studies were carried out using 2016-type coin cell in the voltage range of 3.0–4.5 V (vs carbon) using 1 M LiClO4 in ethylene carbonate and diethyl carbonate as the electrolyte. Among the various concentrations of Ti-doped lithiated nickel cobaltate materials, C/LiNi0.8Co0.17Ti0.03O2 cell gives stable charge–discharge features. More... »

PAGES

1665-1669

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10008-007-0320-6

DOI

http://dx.doi.org/10.1007/s10008-007-0320-6

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https://app.dimensions.ai/details/publication/pub.1008586594


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