Using the same organocatalyst for asymmetric synthesis of both enantiomers of glutamic acid-derived Ni(II) complexes via 1,4-additions of achiral glycine ... View Full Text


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Article Info

DATE

2012-07

AUTHORS

Yuri N. Belokon, Zalina T. Gugkaeva, Karine V. Hakobyan, Victor I. Maleev, Margarita A. Moskalenko, Victor N. Khrustalev, Ashot S. Saghyan, Alan T. Tsaloev, Kiryl K. Babievsky

ABSTRACT

(S)- and (R)-BIMBOL were efficient PT catalysts of asymmetric Michael addition of prochiral Ni-PBP-Gly (1) to acrylic esters and malonic esters to Ni-PBP-Δ-Ala (2) correspondingly. The salient feature of the catalysis is opposite configurations of Glu prepared via the two paths with BIMBOL of the same configuration and a perspective novel catalytic procedure for the synthesis of Gla derivatives. More... »

PAGES

299-308

References to SciGraph publications

  • 1999. Protonation of Enolates in COMPREHENSIVE ASYMMETRIC CATALYSIS I–III
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s00726-011-1076-y

    DOI

    http://dx.doi.org/10.1007/s00726-011-1076-y

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1028290652

    PUBMED

    https://www.ncbi.nlm.nih.gov/pubmed/21935708


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