NMR Line Shape for a Rectangular Configuration of Nuclei View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-12

AUTHORS

M. R. Gallyamov, N. K. Moroz, S. G. Kozlova

ABSTRACT

We present an approach to describe nuclear magnetic resonance absorption of dipolar-coupled rectangular configuration of nuclear spins associated with reorientation of ethylene bridge (–CH2–CH2–) in the crystal. The approach was applied to investigate reorientational mobility of dabco-linkers (1,4-diazobycyclo[2,2,2]octane) in metal–organic framework [Zn2(bdc)2(dabco)] (bdc—benzenedicarboxylate). Dabco rotation around the N–N axis is shown to remain down to 80 K and the activation energy of the molecule reorientation does not exceed 12 kJ/mol. More... »

PAGES

477-482

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s00723-011-0278-5

DOI

http://dx.doi.org/10.1007/s00723-011-0278-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1014752403


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