Synthesis and Structural, Magnetic and EPR Characterization of Discrete Finite Antiferromagnetic Chains View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2009-11-15

AUTHORS

Michael L. Baker, Marzio Rancan, Floriana Tuna, Grigore A. Timco, David Collison, Hannu Mutka, Hans-Ulrich Güdel, Robin J. Pritchard, Richard E. P. Winpenny, Eric J. L. McInnes

ABSTRACT

The synthesis, magnetic and electron paramagnetic resonance (EPR) characterisation of isolated, discrete, {CrnIII} antiferromagnetically coupled chain complexes is reported for n = 6 and 7. Previous studies had reported supramolecular linked {CrnIII}x species. For n = 6, the lowest lying total spin state is diamagnetic with S = 1 and 2 first and second excited states, respectively; for n = 7, the lowest lying total spin state is S = 3/2 with S = 1/2 and 5/2 first and second excited states, respectively. The zero-field splittings of these states are well defined by low-temperature, multi-frequency EPR spectroscopy. More... »

PAGES

685

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s00723-009-0063-x

DOI

http://dx.doi.org/10.1007/s00723-009-0063-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1004390518


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