Genetic significance of the 867 cm− 1 out-of-plane Raman mode in graphite associated with V-bearing green grossular View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-10

AUTHORS

Rainer Thomas, Adolf Rericha, Walter L. Pohl, Paul Davidson

ABSTRACT

SE Kenya is the world’s largest producer of green vanadium grossular gemstones (tsavorite). Samples from one of the mines near Mwatate, and of occurrences in Tanzania yielded remarkable new insights into the genesis of tsavorite. Graphite is intimately associated with V-grossular and is one of the keys to understanding its origin. In the course of this study we found five different types of graphite. Surprisingly, in one graphite type the “Raman-forbidden” and IR-active 867 cm− 1 band was observed. In this communication, we attempt to find an explanation for this unusual phenomenon. Additionally, our observations also address some of the issues pertaining to the origin of the green grossular-dominated rocks (grossularites), as well as the gem quality tsavorite crystals, since we propose that the anomalous spectroscopic behavior of the graphite is related to the unusual conditions during crystallization of both the grossular and graphite from a near-supercritical volatile- and sulfur-rich silicate melt. The massive green vanadium grossular contains abundant unequivocal crystallized melt inclusions, while the transparent gem quality grossular (tsavorite) displays only fluid inclusions. On the basis of inclusion studies we suggest that anatectic melts originated in the peculiar evaporitic host lithology of the tsavorite deposits. Near peak metamorphic temperatures (~ 700 °C) these liquids occurred as a supercritical volatile-rich “fluid/melt phase” characterized by complete miscibility between H2O and silicate liquid. Relatively dry liquid batches precipitated non-transparent green grossular, whereas wet batches segregated fluids that formed transparent tsavorite. More... »

PAGES

633-645

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s00710-018-0563-1

DOI

http://dx.doi.org/10.1007/s00710-018-0563-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1101719594


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0403", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Geology", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/04", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Earth Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Helmholtz Centre Potsdam - GFZ German Research Centre for Geosciences", 
          "id": "https://www.grid.ac/institutes/grid.23731.34", 
          "name": [
            "Helmholtz-Centre Potsdam, German Research Centre for Geoscience \u2013 GFZ, Section 4.3., Chemistry and Physics of Earth Materials, Telegrafenberg, 14473, Potsdam, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Thomas", 
        "givenName": "Rainer", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Alemannenstr. 4a, 14612, Falkensee, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rericha", 
        "givenName": "Adolf", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Austrian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4299.6", 
          "name": [
            "Austrian Academy of Sciences, Dr. Ignaz Seipel-Platz 2, 1010, Vienna, Austria"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pohl", 
        "givenName": "Walter L.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Tasmania", 
          "id": "https://www.grid.ac/institutes/grid.1009.8", 
          "name": [
            "CODES, Centre for Ore Deposit and Earth Science, University of Tasmania, 7001, Hobart, Australia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Davidson", 
        "givenName": "Paul", 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1038/385710a0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003507884", 
          "https://doi.org/10.1038/385710a0"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.oregeorev.2016.09.017", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005191511"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0025-5416(77)90027-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006231148"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0025-5416(77)90027-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006231148"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1098/rsta.2004.1454", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006357719"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1139/v73-106", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008710298"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1111/j.1525-1314.2004.00553.x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009958006"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0016-7037(85)90260-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011084404"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0016-7037(85)90260-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011084404"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0256-307x/18/12/332", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013538616"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1515/9783110417104-003", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015915446"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1111/j.1525-1314.2011.00929.x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016306572"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.2138/am.2014.4311", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019263783"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/3-540-32344-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020152702", 
          "https://doi.org/10.1007/3-540-32344-9"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/3-540-32344-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020152702", 
          "https://doi.org/10.1007/3-540-32344-9"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1179/1743275815y.0000000014", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021138186"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0016702908060025", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027996436", 
          "https://doi.org/10.1134/s0016702908060025"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0038-1098(77)90663-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028171236"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0038-1098(77)90663-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028171236"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.oregeorev.2015.10.004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029771101"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00710-012-0210-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030414659", 
          "https://doi.org/10.1007/s00710-012-0210-1"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00410-002-0368-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030866320", 
          "https://doi.org/10.1007/s00410-002-0368-3"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/zaac.19562880302", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031698917"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.crte.2010.06.003", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037466932"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0743-9547(96)00066-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038530593"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jafrearsci.2013.06.004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041002909"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0896-8446(98)00095-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043633150"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.oregeorev.2013.01.016", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043992031"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00126-013-0489-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044079490", 
          "https://doi.org/10.1007/s00126-013-0489-9"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.molstruc.2013.07.051", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045603103"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1046/j.1525-1314.2002.00408.x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050895410"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/aenm.201400482", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052591707"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.59.62", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060591872"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.59.62", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060591872"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.61.7752", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060596301"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.61.7752", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060596301"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.66.104109", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060604337"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.66.104109", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060604337"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1127/1860-1804/2012/0163-0113", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062700734"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.15506/jog.2013.33.5.161", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1067850338"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.15506/jog.2014.34.3.230", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1067850389"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00710-016-0489-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1083694837", 
          "https://doi.org/10.1007/s00710-016-0489-4"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00710-016-0489-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1083694837", 
          "https://doi.org/10.1007/s00710-016-0489-4"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00126-017-0738-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1085577224", 
          "https://doi.org/10.1007/s00126-017-0738-4"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00126-017-0738-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1085577224", 
          "https://doi.org/10.1007/s00126-017-0738-4"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1180/emu-notes.12.12", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1090269456"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.3749/canmin.1600085", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1090970266"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.3749/canmin.1700019", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1092161013"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1130/g39634.1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1092172998"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2018-10", 
    "datePublishedReg": "2018-10-01", 
    "description": "SE Kenya is the world\u2019s largest producer of green vanadium grossular gemstones (tsavorite). Samples from one of the mines near Mwatate, and of occurrences in Tanzania yielded remarkable new insights into the genesis of tsavorite. Graphite is intimately associated with V-grossular and is one of the keys to understanding its origin. In the course of this study we found five different types of graphite. Surprisingly, in one graphite type the \u201cRaman-forbidden\u201d and IR-active 867 cm\u2212 1 band was observed. In this communication, we attempt to find an explanation for this unusual phenomenon. Additionally, our observations also address some of the issues pertaining to the origin of the green grossular-dominated rocks (grossularites), as well as the gem quality tsavorite crystals, since we propose that the anomalous spectroscopic behavior of the graphite is related to the unusual conditions during crystallization of both the grossular and graphite from a near-supercritical volatile- and sulfur-rich silicate melt. The massive green vanadium grossular contains abundant unequivocal crystallized melt inclusions, while the transparent gem quality grossular (tsavorite) displays only fluid inclusions. On the basis of inclusion studies we suggest that anatectic melts originated in the peculiar evaporitic host lithology of the tsavorite deposits. Near peak metamorphic temperatures (~ 700 \u00b0C) these liquids occurred as a supercritical volatile-rich \u201cfluid/melt phase\u201d characterized by complete miscibility between H2O and silicate liquid. Relatively dry liquid batches precipitated non-transparent green grossular, whereas wet batches segregated fluids that formed transparent tsavorite.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s00710-018-0563-1", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1053337", 
        "issn": [
          "0930-0708", 
          "1438-1168"
        ], 
        "name": "Mineralogy and Petrology", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "5", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "112"
      }
    ], 
    "name": "Genetic significance of the 867 cm\u2212 1 out-of-plane Raman mode in graphite associated with V-bearing green grossular", 
    "pagination": "633-645", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "f311df426edf59da77eefa08fb9f07995d727a7e00693412a52b1602cc3847f1"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s00710-018-0563-1"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1101719594"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s00710-018-0563-1", 
      "https://app.dimensions.ai/details/publication/pub.1101719594"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T12:53", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000364_0000000364/records_72847_00000001.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1007%2Fs00710-018-0563-1"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s00710-018-0563-1'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s00710-018-0563-1'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s00710-018-0563-1'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s00710-018-0563-1'


 

This table displays all metadata directly associated to this object as RDF triples.

214 TRIPLES      21 PREDICATES      67 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s00710-018-0563-1 schema:about anzsrc-for:04
2 anzsrc-for:0403
3 schema:author Nb48451a8a5f341d9be3b4722c5c102e1
4 schema:citation sg:pub.10.1007/3-540-32344-9
5 sg:pub.10.1007/s00126-013-0489-9
6 sg:pub.10.1007/s00126-017-0738-4
7 sg:pub.10.1007/s00410-002-0368-3
8 sg:pub.10.1007/s00710-012-0210-1
9 sg:pub.10.1007/s00710-016-0489-4
10 sg:pub.10.1038/385710a0
11 sg:pub.10.1134/s0016702908060025
12 https://doi.org/10.1002/aenm.201400482
13 https://doi.org/10.1002/zaac.19562880302
14 https://doi.org/10.1016/0016-7037(85)90260-1
15 https://doi.org/10.1016/0025-5416(77)90027-1
16 https://doi.org/10.1016/0038-1098(77)90663-9
17 https://doi.org/10.1016/j.crte.2010.06.003
18 https://doi.org/10.1016/j.jafrearsci.2013.06.004
19 https://doi.org/10.1016/j.molstruc.2013.07.051
20 https://doi.org/10.1016/j.oregeorev.2013.01.016
21 https://doi.org/10.1016/j.oregeorev.2015.10.004
22 https://doi.org/10.1016/j.oregeorev.2016.09.017
23 https://doi.org/10.1016/s0743-9547(96)00066-9
24 https://doi.org/10.1016/s0896-8446(98)00095-3
25 https://doi.org/10.1046/j.1525-1314.2002.00408.x
26 https://doi.org/10.1088/0256-307x/18/12/332
27 https://doi.org/10.1098/rsta.2004.1454
28 https://doi.org/10.1103/physrevb.59.62
29 https://doi.org/10.1103/physrevb.61.7752
30 https://doi.org/10.1103/physrevb.66.104109
31 https://doi.org/10.1111/j.1525-1314.2004.00553.x
32 https://doi.org/10.1111/j.1525-1314.2011.00929.x
33 https://doi.org/10.1127/1860-1804/2012/0163-0113
34 https://doi.org/10.1130/g39634.1
35 https://doi.org/10.1139/v73-106
36 https://doi.org/10.1179/1743275815y.0000000014
37 https://doi.org/10.1180/emu-notes.12.12
38 https://doi.org/10.1515/9783110417104-003
39 https://doi.org/10.15506/jog.2013.33.5.161
40 https://doi.org/10.15506/jog.2014.34.3.230
41 https://doi.org/10.2138/am.2014.4311
42 https://doi.org/10.3749/canmin.1600085
43 https://doi.org/10.3749/canmin.1700019
44 schema:datePublished 2018-10
45 schema:datePublishedReg 2018-10-01
46 schema:description SE Kenya is the world’s largest producer of green vanadium grossular gemstones (tsavorite). Samples from one of the mines near Mwatate, and of occurrences in Tanzania yielded remarkable new insights into the genesis of tsavorite. Graphite is intimately associated with V-grossular and is one of the keys to understanding its origin. In the course of this study we found five different types of graphite. Surprisingly, in one graphite type the “Raman-forbidden” and IR-active 867 cm− 1 band was observed. In this communication, we attempt to find an explanation for this unusual phenomenon. Additionally, our observations also address some of the issues pertaining to the origin of the green grossular-dominated rocks (grossularites), as well as the gem quality tsavorite crystals, since we propose that the anomalous spectroscopic behavior of the graphite is related to the unusual conditions during crystallization of both the grossular and graphite from a near-supercritical volatile- and sulfur-rich silicate melt. The massive green vanadium grossular contains abundant unequivocal crystallized melt inclusions, while the transparent gem quality grossular (tsavorite) displays only fluid inclusions. On the basis of inclusion studies we suggest that anatectic melts originated in the peculiar evaporitic host lithology of the tsavorite deposits. Near peak metamorphic temperatures (~ 700 °C) these liquids occurred as a supercritical volatile-rich “fluid/melt phase” characterized by complete miscibility between H2O and silicate liquid. Relatively dry liquid batches precipitated non-transparent green grossular, whereas wet batches segregated fluids that formed transparent tsavorite.
47 schema:genre research_article
48 schema:inLanguage en
49 schema:isAccessibleForFree false
50 schema:isPartOf N9ed1f646c3a14d32b642188ed88d9b56
51 Nc5233ef71c5a40f88d7fa39730a3a122
52 sg:journal.1053337
53 schema:name Genetic significance of the 867 cm− 1 out-of-plane Raman mode in graphite associated with V-bearing green grossular
54 schema:pagination 633-645
55 schema:productId N4a44d8257a6a44399945cb8817585650
56 N8a7ac25bae894b3b93095b5ae04b0653
57 Ndb4f115cfdbb48b7a18e3ff79a123f9b
58 schema:sameAs https://app.dimensions.ai/details/publication/pub.1101719594
59 https://doi.org/10.1007/s00710-018-0563-1
60 schema:sdDatePublished 2019-04-11T12:53
61 schema:sdLicense https://scigraph.springernature.com/explorer/license/
62 schema:sdPublisher Nfd94331b94b048adbf7a2a549a139258
63 schema:url https://link.springer.com/10.1007%2Fs00710-018-0563-1
64 sgo:license sg:explorer/license/
65 sgo:sdDataset articles
66 rdf:type schema:ScholarlyArticle
67 N08db2e5581e14976860863c6970ae7cb schema:affiliation https://www.grid.ac/institutes/grid.1009.8
68 schema:familyName Davidson
69 schema:givenName Paul
70 rdf:type schema:Person
71 N0c7e92df23064c8cbf15dd9a2efd9774 rdf:first N08db2e5581e14976860863c6970ae7cb
72 rdf:rest rdf:nil
73 N306f2f2b8ba1466e8fb65c1ec5a8d0e9 schema:affiliation https://www.grid.ac/institutes/grid.4299.6
74 schema:familyName Pohl
75 schema:givenName Walter L.
76 rdf:type schema:Person
77 N4a44d8257a6a44399945cb8817585650 schema:name doi
78 schema:value 10.1007/s00710-018-0563-1
79 rdf:type schema:PropertyValue
80 N57e16cdf79ac4c2c8f143fb1da7b3d53 schema:affiliation Neef0334dc6dd4deeb56d6b0a0e5205c5
81 schema:familyName Rericha
82 schema:givenName Adolf
83 rdf:type schema:Person
84 N8a7ac25bae894b3b93095b5ae04b0653 schema:name readcube_id
85 schema:value f311df426edf59da77eefa08fb9f07995d727a7e00693412a52b1602cc3847f1
86 rdf:type schema:PropertyValue
87 N9ed1f646c3a14d32b642188ed88d9b56 schema:volumeNumber 112
88 rdf:type schema:PublicationVolume
89 Na1ceba65b4904c2693835a86cba7a7ab rdf:first N306f2f2b8ba1466e8fb65c1ec5a8d0e9
90 rdf:rest N0c7e92df23064c8cbf15dd9a2efd9774
91 Nb48451a8a5f341d9be3b4722c5c102e1 rdf:first Nd914e2d553b947fa8ea1bad5aa76b65f
92 rdf:rest Ncc6d36c424654c0f9f373633586524c0
93 Nc5233ef71c5a40f88d7fa39730a3a122 schema:issueNumber 5
94 rdf:type schema:PublicationIssue
95 Ncc6d36c424654c0f9f373633586524c0 rdf:first N57e16cdf79ac4c2c8f143fb1da7b3d53
96 rdf:rest Na1ceba65b4904c2693835a86cba7a7ab
97 Nd914e2d553b947fa8ea1bad5aa76b65f schema:affiliation https://www.grid.ac/institutes/grid.23731.34
98 schema:familyName Thomas
99 schema:givenName Rainer
100 rdf:type schema:Person
101 Ndb4f115cfdbb48b7a18e3ff79a123f9b schema:name dimensions_id
102 schema:value pub.1101719594
103 rdf:type schema:PropertyValue
104 Neef0334dc6dd4deeb56d6b0a0e5205c5 schema:name Alemannenstr. 4a, 14612, Falkensee, Germany
105 rdf:type schema:Organization
106 Nfd94331b94b048adbf7a2a549a139258 schema:name Springer Nature - SN SciGraph project
107 rdf:type schema:Organization
108 anzsrc-for:04 schema:inDefinedTermSet anzsrc-for:
109 schema:name Earth Sciences
110 rdf:type schema:DefinedTerm
111 anzsrc-for:0403 schema:inDefinedTermSet anzsrc-for:
112 schema:name Geology
113 rdf:type schema:DefinedTerm
114 sg:journal.1053337 schema:issn 0930-0708
115 1438-1168
116 schema:name Mineralogy and Petrology
117 rdf:type schema:Periodical
118 sg:pub.10.1007/3-540-32344-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020152702
119 https://doi.org/10.1007/3-540-32344-9
120 rdf:type schema:CreativeWork
121 sg:pub.10.1007/s00126-013-0489-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044079490
122 https://doi.org/10.1007/s00126-013-0489-9
123 rdf:type schema:CreativeWork
124 sg:pub.10.1007/s00126-017-0738-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1085577224
125 https://doi.org/10.1007/s00126-017-0738-4
126 rdf:type schema:CreativeWork
127 sg:pub.10.1007/s00410-002-0368-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030866320
128 https://doi.org/10.1007/s00410-002-0368-3
129 rdf:type schema:CreativeWork
130 sg:pub.10.1007/s00710-012-0210-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030414659
131 https://doi.org/10.1007/s00710-012-0210-1
132 rdf:type schema:CreativeWork
133 sg:pub.10.1007/s00710-016-0489-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1083694837
134 https://doi.org/10.1007/s00710-016-0489-4
135 rdf:type schema:CreativeWork
136 sg:pub.10.1038/385710a0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003507884
137 https://doi.org/10.1038/385710a0
138 rdf:type schema:CreativeWork
139 sg:pub.10.1134/s0016702908060025 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027996436
140 https://doi.org/10.1134/s0016702908060025
141 rdf:type schema:CreativeWork
142 https://doi.org/10.1002/aenm.201400482 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052591707
143 rdf:type schema:CreativeWork
144 https://doi.org/10.1002/zaac.19562880302 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031698917
145 rdf:type schema:CreativeWork
146 https://doi.org/10.1016/0016-7037(85)90260-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011084404
147 rdf:type schema:CreativeWork
148 https://doi.org/10.1016/0025-5416(77)90027-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006231148
149 rdf:type schema:CreativeWork
150 https://doi.org/10.1016/0038-1098(77)90663-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028171236
151 rdf:type schema:CreativeWork
152 https://doi.org/10.1016/j.crte.2010.06.003 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037466932
153 rdf:type schema:CreativeWork
154 https://doi.org/10.1016/j.jafrearsci.2013.06.004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041002909
155 rdf:type schema:CreativeWork
156 https://doi.org/10.1016/j.molstruc.2013.07.051 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045603103
157 rdf:type schema:CreativeWork
158 https://doi.org/10.1016/j.oregeorev.2013.01.016 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043992031
159 rdf:type schema:CreativeWork
160 https://doi.org/10.1016/j.oregeorev.2015.10.004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029771101
161 rdf:type schema:CreativeWork
162 https://doi.org/10.1016/j.oregeorev.2016.09.017 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005191511
163 rdf:type schema:CreativeWork
164 https://doi.org/10.1016/s0743-9547(96)00066-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038530593
165 rdf:type schema:CreativeWork
166 https://doi.org/10.1016/s0896-8446(98)00095-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043633150
167 rdf:type schema:CreativeWork
168 https://doi.org/10.1046/j.1525-1314.2002.00408.x schema:sameAs https://app.dimensions.ai/details/publication/pub.1050895410
169 rdf:type schema:CreativeWork
170 https://doi.org/10.1088/0256-307x/18/12/332 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013538616
171 rdf:type schema:CreativeWork
172 https://doi.org/10.1098/rsta.2004.1454 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006357719
173 rdf:type schema:CreativeWork
174 https://doi.org/10.1103/physrevb.59.62 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060591872
175 rdf:type schema:CreativeWork
176 https://doi.org/10.1103/physrevb.61.7752 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060596301
177 rdf:type schema:CreativeWork
178 https://doi.org/10.1103/physrevb.66.104109 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060604337
179 rdf:type schema:CreativeWork
180 https://doi.org/10.1111/j.1525-1314.2004.00553.x schema:sameAs https://app.dimensions.ai/details/publication/pub.1009958006
181 rdf:type schema:CreativeWork
182 https://doi.org/10.1111/j.1525-1314.2011.00929.x schema:sameAs https://app.dimensions.ai/details/publication/pub.1016306572
183 rdf:type schema:CreativeWork
184 https://doi.org/10.1127/1860-1804/2012/0163-0113 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062700734
185 rdf:type schema:CreativeWork
186 https://doi.org/10.1130/g39634.1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1092172998
187 rdf:type schema:CreativeWork
188 https://doi.org/10.1139/v73-106 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008710298
189 rdf:type schema:CreativeWork
190 https://doi.org/10.1179/1743275815y.0000000014 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021138186
191 rdf:type schema:CreativeWork
192 https://doi.org/10.1180/emu-notes.12.12 schema:sameAs https://app.dimensions.ai/details/publication/pub.1090269456
193 rdf:type schema:CreativeWork
194 https://doi.org/10.1515/9783110417104-003 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015915446
195 rdf:type schema:CreativeWork
196 https://doi.org/10.15506/jog.2013.33.5.161 schema:sameAs https://app.dimensions.ai/details/publication/pub.1067850338
197 rdf:type schema:CreativeWork
198 https://doi.org/10.15506/jog.2014.34.3.230 schema:sameAs https://app.dimensions.ai/details/publication/pub.1067850389
199 rdf:type schema:CreativeWork
200 https://doi.org/10.2138/am.2014.4311 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019263783
201 rdf:type schema:CreativeWork
202 https://doi.org/10.3749/canmin.1600085 schema:sameAs https://app.dimensions.ai/details/publication/pub.1090970266
203 rdf:type schema:CreativeWork
204 https://doi.org/10.3749/canmin.1700019 schema:sameAs https://app.dimensions.ai/details/publication/pub.1092161013
205 rdf:type schema:CreativeWork
206 https://www.grid.ac/institutes/grid.1009.8 schema:alternateName University of Tasmania
207 schema:name CODES, Centre for Ore Deposit and Earth Science, University of Tasmania, 7001, Hobart, Australia
208 rdf:type schema:Organization
209 https://www.grid.ac/institutes/grid.23731.34 schema:alternateName Helmholtz Centre Potsdam - GFZ German Research Centre for Geosciences
210 schema:name Helmholtz-Centre Potsdam, German Research Centre for Geoscience – GFZ, Section 4.3., Chemistry and Physics of Earth Materials, Telegrafenberg, 14473, Potsdam, Germany
211 rdf:type schema:Organization
212 https://www.grid.ac/institutes/grid.4299.6 schema:alternateName Austrian Academy of Sciences
213 schema:name Austrian Academy of Sciences, Dr. Ignaz Seipel-Platz 2, 1010, Vienna, Austria
214 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...