Studies on the Anode/Electrolyte Interfacein Lithium Ion Batteries View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2001-04

AUTHORS

Martin Winter, Wolfgang K. Appel, Bernd Evers, Tomásě Hodal, Kai-Christian Möller, Ingo Schneider, Mario Wachtler, Markus R. Wagner, Gerhard H. Wrodnigg, Jürgen O. Besenhard

ABSTRACT

Rechargeable lithium ion cells operate at voltages of 3.5–4.5 V, which is far beyond the thermodynamic stability window of the battery electrolyte. Strong electrolyte reduction and anode corrosion has to be anticipated, leading to irreversible loss of electroactive material and electrolyte and thus strongly deteriorating cell performance. To minimize these reactions, anode and electrolyte components have to be combined that induce the electrolyte reduction products to form an effectively protecting film at the anode/electrolyte interface, which hinders further electrolyte decomposition reactions, but acts as membrane for the lithium cations, i.e. behaving as a solid electrolyte interphase (SEI). This paper focuses on important aspects of the SEI. By using key examples, the effects of film forming electrolyte additives and the change of the active anode material from carbons to lithium storage alloys are highlighted. More... »

PAGES

473-486

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s007060170110

DOI

http://dx.doi.org/10.1007/s007060170110

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1020188295


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