Benzil/triethylamine: a photo-reducing system for Cu2+ View Full Text


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Article Info

DATE

2018-03

AUTHORS

Max Schmallegger, Georg Gescheidt

ABSTRACT

: We have investigated the photo-induced reduction of Cu2+-Cu0 using benzil/triethylamine mixtures. The formation of elemental Cu is indicated by the appearance of its characteristic plasmon absorption peaks at 515 nm and 620 nm. Importantly, the nature of the counterion of the Cu2+ salt affects the reduction process. In the presence of Cl-, the reduction proceeds faster than with SO42-. Photo-induced electron transfer between excited benzil and triethylamine leads to the benzil radical anion, which acts as the reducing agent for Cu2+ and generates Cu0. Graphical abstract: More... »

PAGES

499-504

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s00706-017-2085-7

DOI

http://dx.doi.org/10.1007/s00706-017-2085-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1100809011

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/29576659


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