Crystal structure and antimicrobial activity of a transplatin adduct of N,N′-dimethylthiourea, trans-[Pt(NH3)2(dmtu)2]Cl2 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-08-25

AUTHORS

Saeed Ahmad, Seerat-ur-Rehman, Tobias Rüffer, Tanzeel Khalid, Anvarhusein A. Isab, Abdul Rahman Al-Arfaj, Muhammad Saleem, Ejaz, Islam Ullah Khan, Muhammad Aziz Choudhary

ABSTRACT

The crystal structure of a transplatin-derived complex, trans-[Pt(NH3)2(dmtu)2]Cl2 (dmtu = N,N’-dimethylthiourea) was determined by X-ray crystallography and its antimicrobial activities were evaluated by minimum inhibitory concentration. The structure consists of trans-[Pt(NH3)2(dmtu)2]2+ cation and two chloride ions. In trans-[Pt(NH3)2(dmtu)2]2+, the geometry at platinum is nearly regular square planar with the average cis and trans angles of 90 and 178.6°, respectively. The 1H and 13C NMR spectral data indicated the coordination of both ligands to platinum(II). The results of antimicrobial studies showed that the complex exhibited significant activity against gram-negative bacteria (Escherichia coli, Pseudomonas aeruginosa), while relatively poor activities were observed against molds (Aspergillus niger, Penicillium citrinum) and yeasts (Candida albicans, Saccharomyces cerevisiae).Graphical abstract More... »

PAGES

669-674

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s00706-016-1809-4

DOI

http://dx.doi.org/10.1007/s00706-016-1809-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032209904


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