Dimethylaminomethylene derivatives of S,S-dioxides of 1,4-benzothiazepin-3(2H)-one and 4,1-benzothiazepin-2(3H)-one: comparison of interaction with nucleophiles View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-12

AUTHORS

Taras M. Tarasiuk, Tetiana A. Volovnenko, Yulian M. Volovenko, Volodymyr V. Medviediev, Oleg V. Shishkin

ABSTRACT

Reactions of dimethylaminomethylene derivatives of 4,5-dihydro-1,4-benzothiazepin-3(2H)-one 1,1-dioxide and 1,5-dihydro-4,1-benzothiazepin-2(3H)-one 4,4-dioxide with O-nucleophile (hydroxide ion) and N-nucleophiles (aliphatic and aromatic amines, hydroxylamine, hydrazine, phenylhydrazines, N,N-dimethylhydrazine, amidines, and esters of amino acids) have been investigated. Compounds with a carbonyl group or a hydrogen at the nitrogen atom of the 1,4-benzothiazepine cycle are more reactive than N-Me derivatives. Products of transamination of 4,1-benzothiazepine derivatives have not been obtained, but hydrolysis led to the corresponding enol or 1,1-diol. More... »

PAGES

1987-1997

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s00706-014-1290-x

DOI

http://dx.doi.org/10.1007/s00706-014-1290-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1041120021


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