exo-2,3-Epoxybicyclo[2.2.1]heptan-endo-5,6-dicarboximides: versatile starting materials for the preparation of oxazaheterocyclic cage compounds View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-07

AUTHORS

Vitaliy A. Palchikov, Igor N. Tarabara, Oxana V. Krishchik, Irina V. Omelchenko, Svetlana V. Shishkina, Oleg V. Shishkin, Liliya I. Kasyan

ABSTRACT

A convenient method is reported for the synthesis of N-substituted exo-2-hydroxy-6-aza-4-oxatetracyclo[5.2.1.13,508,9]undecan-7-ones, exo-2-hydroxy-6-aza-4-oxatetracyclo[5.2.1.13,508,9]undecanes, and endo-8,exo-9-dihydroxy-4-azatricyclo[5.2.1.02,6]decanes in high to moderate yields. The method involves treatment of easily available exo-2,3-epoxybicyclo[2.2.1]heptan-endo-5,6-dicarboximides with LiAlH4.

PAGES

1155-1163

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s00706-014-1192-y

DOI

http://dx.doi.org/10.1007/s00706-014-1192-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1039618563


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