One-dimensional coordination polymer of copper(I) thiocyanate with the Schiff base ligand N,N′-bis(3,4-dimethoxybenzylidene)butane-1,4-diamine: synthesis, crystal structure, spectroscopic and thermal properties View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-04

AUTHORS

Aliakbar Dehno Khalaji, Helen Stoeckli-Evans, Debasis Das

ABSTRACT

A new one-dimensional polymeric copper(I)–thiocyanate complex with the Schiff base ligand N,N′-bis(3,4-dimethoxybenzylidene)butane-1,4-diamine, {Cu2((μN,N′-3,4-MeO-ba)2bn)(μ1,3-NCS)2}n, was synthesized and characterized by elemental analysis, 1H and 13C NMR, FT–IR spectroscopy, and thermal analysis. The thermal behavior of the complex was studied using thermogravimetry in order to evaluate thermal stability and thermal decomposition pathways. The molecular structure of the complex was determined by single-crystal X-ray diffraction which revealed that the coordination geometry around the copper(I) ion is distorted trigonal. The Schiff base ligand (3,4-MeO-ba)2bn acts as a bis-monodentate and bridging ligand (μN,N′) and coordinates via two N atoms to the metal centers and adopts an E,E conformation. The coordination spheres of the metal atoms are completed by the N and S atoms from two thiocyanate anion bridges (μ1,3-NCS), forming a zigzag chain propagating along [001]. More... »

PAGES

595-600

References to SciGraph publications

  • 2007-03. Schiff Base Complexes in Macromolecules in JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
  • 2010-01. Synthesis, crystal structure, and third-order nonlinear optical properties of a copper(I) one-dimensional coordination polymer in RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s00706-011-0627-y

    DOI

    http://dx.doi.org/10.1007/s00706-011-0627-y

    DIMENSIONS

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