Asymmetric Catalysis. Part 149 [1]. Synthesis of New Chiral Tridentate Ligands for Enantioselective Catalysis View Full Text


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Article Info

DATE

2003-09

AUTHORS

Henri Brunner, Christian Zettler, Manfred Zabel

ABSTRACT

The synthesis of new chiral tridentate ligands is reported which coordinate transition metals in a meridional way. The ligands contain a pyridine ring, an oxazoline ring, and a strongly coordinating diphenylphosphanyl group. The methionine-derived ligand forms a copper complex, which has been studied by X-ray crystallography. The new ligands were tested in models of enantioselective catalyses, such as hydrogenation of ketopantolactone, hydrosilylation of acetophenone, and transfer hydrogenation of acetophenone. More... »

PAGES

1253-1269

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s00706-003-0039-8

DOI

http://dx.doi.org/10.1007/s00706-003-0039-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1007355850


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