Ultrafast dynamics in ammonia clusters: analysis of protonated and unprotonated cluster ion signals View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1997-12

AUTHORS

Th. Freudenberg, W. Radloff, H.-H. Ritze, V. Stert, F. Noack, I.V. Hertel

ABSTRACT

The dynamics of ammonia clusters excited to the à state with 160 fs laser pulses of 6.2 eV was studied by pump-probe experiments with a low probe photon energy of 3.1 eV. Protonated as well as unprotonated cluster ion signals have been observed. The time evolution of both species is characteristic of the intermediate rearrangement and fragmentation processes. The observations strongly support a previously developed kinetic model for this dynamics with the signal at long delay times>6 ps reflecting the species involved in the absorption dissociation ionization (ADI) mechanism. Strong evidence is found for the formation of an internally ‘quasi protonated’ excited state and of ammoniated NH4 radicals. More... »

PAGES

267-273

References to SciGraph publications

  • 1988-12. On the photoionization and fragmentation of ammonia clusters using TPEPICO in ZEITSCHRIFT FÜR PHYSIK D ATOMS,MOLECULES AND CLUSTERS
  • 1991-12. Proton transfer in ammonia cluster cations: molecular dynamics in a self consistent field in ZEITSCHRIFT FÜR PHYSIK D ATOMS,MOLECULES AND CLUSTERS
  • 1996-09. Ultrafast fragmentation and ionisation dynamics of ammonia clusters in ZEITSCHRIFT FÜR PHYSIK D ATOMS,MOLECULES AND CLUSTERS
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s004600050322

    DOI

    http://dx.doi.org/10.1007/s004600050322

    DIMENSIONS

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