Ontology type: schema:ScholarlyArticle
2017-09-30
AUTHORSLi-Qun Jin, Nan Zhao, Zhi-Qiang Liu, Cheng-Jun Liao, Xiao-Yang Zheng, Yu-Guo Zheng
ABSTRACTThe acid-catalyzed treatment was a conventional process for xylose production from corncob. To increase the release of xylose and to reduce the by-products formation and water usage, the oxalic acid was used as catalyst to hydrolyze the corncob and the hydrolytic conditions were investigated. The highest xylose yield of 32.7 g L−1, representing 96.1% of total theoretical xylose yield, was obtained using 1.2% oxalic acid after hydrolysis for 120 min at 130 °C, which was more than 10% higher than that of sulfuric acid-catalyzed hydrolysis. Mixed acids-catalyzed hydrolysis performed a synergistic effect for xylose production and 31.7 g L−1 of xylose was reached after reacting for 90 min with oxalic acid and sulfuric acid at a ratio of 1:4 (w/w). A kinetic model was developed to elucidate the competitive reaction between xylose formation and its degradation in the hydrolysis process, and the experimental data obtained in this study were perfectly in agreement with that of predicted from the model. Furthermore, the final xylose yield of 85% was achieved after purification and crystallization. It was demonstrated that xylose production from the corncob hydrolysis with oxalic acid as the catalyst was an effective alternative to the traditional sulfuric acid-based hydrolysis. More... »
PAGES57-64
http://scigraph.springernature.com/pub.10.1007/s00449-017-1843-6
DOIhttp://dx.doi.org/10.1007/s00449-017-1843-6
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1092000193
PUBMEDhttps://www.ncbi.nlm.nih.gov/pubmed/28965246
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Engineering",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/10",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Technology",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0903",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Biomedical Engineering",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0904",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Engineering",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/1003",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Industrial Biotechnology",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Catalysis",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Hydrolysis",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Oxalic Acid",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Xylose",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Zea mays",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Engineering Research Center of Bioconversion and Biopurification of Ministry of Education, Zhejiang University of Technology, 310014, Hangzhou, People\u2019s Republic of China",
"id": "http://www.grid.ac/institutes/grid.469325.f",
"name": [
"Key Laboratory of Bioorganic Synthesis of Zhejiang Province, College of Biotechnology and Bioengineering, Zhejiang University of Technology, 310014, Hangzhou, People\u2019s Republic of China",
"Engineering Research Center of Bioconversion and Biopurification of Ministry of Education, Zhejiang University of Technology, 310014, Hangzhou, People\u2019s Republic of China"
],
"type": "Organization"
},
"familyName": "Jin",
"givenName": "Li-Qun",
"id": "sg:person.01105203476.08",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01105203476.08"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Engineering Research Center of Bioconversion and Biopurification of Ministry of Education, Zhejiang University of Technology, 310014, Hangzhou, People\u2019s Republic of China",
"id": "http://www.grid.ac/institutes/grid.469325.f",
"name": [
"Key Laboratory of Bioorganic Synthesis of Zhejiang Province, College of Biotechnology and Bioengineering, Zhejiang University of Technology, 310014, Hangzhou, People\u2019s Republic of China",
"Engineering Research Center of Bioconversion and Biopurification of Ministry of Education, Zhejiang University of Technology, 310014, Hangzhou, People\u2019s Republic of China"
],
"type": "Organization"
},
"familyName": "Zhao",
"givenName": "Nan",
"type": "Person"
},
{
"affiliation": {
"alternateName": "Engineering Research Center of Bioconversion and Biopurification of Ministry of Education, Zhejiang University of Technology, 310014, Hangzhou, People\u2019s Republic of China",
"id": "http://www.grid.ac/institutes/grid.469325.f",
"name": [
"Key Laboratory of Bioorganic Synthesis of Zhejiang Province, College of Biotechnology and Bioengineering, Zhejiang University of Technology, 310014, Hangzhou, People\u2019s Republic of China",
"Engineering Research Center of Bioconversion and Biopurification of Ministry of Education, Zhejiang University of Technology, 310014, Hangzhou, People\u2019s Republic of China"
],
"type": "Organization"
},
"familyName": "Liu",
"givenName": "Zhi-Qiang",
"id": "sg:person.01256734541.85",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01256734541.85"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Zhejiang Huakang Pharmaceutical Co., LTD., 18 Huagong Road, Huabu Town, 324302, Kaihua, People\u2019s Republic of China",
"id": "http://www.grid.ac/institutes/None",
"name": [
"Zhejiang Huakang Pharmaceutical Co., LTD., 18 Huagong Road, Huabu Town, 324302, Kaihua, People\u2019s Republic of China"
],
"type": "Organization"
},
"familyName": "Liao",
"givenName": "Cheng-Jun",
"id": "sg:person.0617267571.53",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0617267571.53"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Zhejiang Huakang Pharmaceutical Co., LTD., 18 Huagong Road, Huabu Town, 324302, Kaihua, People\u2019s Republic of China",
"id": "http://www.grid.ac/institutes/None",
"name": [
"Zhejiang Huakang Pharmaceutical Co., LTD., 18 Huagong Road, Huabu Town, 324302, Kaihua, People\u2019s Republic of China"
],
"type": "Organization"
},
"familyName": "Zheng",
"givenName": "Xiao-Yang",
"id": "sg:person.016324612243.75",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016324612243.75"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Engineering Research Center of Bioconversion and Biopurification of Ministry of Education, Zhejiang University of Technology, 310014, Hangzhou, People\u2019s Republic of China",
"id": "http://www.grid.ac/institutes/grid.469325.f",
"name": [
"Key Laboratory of Bioorganic Synthesis of Zhejiang Province, College of Biotechnology and Bioengineering, Zhejiang University of Technology, 310014, Hangzhou, People\u2019s Republic of China",
"Engineering Research Center of Bioconversion and Biopurification of Ministry of Education, Zhejiang University of Technology, 310014, Hangzhou, People\u2019s Republic of China"
],
"type": "Organization"
},
"familyName": "Zheng",
"givenName": "Yu-Guo",
"id": "sg:person.01144225405.06",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01144225405.06"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1007/s10295-003-0049-x",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1031678297",
"https://doi.org/10.1007/s10295-003-0049-x"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1385/abab:84-86:1-9:81",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1039154765",
"https://doi.org/10.1385/abab:84-86:1-9:81"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1186/s13068-014-0179-6",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1035594727",
"https://doi.org/10.1186/s13068-014-0179-6"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s00253-010-2612-5",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1002603200",
"https://doi.org/10.1007/s00253-010-2612-5"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s00449-014-1219-0",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1014125372",
"https://doi.org/10.1007/s00449-014-1219-0"
],
"type": "CreativeWork"
}
],
"datePublished": "2017-09-30",
"datePublishedReg": "2017-09-30",
"description": "The acid-catalyzed treatment was a conventional process for xylose production from corncob. To increase the release of xylose and to reduce the by-products formation and water usage, the oxalic acid was used as catalyst to hydrolyze the corncob and the hydrolytic conditions were investigated. The highest xylose yield of 32.7\u00a0g\u00a0L\u22121, representing 96.1% of total theoretical xylose yield, was obtained using 1.2% oxalic acid after hydrolysis for 120\u00a0min at 130\u00a0\u00b0C, which was more than 10% higher than that of sulfuric acid-catalyzed hydrolysis. Mixed acids-catalyzed hydrolysis performed a synergistic effect for xylose production and 31.7\u00a0g\u00a0L\u22121 of xylose was reached after reacting for 90\u00a0min with oxalic acid and sulfuric acid at a ratio of 1:4 (w/w). A kinetic model was developed to elucidate the competitive reaction between xylose formation and its degradation in the hydrolysis process, and the experimental data obtained in this study were perfectly in agreement with that of predicted from the model. Furthermore, the final xylose yield of 85% was achieved after purification and crystallization. It was demonstrated that xylose production from the corncob hydrolysis with oxalic acid as the catalyst was an effective alternative to the traditional sulfuric acid-based hydrolysis.",
"genre": "article",
"id": "sg:pub.10.1007/s00449-017-1843-6",
"inLanguage": "en",
"isAccessibleForFree": false,
"isFundedItemOf": [
{
"id": "sg:grant.8154015",
"type": "MonetaryGrant"
},
{
"id": "sg:grant.8181893",
"type": "MonetaryGrant"
}
],
"isPartOf": [
{
"id": "sg:journal.1297453",
"issn": [
"0178-515X",
"1432-0797"
],
"name": "Bioprocess and Biosystems Engineering",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "1",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "41"
}
],
"keywords": [
"corncob hydrolysis",
"sulfuric acid-catalyzed hydrolysis",
"xylose production",
"xylose yield",
"conventional process",
"highest xylose yield",
"oxalic acid",
"by-products formation",
"xylose formation",
"kinetic model",
"water usage",
"experimental data",
"hydrolysis process",
"sulfuric acid",
"acid-base hydrolysis",
"corncob",
"catalyst",
"synergistic effect",
"acid-catalyzed treatment",
"process",
"hydrolytic conditions",
"competitive reactions",
"acid-catalyzed hydrolysis",
"model",
"crystallization",
"degradation",
"formation",
"production",
"agreement",
"conditions",
"ratio",
"min",
"yield",
"effective alternative",
"hydrolysis",
"alternative",
"release of xylose",
"usage",
"effect",
"reaction",
"xylose",
"release",
"acid",
"purification",
"data",
"study",
"enhanced production",
"treatment"
],
"name": "Enhanced production of xylose from corncob hydrolysis with oxalic acid as catalyst",
"pagination": "57-64",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1092000193"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/s00449-017-1843-6"
]
},
{
"name": "pubmed_id",
"type": "PropertyValue",
"value": [
"28965246"
]
}
],
"sameAs": [
"https://doi.org/10.1007/s00449-017-1843-6",
"https://app.dimensions.ai/details/publication/pub.1092000193"
],
"sdDataset": "articles",
"sdDatePublished": "2022-06-01T22:18",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220601/entities/gbq_results/article/article_744.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1007/s00449-017-1843-6"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s00449-017-1843-6'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s00449-017-1843-6'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s00449-017-1843-6'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s00449-017-1843-6'
This table displays all metadata directly associated to this object as RDF triples.
204 TRIPLES
22 PREDICATES
87 URIs
71 LITERALS
12 BLANK NODES