Effects of strong network modifiers on Fe3+/Fe2+ in silicate melts: an experimental study View Full Text


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Article Info

DATE

2017-05

AUTHORS

Alexander Borisov, Harald Behrens, Francois Holtz

ABSTRACT

The effect of CaO, Na2O, and K2O on ferric/ferrous ratio in model multicomponent silicate melts was investigated in the temperature range 1450–1550 °C at 1-atm total pressure in air. It is demonstrated that the addition of these network modifier cations results in an increase of Fe3+/Fe2+ ratio. The influence of network modifier cations on the ferric/ferrous ratio increases in the order Ca < Na < K. Some old controversial conceptions concerning the effect of potassium on Fe3+/Fe2+ ratio in simple model liquids are critically evaluated. An empirical equation is proposed to predict the ferric/ferrous ratio in SiO2–TiO2–Al2O3–FeO–Fe2O3–MgO–CaO–Na2O–K2O–P2O5 melts at air conditions. More... »

PAGES

34

References to SciGraph publications

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    http://scigraph.springernature.com/pub.10.1007/s00410-017-1337-1

    DOI

    http://dx.doi.org/10.1007/s00410-017-1337-1

    DIMENSIONS

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    HOW TO GET THIS DATA PROGRAMMATICALLY:

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