Ontology type: schema:ScholarlyArticle
2015-02
AUTHORSAlexander Borisov, Harald Behrens, Francois Holtz
ABSTRACTThe effect of Al2O3, MgO and total iron on the ferric/ferrous ratio in silicate melts was investigated in model silicate melts in the temperature range 1400–1550 °C at 1 atm total pressure. The experiments were done mostly in air and partially in pure CO2. It is demonstrated that an increase in Al2O3 concentration in a basaltic melt results in a moderate decrease of Fe3+/Fe2+ ratio. In contrast, the increase in Al2O3 in more silicic melts results in a much more pronounced decrease of Fe3+/Fe2+ ratio. The increase of MgO concentration in a basaltic melt results in a moderate increase of Fe3+/Fe2+ ratio but has a negligible effects in more silicic melts. The different behavior of Al2O3 and MgO in basaltic and more silicic melts indicates that at constant T–fO2 conditions, the effects of melt composition on ferric/ferrous ratio cannot be predicted accurately as a function of ΣdiXi where di are fixed empirical coefficients and Xi are mole fractions of the main oxide component in silicate melts. We suggest an alternative approach which accounts for the interaction of cations in complex silicate melts. Based on the data obtained in this study, an equation predicting the ferric/ferrous ratio of ultramafic to silicic melts at air conditions with changing SiO2, TiO2, Al2O3, total iron, MgO and P2O5 is proposed. More... »
PAGES24
http://scigraph.springernature.com/pub.10.1007/s00410-015-1119-6
DOIhttp://dx.doi.org/10.1007/s00410-015-1119-6
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1040179435
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0402",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Geochemistry",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/04",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Earth Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "University of Hannover",
"id": "https://www.grid.ac/institutes/grid.9122.8",
"name": [
"Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry, Russian Academy of Sciences, Staromonetny 35, 109017, Moscow, Russia",
"Institut f\u00fcr Mineralogie, Leibniz Universit\u00e4t Hannover, Callinstrasse 3, 30167, Hannover, Germany"
],
"type": "Organization"
},
"familyName": "Borisov",
"givenName": "Alexander",
"id": "sg:person.016337546241.90",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016337546241.90"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of Hannover",
"id": "https://www.grid.ac/institutes/grid.9122.8",
"name": [
"Institut f\u00fcr Mineralogie, Leibniz Universit\u00e4t Hannover, Callinstrasse 3, 30167, Hannover, Germany"
],
"type": "Organization"
},
"familyName": "Behrens",
"givenName": "Harald",
"id": "sg:person.01364645705.48",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01364645705.48"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of Hannover",
"id": "https://www.grid.ac/institutes/grid.9122.8",
"name": [
"Institut f\u00fcr Mineralogie, Leibniz Universit\u00e4t Hannover, Callinstrasse 3, 30167, Hannover, Germany"
],
"type": "Organization"
},
"familyName": "Holtz",
"givenName": "Francois",
"id": "sg:person.0647667441.13",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0647667441.13"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1007/bf00371177",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1001415336",
"https://doi.org/10.1007/bf00371177"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00373086",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1004074008",
"https://doi.org/10.1007/bf00373086"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.epsl.2011.03.014",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1005261636"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0012-821x(86)90195-0",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1011015536"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0016-7037(89)90165-8",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1014031037"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0016-7037(89)90165-8",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1014031037"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1093/petrology/37.4.837",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1016069005"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s0869591110050024",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1020452390",
"https://doi.org/10.1134/s0869591110050024"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s0869591110050024",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1020452390",
"https://doi.org/10.1134/s0869591110050024"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.2138/am.2010.3217",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1022537874"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1111/j.1151-2916.1983.tb10018.x",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1024146129"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1111/j.1151-2916.1975.tb19567.x",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1025932407"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0016-7037(89)90343-8",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1027778349"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0016-7037(89)90343-8",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1027778349"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1107/s0567739476001551",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1028010813"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00307328",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1033779883",
"https://doi.org/10.1007/bf00307328"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00307328",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1033779883",
"https://doi.org/10.1007/bf00307328"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0016-7037(80)90048-4",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1033829419"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0016-7037(80)90048-4",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1033829419"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.2138/am.2008.2795",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1040918442"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0016-7037(93)90430-5",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1043611358"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0016-7037(93)90430-5",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1043611358"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s00410-013-0943-9",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1043922373",
"https://doi.org/10.1007/s00410-013-0943-9"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/an9608500823",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1046445075"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00374720",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1051318819",
"https://doi.org/10.1007/bf00374720"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.gca.2004.07.026",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1052822943"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1126/science.1233299",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1062467918"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.2138/am-2004-11-1203",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1069056921"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.2205/2003es000115",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1069289715"
],
"type": "CreativeWork"
}
],
"datePublished": "2015-02",
"datePublishedReg": "2015-02-01",
"description": "The effect of Al2O3, MgO and total iron on the ferric/ferrous ratio in silicate melts was investigated in model silicate melts in the temperature range 1400\u20131550 \u00b0C at 1 atm total pressure. The experiments were done mostly in air and partially in pure CO2. It is demonstrated that an increase in Al2O3 concentration in a basaltic melt results in a moderate decrease of Fe3+/Fe2+ ratio. In contrast, the increase in Al2O3 in more silicic melts results in a much more pronounced decrease of Fe3+/Fe2+ ratio. The increase of MgO concentration in a basaltic melt results in a moderate increase of Fe3+/Fe2+ ratio but has a negligible effects in more silicic melts. The different behavior of Al2O3 and MgO in basaltic and more silicic melts indicates that at constant T\u2013fO2 conditions, the effects of melt composition on ferric/ferrous ratio cannot be predicted accurately as a function of \u03a3diXi where di are fixed empirical coefficients and Xi are mole fractions of the main oxide component in silicate melts. We suggest an alternative approach which accounts for the interaction of cations in complex silicate melts. Based on the data obtained in this study, an equation predicting the ferric/ferrous ratio of ultramafic to silicic melts at air conditions with changing SiO2, TiO2, Al2O3, total iron, MgO and P2O5 is proposed.",
"genre": "research_article",
"id": "sg:pub.10.1007/s00410-015-1119-6",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1026106",
"issn": [
"0010-7999",
"1432-0967"
],
"name": "Contributions to Mineralogy and Petrology",
"type": "Periodical"
},
{
"issueNumber": "2",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "169"
}
],
"name": "Effects of melt composition on Fe3+/Fe2+ in silicate melts: a step to model ferric/ferrous ratio in multicomponent systems",
"pagination": "24",
"productId": [
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"bf6686ffa3acc942377d5603471403216ce2daff7bb47bc28b3785c75835d900"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/s00410-015-1119-6"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1040179435"
]
}
],
"sameAs": [
"https://doi.org/10.1007/s00410-015-1119-6",
"https://app.dimensions.ai/details/publication/pub.1040179435"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-10T23:19",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8693_00000490.jsonl",
"type": "ScholarlyArticle",
"url": "http://link.springer.com/10.1007/s00410-015-1119-6"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s00410-015-1119-6'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s00410-015-1119-6'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s00410-015-1119-6'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s00410-015-1119-6'
This table displays all metadata directly associated to this object as RDF triples.
151 TRIPLES
21 PREDICATES
50 URIs
19 LITERALS
7 BLANK NODES