Eclogite-facies fluid infiltration: constraints from δ18O zoning in garnet View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-01

AUTHORS

Ashley K. Russell, Kouki Kitajima, Ariel Strickland, L. Gordon Medaris, Daniel J. Schulze, John W. Valley

ABSTRACT

In situ analysis reveals that eclogite-facies garnets are zoned in δ18O with lower values in the core and rims that are ~1.5 to 2.5 ‰ higher. This pattern is present in 9 out of 12 garnets analyzed by SIMS from four orogenic eclogite terranes, and correlates with an increase in the mole fraction of pyrope and Mg/Fe ratio from core to rim, indicating prograde garnet growth. At the maximum temperatures and the time-scales experienced by these garnets, calculated intragranular diffusion distances for oxygen are small (<5 μm), indicating that δ18O records primary growth zoning and not diffusive exchange. The oxygen isotope gradients are larger than could form due to temperature changes during closed-system mineral growth. Thus, gradients reflect the compositions of fluids infiltrating during prograde metamorphism. Values of δ18O in garnet cores range from −1 to 15 ‰, likely preserving the composition of the eclogite protoliths. Two garnet cores from the Almenningen eclogite in the Western Gneiss Region, Norway, have δ18O ~−1 ‰ and are the first negative δ18O eclogites identified in the region. In contrast with orogenic eclogites, seven high δ18O garnets (>5 ‰) from two kimberlites are homogeneous in δ18O, possibly due to diffusive exchange, which is possible for prolonged periods at higher mantle temperatures. Homogeneity of δ18O in garnets outside the normal mantle range (5–6 ‰) may be common in kimberlitic samples. More... »

PAGES

103-116

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s00410-012-0794-9

DOI

http://dx.doi.org/10.1007/s00410-012-0794-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1022485912


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