Structures and interactions in collapsed hydrogels of thermoresponsive interpenetrating polymer networks View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-03

AUTHORS

Lenka Hanyková, Jiří Spěváček, Marek Radecki, Alexander Zhigunov, Julie Šťastná, Helena Valentová, Zdeňka Sedláková

ABSTRACT

Temperature-induced collapse of hydrogels of interpenetrating polymer networks (IPNs) poly(N-vinylcaprolactam)/poly(N-isopropylacrylamide) (PVCL/PNIPAm) and poly(N-isopropylmethacrylamide) (PNIPMAm)/PNIPAm, where both components are thermoresponsive, was studied by combination of 1H nuclear magnetic resonance (NMR) spectroscopy, small-angle neutron scattering (SANS), differential scanning calorimetry (DSC), and dynamic mechanical measurements. Behavior of studied hydrogels (one or two transitions) was found to depend on the ratio of both IPN components. For hydrogels of IPNs containing around 50 mol% of PNIPAm monomer units, separate transitions were revealed for both components. From SANS curves, it follows that compact three-dimensional multi-chain globules are formed in PNIPMAm/PNIPAm and PVCL/PNIPAm IPN hydrogels at temperatures above the phase transition, with a gyration radius of 14–28 nm. A certain portion of spatially restricted bound water (HDO) was established for all the studied IPNs at temperature above the volume phase transition from measurements of 1H NMR spectra, spin-spin relaxation times (T2), and diffusion coefficients (D) of HDO. Slow exchange regime between bound and free water was revealed. Spin–spin relaxation times (T2) and diffusion coefficients (D) as obtained for the bound HDO are up to 2 orders of magnitude smaller in comparison with “free” HDO. Higher content of bound water as found for collapsed hydrogels of IPN PVCL/PNIPAm in comparison with PNIPMAm/PNIPAm hydrogels is in accordance with swelling experiments and lower values of the shear mechanical modulus; this shows the decisive role of bound water in this respect. More... »

PAGES

709-720

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s00396-014-3455-x

DOI

http://dx.doi.org/10.1007/s00396-014-3455-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1037984923


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Macromolecular and Materials Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Charles University", 
          "id": "https://www.grid.ac/institutes/grid.4491.8", 
          "name": [
            "Faculty of Mathematics and Physics, Charles University in Prague, V Hole\u0161ovi\u010dk\u00e1ch 2, 180 00, Prague 8, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Hanykov\u00e1", 
        "givenName": "Lenka", 
        "id": "sg:person.012045322647.66", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012045322647.66"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Macromolecular Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.424999.b", 
          "name": [
            "Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovsky Sq. 2, 162 06, Prague 6, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sp\u011bv\u00e1\u010dek", 
        "givenName": "Ji\u0159\u00ed", 
        "id": "sg:person.016104226437.52", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016104226437.52"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Charles University", 
          "id": "https://www.grid.ac/institutes/grid.4491.8", 
          "name": [
            "Faculty of Mathematics and Physics, Charles University in Prague, V Hole\u0161ovi\u010dk\u00e1ch 2, 180 00, Prague 8, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Radecki", 
        "givenName": "Marek", 
        "id": "sg:person.016432231722.83", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016432231722.83"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Macromolecular Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.424999.b", 
          "name": [
            "Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovsky Sq. 2, 162 06, Prague 6, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zhigunov", 
        "givenName": "Alexander", 
        "id": "sg:person.01014351020.24", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01014351020.24"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Charles University", 
          "id": "https://www.grid.ac/institutes/grid.4491.8", 
          "name": [
            "Faculty of Mathematics and Physics, Charles University in Prague, V Hole\u0161ovi\u010dk\u00e1ch 2, 180 00, Prague 8, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "\u0160\u0165astn\u00e1", 
        "givenName": "Julie", 
        "id": "sg:person.014302402407.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014302402407.01"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Charles University", 
          "id": "https://www.grid.ac/institutes/grid.4491.8", 
          "name": [
            "Faculty of Mathematics and Physics, Charles University in Prague, V Hole\u0161ovi\u010dk\u00e1ch 2, 180 00, Prague 8, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Valentov\u00e1", 
        "givenName": "Helena", 
        "id": "sg:person.013712753073.83", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013712753073.83"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Macromolecular Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.424999.b", 
          "name": [
            "Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovsky Sq. 2, 162 06, Prague 6, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sedl\u00e1kov\u00e1", 
        "givenName": "Zde\u0148ka", 
        "id": "sg:person.011377636253.41", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011377636253.41"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/12_2010_57", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001430475", 
          "https://doi.org/10.1007/12_2010_57"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/12_2010_57", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001430475", 
          "https://doi.org/10.1007/12_2010_57"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cocis.2008.10.003", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002679403"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00255620", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002786542", 
          "https://doi.org/10.1007/bf00255620"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00255620", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002786542", 
          "https://doi.org/10.1007/bf00255620"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/app.12794", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003957217"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/masy.201300002", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007215148"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/bp00018a008", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007475041"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/1521-3935(20010301)202:5<750::aid-macp750>3.0.co;2-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008897213"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-2860(91)87113-v", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009783227"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/1521-3935(20020201)203:3<491::aid-macp491>3.0.co;2-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012148871"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma991398q", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013452288"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma991398q", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013452288"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.polymer.2005.07.072", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018465519"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/bbpc.19510550113", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022945473"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0079-6700(92)90023-r", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025259593"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0079-6700(92)90023-r", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025259593"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/35007047", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025343153", 
          "https://doi.org/10.1038/35007047"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/35007047", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025343153", 
          "https://doi.org/10.1038/35007047"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/12_052", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025683683", 
          "https://doi.org/10.1007/12_052"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c2sm25432h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026133617"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/app.13076", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026825975"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/app.12331", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028836487"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/355208a0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028854831", 
          "https://doi.org/10.1038/355208a0"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.polymer.2004.06.041", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031476063"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.colsurfa.2005.06.044", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031691101"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.colsurfa.2005.06.044", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031691101"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.polymer.2006.06.061", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032722186"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0032-3861(00)00255-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034411484"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00396-013-2992-z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034670744", 
          "https://doi.org/10.1007/s00396-013-2992-z"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/21619", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035335278", 
          "https://doi.org/10.1038/21619"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0021889803008422", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038357101"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.polymer.2004.11.089", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043983428"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0032-3861(01)00381-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045511975"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr940351u", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048048943"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr940351u", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048048943"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02706727", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049229556", 
          "https://doi.org/10.1007/bf02706727"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02706727", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049229556", 
          "https://doi.org/10.1007/bf02706727"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0014-3057(98)00025-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050171938"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00289-012-0831-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050849202", 
          "https://doi.org/10.1007/s00289-012-0831-x"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100345a085", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055666016"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100373a088", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055667788"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100624a025", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055674400"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp2071056", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056085067"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp2071056", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056085067"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la8038363", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056164136"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la8038363", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056164136"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma001192l", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056178580"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma001192l", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056178580"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma011034+", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056185908"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma011034+", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056185908"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma035124l", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056188719"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma035124l", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056188719"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma0510284", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056190965"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma0510284", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056190965"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma051425e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056191143"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma051425e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056191143"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma200010h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056195027"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma200010h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056195027"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma302384v", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056196946"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma950677k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056205045"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma950677k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056205045"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma951390q", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056205433"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma951390q", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056205433"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma9609994", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056206394"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma9609994", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056206394"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma9615112", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056206731"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma9615112", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056206731"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1089/ten.1999.5.251", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1059313166"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physreve.60.7143", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060724591"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physreve.60.7143", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060724591"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.40.820", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060782820"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.40.820", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060782820"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1051/anphys/193911120161", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1085295658"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2015-03", 
    "datePublishedReg": "2015-03-01", 
    "description": "Temperature-induced collapse of hydrogels of interpenetrating polymer networks (IPNs) poly(N-vinylcaprolactam)/poly(N-isopropylacrylamide) (PVCL/PNIPAm) and poly(N-isopropylmethacrylamide) (PNIPMAm)/PNIPAm, where both components are thermoresponsive, was studied by combination of 1H nuclear magnetic resonance (NMR) spectroscopy, small-angle neutron scattering (SANS), differential scanning calorimetry (DSC), and dynamic mechanical measurements. Behavior of studied hydrogels (one or two transitions) was found to depend on the ratio of both IPN components. For hydrogels of IPNs containing around 50 mol% of PNIPAm monomer units, separate transitions were revealed for both components. From SANS curves, it follows that compact three-dimensional multi-chain globules are formed in PNIPMAm/PNIPAm and PVCL/PNIPAm IPN hydrogels at temperatures above the phase transition, with a gyration radius of 14\u201328 nm. A certain portion of spatially restricted bound water (HDO) was established for all the studied IPNs at temperature above the volume phase transition from measurements of 1H NMR spectra, spin-spin relaxation times (T2), and diffusion coefficients (D) of HDO. Slow exchange regime between bound and free water was revealed. Spin\u2013spin relaxation times (T2) and diffusion coefficients (D) as obtained for the bound HDO are up to 2 orders of magnitude smaller in comparison with \u201cfree\u201d HDO. Higher content of bound water as found for collapsed hydrogels of IPN PVCL/PNIPAm in comparison with PNIPMAm/PNIPAm hydrogels is in accordance with swelling experiments and lower values of the shear mechanical modulus; this shows the decisive role of bound water in this respect.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s00396-014-3455-x", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isFundedItemOf": [
      {
        "id": "sg:grant.6874874", 
        "type": "MonetaryGrant"
      }
    ], 
    "isPartOf": [
      {
        "id": "sg:journal.1083512", 
        "issn": [
          "0303-402X", 
          "1435-1536"
        ], 
        "name": "Colloid and Polymer Science", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "293"
      }
    ], 
    "name": "Structures and interactions in collapsed hydrogels of thermoresponsive interpenetrating polymer networks", 
    "pagination": "709-720", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "b4f289eae661a1f46c727080a8d1ca75897cb32ea795aa9275b2616ca808e2fd"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s00396-014-3455-x"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1037984923"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s00396-014-3455-x", 
      "https://app.dimensions.ai/details/publication/pub.1037984923"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T13:17", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8659_00000514.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs00396-014-3455-x"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s00396-014-3455-x'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s00396-014-3455-x'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s00396-014-3455-x'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s00396-014-3455-x'


 

This table displays all metadata directly associated to this object as RDF triples.

273 TRIPLES      21 PREDICATES      79 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s00396-014-3455-x schema:about anzsrc-for:03
2 anzsrc-for:0303
3 schema:author Neaf537c9029e40f9ac8292b293d0e4aa
4 schema:citation sg:pub.10.1007/12_052
5 sg:pub.10.1007/12_2010_57
6 sg:pub.10.1007/bf00255620
7 sg:pub.10.1007/bf02706727
8 sg:pub.10.1007/s00289-012-0831-x
9 sg:pub.10.1007/s00396-013-2992-z
10 sg:pub.10.1038/21619
11 sg:pub.10.1038/35007047
12 sg:pub.10.1038/355208a0
13 https://doi.org/10.1002/1521-3935(20010301)202:5<750::aid-macp750>3.0.co;2-8
14 https://doi.org/10.1002/1521-3935(20020201)203:3<491::aid-macp491>3.0.co;2-1
15 https://doi.org/10.1002/app.12331
16 https://doi.org/10.1002/app.12794
17 https://doi.org/10.1002/app.13076
18 https://doi.org/10.1002/bbpc.19510550113
19 https://doi.org/10.1002/masy.201300002
20 https://doi.org/10.1016/0022-2860(91)87113-v
21 https://doi.org/10.1016/0079-6700(92)90023-r
22 https://doi.org/10.1016/j.cocis.2008.10.003
23 https://doi.org/10.1016/j.colsurfa.2005.06.044
24 https://doi.org/10.1016/j.polymer.2004.06.041
25 https://doi.org/10.1016/j.polymer.2004.11.089
26 https://doi.org/10.1016/j.polymer.2005.07.072
27 https://doi.org/10.1016/j.polymer.2006.06.061
28 https://doi.org/10.1016/s0014-3057(98)00025-1
29 https://doi.org/10.1016/s0032-3861(00)00255-x
30 https://doi.org/10.1016/s0032-3861(01)00381-0
31 https://doi.org/10.1021/bp00018a008
32 https://doi.org/10.1021/cr940351u
33 https://doi.org/10.1021/j100345a085
34 https://doi.org/10.1021/j100373a088
35 https://doi.org/10.1021/j100624a025
36 https://doi.org/10.1021/jp2071056
37 https://doi.org/10.1021/la8038363
38 https://doi.org/10.1021/ma001192l
39 https://doi.org/10.1021/ma011034+
40 https://doi.org/10.1021/ma035124l
41 https://doi.org/10.1021/ma0510284
42 https://doi.org/10.1021/ma051425e
43 https://doi.org/10.1021/ma200010h
44 https://doi.org/10.1021/ma302384v
45 https://doi.org/10.1021/ma950677k
46 https://doi.org/10.1021/ma951390q
47 https://doi.org/10.1021/ma9609994
48 https://doi.org/10.1021/ma9615112
49 https://doi.org/10.1021/ma991398q
50 https://doi.org/10.1039/c2sm25432h
51 https://doi.org/10.1051/anphys/193911120161
52 https://doi.org/10.1089/ten.1999.5.251
53 https://doi.org/10.1103/physreve.60.7143
54 https://doi.org/10.1103/physrevlett.40.820
55 https://doi.org/10.1107/s0021889803008422
56 schema:datePublished 2015-03
57 schema:datePublishedReg 2015-03-01
58 schema:description Temperature-induced collapse of hydrogels of interpenetrating polymer networks (IPNs) poly(N-vinylcaprolactam)/poly(N-isopropylacrylamide) (PVCL/PNIPAm) and poly(N-isopropylmethacrylamide) (PNIPMAm)/PNIPAm, where both components are thermoresponsive, was studied by combination of 1H nuclear magnetic resonance (NMR) spectroscopy, small-angle neutron scattering (SANS), differential scanning calorimetry (DSC), and dynamic mechanical measurements. Behavior of studied hydrogels (one or two transitions) was found to depend on the ratio of both IPN components. For hydrogels of IPNs containing around 50 mol% of PNIPAm monomer units, separate transitions were revealed for both components. From SANS curves, it follows that compact three-dimensional multi-chain globules are formed in PNIPMAm/PNIPAm and PVCL/PNIPAm IPN hydrogels at temperatures above the phase transition, with a gyration radius of 14–28 nm. A certain portion of spatially restricted bound water (HDO) was established for all the studied IPNs at temperature above the volume phase transition from measurements of 1H NMR spectra, spin-spin relaxation times (T2), and diffusion coefficients (D) of HDO. Slow exchange regime between bound and free water was revealed. Spin–spin relaxation times (T2) and diffusion coefficients (D) as obtained for the bound HDO are up to 2 orders of magnitude smaller in comparison with “free” HDO. Higher content of bound water as found for collapsed hydrogels of IPN PVCL/PNIPAm in comparison with PNIPMAm/PNIPAm hydrogels is in accordance with swelling experiments and lower values of the shear mechanical modulus; this shows the decisive role of bound water in this respect.
59 schema:genre research_article
60 schema:inLanguage en
61 schema:isAccessibleForFree false
62 schema:isPartOf N3d2ee992140e46d9815bcc39fede3429
63 Nc4c4aa9aeb804ddfa289dbbf3507db05
64 sg:journal.1083512
65 schema:name Structures and interactions in collapsed hydrogels of thermoresponsive interpenetrating polymer networks
66 schema:pagination 709-720
67 schema:productId N1fe53cc1f57341ecad9ce85792a8fa0a
68 N72f9f6c222424e3c904adcdab1c469e5
69 Ndbebdbe9285a466fa24b50a15861d9ac
70 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037984923
71 https://doi.org/10.1007/s00396-014-3455-x
72 schema:sdDatePublished 2019-04-10T13:17
73 schema:sdLicense https://scigraph.springernature.com/explorer/license/
74 schema:sdPublisher Nee3fbbb4a1f04e568db2d1b8a4c2c43f
75 schema:url http://link.springer.com/10.1007%2Fs00396-014-3455-x
76 sgo:license sg:explorer/license/
77 sgo:sdDataset articles
78 rdf:type schema:ScholarlyArticle
79 N01220d7da87248ce8a3606680d5086ec rdf:first sg:person.014302402407.01
80 rdf:rest N2a7217e3b2a24a458f7f23207b58d349
81 N04db1ee492284a169e5e87bc0d11559f rdf:first sg:person.011377636253.41
82 rdf:rest rdf:nil
83 N1fe53cc1f57341ecad9ce85792a8fa0a schema:name dimensions_id
84 schema:value pub.1037984923
85 rdf:type schema:PropertyValue
86 N2a7217e3b2a24a458f7f23207b58d349 rdf:first sg:person.013712753073.83
87 rdf:rest N04db1ee492284a169e5e87bc0d11559f
88 N3d2ee992140e46d9815bcc39fede3429 schema:volumeNumber 293
89 rdf:type schema:PublicationVolume
90 N72f9f6c222424e3c904adcdab1c469e5 schema:name doi
91 schema:value 10.1007/s00396-014-3455-x
92 rdf:type schema:PropertyValue
93 N80dc8914aa734d88806522a51f354c6d rdf:first sg:person.016432231722.83
94 rdf:rest Nbe10fb4f03914f9b83b482cd0b264288
95 Nae42cf3fdb074c76a18515a77a3844e1 rdf:first sg:person.016104226437.52
96 rdf:rest N80dc8914aa734d88806522a51f354c6d
97 Nbe10fb4f03914f9b83b482cd0b264288 rdf:first sg:person.01014351020.24
98 rdf:rest N01220d7da87248ce8a3606680d5086ec
99 Nc4c4aa9aeb804ddfa289dbbf3507db05 schema:issueNumber 3
100 rdf:type schema:PublicationIssue
101 Ndbebdbe9285a466fa24b50a15861d9ac schema:name readcube_id
102 schema:value b4f289eae661a1f46c727080a8d1ca75897cb32ea795aa9275b2616ca808e2fd
103 rdf:type schema:PropertyValue
104 Neaf537c9029e40f9ac8292b293d0e4aa rdf:first sg:person.012045322647.66
105 rdf:rest Nae42cf3fdb074c76a18515a77a3844e1
106 Nee3fbbb4a1f04e568db2d1b8a4c2c43f schema:name Springer Nature - SN SciGraph project
107 rdf:type schema:Organization
108 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
109 schema:name Chemical Sciences
110 rdf:type schema:DefinedTerm
111 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
112 schema:name Macromolecular and Materials Chemistry
113 rdf:type schema:DefinedTerm
114 sg:grant.6874874 http://pending.schema.org/fundedItem sg:pub.10.1007/s00396-014-3455-x
115 rdf:type schema:MonetaryGrant
116 sg:journal.1083512 schema:issn 0303-402X
117 1435-1536
118 schema:name Colloid and Polymer Science
119 rdf:type schema:Periodical
120 sg:person.01014351020.24 schema:affiliation https://www.grid.ac/institutes/grid.424999.b
121 schema:familyName Zhigunov
122 schema:givenName Alexander
123 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01014351020.24
124 rdf:type schema:Person
125 sg:person.011377636253.41 schema:affiliation https://www.grid.ac/institutes/grid.424999.b
126 schema:familyName Sedláková
127 schema:givenName Zdeňka
128 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011377636253.41
129 rdf:type schema:Person
130 sg:person.012045322647.66 schema:affiliation https://www.grid.ac/institutes/grid.4491.8
131 schema:familyName Hanyková
132 schema:givenName Lenka
133 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012045322647.66
134 rdf:type schema:Person
135 sg:person.013712753073.83 schema:affiliation https://www.grid.ac/institutes/grid.4491.8
136 schema:familyName Valentová
137 schema:givenName Helena
138 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013712753073.83
139 rdf:type schema:Person
140 sg:person.014302402407.01 schema:affiliation https://www.grid.ac/institutes/grid.4491.8
141 schema:familyName Šťastná
142 schema:givenName Julie
143 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014302402407.01
144 rdf:type schema:Person
145 sg:person.016104226437.52 schema:affiliation https://www.grid.ac/institutes/grid.424999.b
146 schema:familyName Spěváček
147 schema:givenName Jiří
148 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016104226437.52
149 rdf:type schema:Person
150 sg:person.016432231722.83 schema:affiliation https://www.grid.ac/institutes/grid.4491.8
151 schema:familyName Radecki
152 schema:givenName Marek
153 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016432231722.83
154 rdf:type schema:Person
155 sg:pub.10.1007/12_052 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025683683
156 https://doi.org/10.1007/12_052
157 rdf:type schema:CreativeWork
158 sg:pub.10.1007/12_2010_57 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001430475
159 https://doi.org/10.1007/12_2010_57
160 rdf:type schema:CreativeWork
161 sg:pub.10.1007/bf00255620 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002786542
162 https://doi.org/10.1007/bf00255620
163 rdf:type schema:CreativeWork
164 sg:pub.10.1007/bf02706727 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049229556
165 https://doi.org/10.1007/bf02706727
166 rdf:type schema:CreativeWork
167 sg:pub.10.1007/s00289-012-0831-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1050849202
168 https://doi.org/10.1007/s00289-012-0831-x
169 rdf:type schema:CreativeWork
170 sg:pub.10.1007/s00396-013-2992-z schema:sameAs https://app.dimensions.ai/details/publication/pub.1034670744
171 https://doi.org/10.1007/s00396-013-2992-z
172 rdf:type schema:CreativeWork
173 sg:pub.10.1038/21619 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035335278
174 https://doi.org/10.1038/21619
175 rdf:type schema:CreativeWork
176 sg:pub.10.1038/35007047 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025343153
177 https://doi.org/10.1038/35007047
178 rdf:type schema:CreativeWork
179 sg:pub.10.1038/355208a0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028854831
180 https://doi.org/10.1038/355208a0
181 rdf:type schema:CreativeWork
182 https://doi.org/10.1002/1521-3935(20010301)202:5<750::aid-macp750>3.0.co;2-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008897213
183 rdf:type schema:CreativeWork
184 https://doi.org/10.1002/1521-3935(20020201)203:3<491::aid-macp491>3.0.co;2-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012148871
185 rdf:type schema:CreativeWork
186 https://doi.org/10.1002/app.12331 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028836487
187 rdf:type schema:CreativeWork
188 https://doi.org/10.1002/app.12794 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003957217
189 rdf:type schema:CreativeWork
190 https://doi.org/10.1002/app.13076 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026825975
191 rdf:type schema:CreativeWork
192 https://doi.org/10.1002/bbpc.19510550113 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022945473
193 rdf:type schema:CreativeWork
194 https://doi.org/10.1002/masy.201300002 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007215148
195 rdf:type schema:CreativeWork
196 https://doi.org/10.1016/0022-2860(91)87113-v schema:sameAs https://app.dimensions.ai/details/publication/pub.1009783227
197 rdf:type schema:CreativeWork
198 https://doi.org/10.1016/0079-6700(92)90023-r schema:sameAs https://app.dimensions.ai/details/publication/pub.1025259593
199 rdf:type schema:CreativeWork
200 https://doi.org/10.1016/j.cocis.2008.10.003 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002679403
201 rdf:type schema:CreativeWork
202 https://doi.org/10.1016/j.colsurfa.2005.06.044 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031691101
203 rdf:type schema:CreativeWork
204 https://doi.org/10.1016/j.polymer.2004.06.041 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031476063
205 rdf:type schema:CreativeWork
206 https://doi.org/10.1016/j.polymer.2004.11.089 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043983428
207 rdf:type schema:CreativeWork
208 https://doi.org/10.1016/j.polymer.2005.07.072 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018465519
209 rdf:type schema:CreativeWork
210 https://doi.org/10.1016/j.polymer.2006.06.061 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032722186
211 rdf:type schema:CreativeWork
212 https://doi.org/10.1016/s0014-3057(98)00025-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050171938
213 rdf:type schema:CreativeWork
214 https://doi.org/10.1016/s0032-3861(00)00255-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1034411484
215 rdf:type schema:CreativeWork
216 https://doi.org/10.1016/s0032-3861(01)00381-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045511975
217 rdf:type schema:CreativeWork
218 https://doi.org/10.1021/bp00018a008 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007475041
219 rdf:type schema:CreativeWork
220 https://doi.org/10.1021/cr940351u schema:sameAs https://app.dimensions.ai/details/publication/pub.1048048943
221 rdf:type schema:CreativeWork
222 https://doi.org/10.1021/j100345a085 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055666016
223 rdf:type schema:CreativeWork
224 https://doi.org/10.1021/j100373a088 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055667788
225 rdf:type schema:CreativeWork
226 https://doi.org/10.1021/j100624a025 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055674400
227 rdf:type schema:CreativeWork
228 https://doi.org/10.1021/jp2071056 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056085067
229 rdf:type schema:CreativeWork
230 https://doi.org/10.1021/la8038363 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056164136
231 rdf:type schema:CreativeWork
232 https://doi.org/10.1021/ma001192l schema:sameAs https://app.dimensions.ai/details/publication/pub.1056178580
233 rdf:type schema:CreativeWork
234 https://doi.org/10.1021/ma011034+ schema:sameAs https://app.dimensions.ai/details/publication/pub.1056185908
235 rdf:type schema:CreativeWork
236 https://doi.org/10.1021/ma035124l schema:sameAs https://app.dimensions.ai/details/publication/pub.1056188719
237 rdf:type schema:CreativeWork
238 https://doi.org/10.1021/ma0510284 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056190965
239 rdf:type schema:CreativeWork
240 https://doi.org/10.1021/ma051425e schema:sameAs https://app.dimensions.ai/details/publication/pub.1056191143
241 rdf:type schema:CreativeWork
242 https://doi.org/10.1021/ma200010h schema:sameAs https://app.dimensions.ai/details/publication/pub.1056195027
243 rdf:type schema:CreativeWork
244 https://doi.org/10.1021/ma302384v schema:sameAs https://app.dimensions.ai/details/publication/pub.1056196946
245 rdf:type schema:CreativeWork
246 https://doi.org/10.1021/ma950677k schema:sameAs https://app.dimensions.ai/details/publication/pub.1056205045
247 rdf:type schema:CreativeWork
248 https://doi.org/10.1021/ma951390q schema:sameAs https://app.dimensions.ai/details/publication/pub.1056205433
249 rdf:type schema:CreativeWork
250 https://doi.org/10.1021/ma9609994 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056206394
251 rdf:type schema:CreativeWork
252 https://doi.org/10.1021/ma9615112 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056206731
253 rdf:type schema:CreativeWork
254 https://doi.org/10.1021/ma991398q schema:sameAs https://app.dimensions.ai/details/publication/pub.1013452288
255 rdf:type schema:CreativeWork
256 https://doi.org/10.1039/c2sm25432h schema:sameAs https://app.dimensions.ai/details/publication/pub.1026133617
257 rdf:type schema:CreativeWork
258 https://doi.org/10.1051/anphys/193911120161 schema:sameAs https://app.dimensions.ai/details/publication/pub.1085295658
259 rdf:type schema:CreativeWork
260 https://doi.org/10.1089/ten.1999.5.251 schema:sameAs https://app.dimensions.ai/details/publication/pub.1059313166
261 rdf:type schema:CreativeWork
262 https://doi.org/10.1103/physreve.60.7143 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060724591
263 rdf:type schema:CreativeWork
264 https://doi.org/10.1103/physrevlett.40.820 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060782820
265 rdf:type schema:CreativeWork
266 https://doi.org/10.1107/s0021889803008422 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038357101
267 rdf:type schema:CreativeWork
268 https://www.grid.ac/institutes/grid.424999.b schema:alternateName Institute of Macromolecular Chemistry
269 schema:name Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovsky Sq. 2, 162 06, Prague 6, Czech Republic
270 rdf:type schema:Organization
271 https://www.grid.ac/institutes/grid.4491.8 schema:alternateName Charles University
272 schema:name Faculty of Mathematics and Physics, Charles University in Prague, V Holešovičkách 2, 180 00, Prague 8, Czech Republic
273 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...