The rheological properties of hydrogenated castor oil crystals View Full Text


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Article Info

DATE

2014-10

AUTHORS

Niels De Meirleir, Linda Pellens, Walter Broeckx, Guy van Assche, Wim De Malsche

ABSTRACT

The present study focuses on the rheological performance of a surfactant-rich aqueous suspension containing hydrogenated castor oil (HCO) crystals. HCO can be typically crystallized in five distinct shapes: spherically shaped, irregularly shaped, star-shaped (also called rosettes), short needles, and thick or thin fibers. The effect of the differences in shape on the rheological performance is studied, and the rheological properties are compared to the behavior of other triacylglycerol’s (TAG) suspensions. A suspension of TAG crystals usually behaves as a colloidal gel wherein a colloidal gel is defined as a network of flocs, with each floc being an aggregate of smaller subunits. All of these surfactant-rich aqueous suspensions of HCO crystals behaved according to a colloidal gel in the transient regime, independent of the studied crystal shapes, except the long thin fibers at a concentration above 0.1 wt% HCO transitioning from a heterogeneous fractal rod network to a homogeneous rod network, shifting from a colloidal gel to a glass. More... »

PAGES

2539-2547

References to SciGraph publications

  • 2006-05. Microstructure and fractal analysis of fat crystal networks in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 2011-04-01. Colloidal Glasses in GLASSES AND GRAINS
  • 2005-06-10. Structural and mechanical properties of biopolymer gels in BIOPOLYMERS
  • 1988-09. Rheology of concentrated microgel solutions in RHEOLOGICA ACTA
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    URI

    http://scigraph.springernature.com/pub.10.1007/s00396-014-3298-5

    DOI

    http://dx.doi.org/10.1007/s00396-014-3298-5

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1005080755


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