A modifier that enables the easy dispersion of alkyl-coated nanoparticles in an epoxy network View Full Text


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Article Info

DATE

2013-07

AUTHORS

Julieta Puig, Ileana A. Zucchi, Cristina E. Hoppe, M. Arturo López-Quintela, Roberto J. J. Williams

ABSTRACT

Nanoparticles (NPs) coated with alkyl chains cannot be dissolved in diglycidylether of bisphenol A (DGEBA), which is a typical monomer used in the synthesis of epoxy networks. We show that adding small amounts of the linear amphiphilic polymer obtained by reaction of DGEBA with dodecylamine, produced a stable dispersion of dodecanethiol-coated gold NPs in DGEBA. The anionic homopolymerization of this blend initiated by a tertiary amine led to a nanocomposite with a uniform dispersion of gold NPs. The selected crosslinking chemistry allowed covalent bonding of the modifier to the matrix, avoiding phase separation and enabling easy tuning of the thermal properties of the matrix. More... »

PAGES

1677-1682

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s00396-013-2902-4

DOI

http://dx.doi.org/10.1007/s00396-013-2902-4

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https://app.dimensions.ai/details/publication/pub.1050441496


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